Chapter 52

EPSOM SALTS.Sulphate of Magnesia.

EQUIVALENTS, CHEMICAL. (Stöchiometrie, Germ.) This expression was first employed by Dr. Wollaston, to denote the primary proportions in which the various chemical bodies reciprocally combine; the numbers representing these proportions being referred to one standard substance of general interest, such as oxygen or hydrogen reckoned unity, or 1,000. Dr. Dalton, who is the true author of the grand discovery of definite, and multiple chemical ratios, calls these equivalent numbersatomic weights, when reduced to their lowest terms, either hydrogen or oxygen being the radix of the scale. Though it belongs to a chemical work, to discuss the principles and develope the applications of the Atomic Theory, I shall be careful, upon all proper occasions, to point out the vast advantages which the chemical manufacturer may derive from it, and to show how much he may economize and improve his actual processes by its means. SeeElement.

ESSENCES, are either ethereous oils, in which all the fragrance of vegetable products reside; or the same combined and diluted with alcohol. SeeOils, Ethereous.

ESSENCE D’ORIENT, the name of a pearly looking matter procured from the blay or bleak, a fish of the genuscyprinus. This substance, which is found principally at the base of the scales, is used in the manufacture of artificial pearls. A large quantity of the scales being scraped into water in a tub, are there rubbed between the hands to separate the shining stuff, which subsides on repose. The first water being decanted, more is added with agitation till the essence is thoroughly washed from all impurities; when the whole is thrown upon a sieve; the substance passes through, but the scales are retained. The water being decanted off, the essence is procured in a viscid state, of a bluish white colour, and a pearly aspect. The intestines of the same fish are also covered with this beautiful glistening matter. Several other fish yield it, but in smaller proportion. When well prepared, it presents exactly the appearance and reflections of the real pearls, or the finest mother of pearl; properties which are probably owing to the interposition of some portions of this same substance, between the laminæ of these shelly concretions. Its chemical nature has not been investigated; it putrefies readily when kept moist, an accident which may however be counteracted by water of ammonia. SeePearls.

ETCHINGVarnish. (Aetzgrund-Deckfirniss, Germ.) Though the practice of this elegant art does not come within the scope of our Dictionary, the preparation of the varnishes, and of the biting menstrua which it employs, legitimately does.The varnish of Mr. Lawrence, an English artist resident in Paris, is made as follows: Take of virgin wax and asphaltum, each two ounces, of black pitch and burgundy-pitch each half an ounce. Melt the wax and pitch in a new earthenware glazed pot, and add to them, by degrees, the asphaltum, finely powdered. Let the whole boil till such time as that, taking a drop upon a plate, it will break when it is cold, on bending it double two or three times betwixt the fingers. The varnish, being then enough boiled, must be taken off the fire, and after it cools a little, must be poured into warm water that it may work the more easily with the hands, so as to be formed into balls, which must be kneaded, and put into a piece of taffety for use.Care must be taken, first, that the fire be not too violent, for fear of burning the ingredients, a slight simmering being sufficient; secondly, that whilst the asphaltum is putting in, and even after it is mixed with the ingredients, they should be stirred continually with the spatula; and, thirdly, that the water into which this composition is thrown should be nearly of the same degree of warmth with it, in order to prevent a kind of cracking that happens when the water is too cold.The varnish ought always to be made harder in summer than in winter, and it will become so if it be suffered to boil longer, or if a greater proportion of the asphaltum orbrown rosin be used. The experiment above mentioned, of the drop suffered to cool, will determine the degree of hardness or softness that may be suitable to the season when it is used.Preparation of the hard varnish used by Callot, commonly called the Florence Varnish:—Take four ounces of fat oil very clear, and made of good linseed oil, like that used by painters; heat it in a clean pot of glazed earthenware, and afterwards put to it four ounces of mastick well powdered, and stir the mixture briskly till the whole be well melted, then pass the mass through a piece of fine linen into a glass bottle with a long neck, that can be stopped very securely; and keep it for the use that will be explained below.Method of applying the soft varnish to the plate, and of blackening it.—The plate being well polished and burnished, as also cleansed from all greasiness by chalk or Spanish white, fix a hand-vice on the edge of the plate where no work is intended to be, to serve as a handle for managing it when warm; then put it upon a chafing dish, in which there is a moderate fire, and cover the whole plate equally with a thin coat of the varnish; and whilst the plate is warm, and the varnish upon it in a fluid state, beat every part of the varnish gently with a small ball or dauber made of cotton tied up in taffety, which operation smooths and distributes the varnish equally over the plate.When the plate is thus uniformly and thinly covered with the varnish, it must be blackened by a piece of flambeau, or of a large candle which affords a copious smoke; sometimes two or even four such candles are used together for the sake of dispatch, that the varnish may not grow cold, which if it does during the operation, the plate must be heated again, that it may be in a melted state when that operation is performed; but great care must be taken not to burn it, which when it happens may be easily perceived by the varnish appearing burnt and losing its gloss.The menstruum used and recommended by Turrell, an eminent London artist, for etching upon steel, was prepared as follows:—TakePyrolignous acid4parts by measure,Alcohol1part, mix, and addNitric acid1part.This mixed liquor is to be applied from 11⁄2to 15 minutes, according to the depth desired. The nitric acid was employed of the strength of 1·28—the double aquafortis of the shops.Theeau forteor menstruum for copper, used by Callot, as also by Piranesi, with a slight modification, is prepared, with8parts of strong French vinegar,4parts of verdigris,4ditto sea salt,4ditto sal ammoniac,1ditto alum,16ditto water.The solid substances are to be well ground, dissolved in the vinegar, and diluted with the water; the mixture is now to be boiled for a moment, and then set aside to cool. This menstruum is applied to the washed, dried, and varnished plate, after it has suffered the ordinary action of aquafortis, in order to deepen and finish the delicate touches. It is at present called theeau forte à passer.

The varnish of Mr. Lawrence, an English artist resident in Paris, is made as follows: Take of virgin wax and asphaltum, each two ounces, of black pitch and burgundy-pitch each half an ounce. Melt the wax and pitch in a new earthenware glazed pot, and add to them, by degrees, the asphaltum, finely powdered. Let the whole boil till such time as that, taking a drop upon a plate, it will break when it is cold, on bending it double two or three times betwixt the fingers. The varnish, being then enough boiled, must be taken off the fire, and after it cools a little, must be poured into warm water that it may work the more easily with the hands, so as to be formed into balls, which must be kneaded, and put into a piece of taffety for use.

Care must be taken, first, that the fire be not too violent, for fear of burning the ingredients, a slight simmering being sufficient; secondly, that whilst the asphaltum is putting in, and even after it is mixed with the ingredients, they should be stirred continually with the spatula; and, thirdly, that the water into which this composition is thrown should be nearly of the same degree of warmth with it, in order to prevent a kind of cracking that happens when the water is too cold.

The varnish ought always to be made harder in summer than in winter, and it will become so if it be suffered to boil longer, or if a greater proportion of the asphaltum orbrown rosin be used. The experiment above mentioned, of the drop suffered to cool, will determine the degree of hardness or softness that may be suitable to the season when it is used.

Preparation of the hard varnish used by Callot, commonly called the Florence Varnish:—Take four ounces of fat oil very clear, and made of good linseed oil, like that used by painters; heat it in a clean pot of glazed earthenware, and afterwards put to it four ounces of mastick well powdered, and stir the mixture briskly till the whole be well melted, then pass the mass through a piece of fine linen into a glass bottle with a long neck, that can be stopped very securely; and keep it for the use that will be explained below.

Method of applying the soft varnish to the plate, and of blackening it.—The plate being well polished and burnished, as also cleansed from all greasiness by chalk or Spanish white, fix a hand-vice on the edge of the plate where no work is intended to be, to serve as a handle for managing it when warm; then put it upon a chafing dish, in which there is a moderate fire, and cover the whole plate equally with a thin coat of the varnish; and whilst the plate is warm, and the varnish upon it in a fluid state, beat every part of the varnish gently with a small ball or dauber made of cotton tied up in taffety, which operation smooths and distributes the varnish equally over the plate.

When the plate is thus uniformly and thinly covered with the varnish, it must be blackened by a piece of flambeau, or of a large candle which affords a copious smoke; sometimes two or even four such candles are used together for the sake of dispatch, that the varnish may not grow cold, which if it does during the operation, the plate must be heated again, that it may be in a melted state when that operation is performed; but great care must be taken not to burn it, which when it happens may be easily perceived by the varnish appearing burnt and losing its gloss.

The menstruum used and recommended by Turrell, an eminent London artist, for etching upon steel, was prepared as follows:—

This mixed liquor is to be applied from 11⁄2to 15 minutes, according to the depth desired. The nitric acid was employed of the strength of 1·28—the double aquafortis of the shops.

Theeau forteor menstruum for copper, used by Callot, as also by Piranesi, with a slight modification, is prepared, with

The solid substances are to be well ground, dissolved in the vinegar, and diluted with the water; the mixture is now to be boiled for a moment, and then set aside to cool. This menstruum is applied to the washed, dried, and varnished plate, after it has suffered the ordinary action of aquafortis, in order to deepen and finish the delicate touches. It is at present called theeau forte à passer.

ETHER, is the name of a class of very light, volatile, inflammable, and fragrant spirituous liquids, obtained by distilling in a glass retort, a mixture of alcohol with almost any strong acid. Every acid modifies the result, in a certain degree, whence several varieties of ether are produced. The only one of commercial importance is sulphuric ether, which was first made known under the name ofsweet oil of vitriol, in 1540, by the receipt of Walterus Cordus. Froberus, 190 years after that date, directed the attention of chemists afresh to this substance, under the new denomination ofether.There are two methods of preparing it; by the first, the whole quantity of acid and alcohol are mixed at once, and directly subjected to distillation; by the second, the alcohol is admitted, in a slender streamlet, into a body of acid previously mixed with a little alcohol, and heated to 220° Fahr.1. Mix equal weights of alcohol at spec. grav. 0·830, and sulphuric acid at 1·842, by introducing the former into a large tubulated retort, giving it a whirling motion, so that the alcohol may revolve round a central conical cavity. Into this species of whirlpool the acid is to be slowly poured. The mixture, which becomes warm, is to be forthwith distilled by attaching a spacious receiver to the retort, and applying the heat of a sand-bath. The formation of ether takes place only at a certain temperature. If the contents of the retort be allowed to cool, and be then slowly heated in a water bath, alcohol alone will come over for some time without ether, till the mixture acquires theproper degree of heat. The first receiver should be a globe, with a tube proceeding from its bottom, into a second receiver, of a cylindric shape, surrounded with ice-cold water. The joints must be well secured by lutes, after the expanded air has been allowed to escape. The liquid in the retort should be kept in a steady state of bullition. The ether, as long as it is produced, condenses in the balloon and neck of the receiver in striæ; when these disappear the process is completed. The retort must now be removed from the sand; otherwise it would become filled with white fumes containing sulphurous acid, and denser striæ would flow over, which would contaminate the light product with a liquid called sweet oil of wine.The theory of etherification demonstrates that when strong sulphuric acid is mixed with alcohol, there is formed, on the one hand, a more aqueous sulphuric acid, and, on the other, sulphovinic acid. When this mixture is made to boil, the sulphovinic acid is decomposed, its dihydrate of carbon combines with the alcohol, and constitutes ether; while the proportion of sulphovinic acid progressively diminishes. Mr. Hennell, of the Apothecaries’ Hall, first explained these phenomena, and he was confirmed in his views by the interesting researches of Serullas. The acid left in the retort is usually of a black colour, and may be employed to convert into ether half as much alcohol again; an experiment which may be repeated several times in succession.The most profitable way of manufacturing ether has been pointed out by Boullay. It consists in letting the alcohol drop in a slender stream into the acid, previously heated to the etherifying temperature. If the acid in this case were concentrated to 1·846, the reaction would be too violent, and the ether would be transformed into bicarburetted hydrogen (dihydrate of carbon.) It is therefore necessary to dilute the acid down to the density of 1·780; but this dilution may be preferably effected with alcohol instead of water, by mixing three parts of the strongest acid with 2 of alcohol, specific gravity 0·830, and distilling off a portion of the ether thereby generated; after which the stream of alcohol is to be introduced into the tubulure of the retort through a small glass tube plunged into the mixture; this tube being the prolongation of a metallic syphon, whose shorter leg dips into a bottle filled with the alcohol. The longer leg is furnished with a stop-cock, for regulating at pleasure the alcoholic streamlet. The distilled vapours should be transmitted through a worm of pure tin surrounded by cold water, and the condensed fluid received in a glass bottle. The quantity of alcohol which can be thus converted into ether by a given weight of sulphuric acid, has not hitherto been accurately determined; but it is at least double. In operating in this way, neither sulphurous acid, nor sweet oil of wine is generated, while the residuary liquid in the retort continues limpid and of a merely brownish yellow colour. No sulphovinic acid is formed, and according to the experiments of Geiger, the proportion of ether approaches to what theory shows to be the maximum amount. In fact 57 parts of alcohol of 0·83 sp. grav. being equivalent to 46·8 parts of anhydrous alcohol, yield according to Geiger, 331⁄2parts of ether; and by calculation, they should yield 371⁄4.The ether of the first distillation is never pure, but always contains a certain quantity of alcohol. The density of that product is usually 0·78, and if prepared by the first of the above methods, contains besides alcohol, pretty frequently sulphurous acid, and sweet oil of wine, impurities from which it must be freed. Being agitated with its bulk of milk of lime, both the acid and the alcohol are removed at the same time; and if it be then decanted and agitated, first with its bulk of water, next decanted into a retort containing chloride of calcium in coarse powder and distilled, one third of perfectly pure ether may be drawn over. Gay Lussac recommends to agitate the ether, first with twice its volume of water, to mix it, and leave it in contact with powdered unslaked lime for 12 or 14 hours, and then to distil off one third of pure ether. The remaining two thirds consist of ether containing a little alcohol. If in preparing ether by Boullay’s method, the alcohol be too rapidly introduced, much of this liquid will come over unchanged. If in this state the ether be shaken with water, a notable quantity of it will be absorbed, because weak alcohol dissolves it very copiously. The above product should therefore be re-distilled, and the first half that comes over may be considered as ether, and treated with water and lime. The other half must be exposed afresh to the action of sulphuric acid.Pure ether possesses the following properties. It is limpid, of spec. grav. 0·713, or 0·715 at 60°; has a peculiar penetrating strong smell; a taste at first acrid, burning, sweetish, and finally cooling. It has neither an acid nor alkaline reaction; is a non-conductor of electricity, and refracts light strongly. It is very volatile, boiling at 96° or 97° F., and produces by its evaporation a great degree of cold. At the temperature of 62·4, the vapour of ether balances a column of mercury 15 inches high, or half the weight of the atmosphere. When ether is cooled to -24° F. it begins to crystallize in brilliant white plates, and at -47° it becomes a white crystalline solid. When vapour of ether is made to traverse a red hot porcelain tube, it deposits within it one half per cent. of charcoal, and there are condensed in the receiver one and two thirdsper cent. of a brown oil, partly in crystalline scales, and partly viscid. The crystalline portion is soluble in alcohol, but the viscid only in ether. The remainder of the decomposed ether consists of bi-carburetted hydrogen gas, tetrahydric carburet, carbonic oxide gas, and one per cent. at most of gaseous carbonic acid.Ether takes fire readily, even at some distance from a flame, and it should not therefore be poured from one vessel to another in the neighbourhood of a lighted candle. It may be likewise set on fire by the electric spark. It burns all away with a bright fuliginous flame. When the vapour of ether is mixed with 10 times its volume of oxygen, it burns with a violent explosion, absorbs 6 times its bulk of oxygen, and produces 4 times its volume of carbonic acid gas.Ether alters gradually with contact of air; absorbing oxygen, and progressively changing into acetic acid and water. This conversion takes place very rapidly when the ether is boiled in an open vessel, while the acid enters into a new combination forming acetic ether. Ether should be preserved in bottles perfectly full and well corked, and kept in a cool place, otherwise it becomes sour, and is destroyed. It contains in this state 15 per cent. of its bulk of azote, but no oxygen gas, as this has combined with its elements. Ether is composed of oxygen 21·24; hydrogen 13·85; carbon 65·05. This composition may be represented by 1 prime equivalent of water, and 4 primes of bi-carburetted hydrogen gas; in other words, ether contains for 1 prime of water, once as much olefiant gas as alcohol, and its prime equivalent is therefore 468·15 to oxygen 100. By my analysis, as published in the Phil. Trans. for 1822, ether is composed of oxygen 27·10; hydrogen 13·3; and carbon 59·6 in 100 parts. The density of my ether was 0·700. One volume of vapour of ether consists of one volume of aqueous vapour and two volumes of olefiant gas (bi-carburetted hydrogen,) while alcohol consists of two volumes of each.

There are two methods of preparing it; by the first, the whole quantity of acid and alcohol are mixed at once, and directly subjected to distillation; by the second, the alcohol is admitted, in a slender streamlet, into a body of acid previously mixed with a little alcohol, and heated to 220° Fahr.

1. Mix equal weights of alcohol at spec. grav. 0·830, and sulphuric acid at 1·842, by introducing the former into a large tubulated retort, giving it a whirling motion, so that the alcohol may revolve round a central conical cavity. Into this species of whirlpool the acid is to be slowly poured. The mixture, which becomes warm, is to be forthwith distilled by attaching a spacious receiver to the retort, and applying the heat of a sand-bath. The formation of ether takes place only at a certain temperature. If the contents of the retort be allowed to cool, and be then slowly heated in a water bath, alcohol alone will come over for some time without ether, till the mixture acquires theproper degree of heat. The first receiver should be a globe, with a tube proceeding from its bottom, into a second receiver, of a cylindric shape, surrounded with ice-cold water. The joints must be well secured by lutes, after the expanded air has been allowed to escape. The liquid in the retort should be kept in a steady state of bullition. The ether, as long as it is produced, condenses in the balloon and neck of the receiver in striæ; when these disappear the process is completed. The retort must now be removed from the sand; otherwise it would become filled with white fumes containing sulphurous acid, and denser striæ would flow over, which would contaminate the light product with a liquid called sweet oil of wine.

The theory of etherification demonstrates that when strong sulphuric acid is mixed with alcohol, there is formed, on the one hand, a more aqueous sulphuric acid, and, on the other, sulphovinic acid. When this mixture is made to boil, the sulphovinic acid is decomposed, its dihydrate of carbon combines with the alcohol, and constitutes ether; while the proportion of sulphovinic acid progressively diminishes. Mr. Hennell, of the Apothecaries’ Hall, first explained these phenomena, and he was confirmed in his views by the interesting researches of Serullas. The acid left in the retort is usually of a black colour, and may be employed to convert into ether half as much alcohol again; an experiment which may be repeated several times in succession.

The most profitable way of manufacturing ether has been pointed out by Boullay. It consists in letting the alcohol drop in a slender stream into the acid, previously heated to the etherifying temperature. If the acid in this case were concentrated to 1·846, the reaction would be too violent, and the ether would be transformed into bicarburetted hydrogen (dihydrate of carbon.) It is therefore necessary to dilute the acid down to the density of 1·780; but this dilution may be preferably effected with alcohol instead of water, by mixing three parts of the strongest acid with 2 of alcohol, specific gravity 0·830, and distilling off a portion of the ether thereby generated; after which the stream of alcohol is to be introduced into the tubulure of the retort through a small glass tube plunged into the mixture; this tube being the prolongation of a metallic syphon, whose shorter leg dips into a bottle filled with the alcohol. The longer leg is furnished with a stop-cock, for regulating at pleasure the alcoholic streamlet. The distilled vapours should be transmitted through a worm of pure tin surrounded by cold water, and the condensed fluid received in a glass bottle. The quantity of alcohol which can be thus converted into ether by a given weight of sulphuric acid, has not hitherto been accurately determined; but it is at least double. In operating in this way, neither sulphurous acid, nor sweet oil of wine is generated, while the residuary liquid in the retort continues limpid and of a merely brownish yellow colour. No sulphovinic acid is formed, and according to the experiments of Geiger, the proportion of ether approaches to what theory shows to be the maximum amount. In fact 57 parts of alcohol of 0·83 sp. grav. being equivalent to 46·8 parts of anhydrous alcohol, yield according to Geiger, 331⁄2parts of ether; and by calculation, they should yield 371⁄4.

The ether of the first distillation is never pure, but always contains a certain quantity of alcohol. The density of that product is usually 0·78, and if prepared by the first of the above methods, contains besides alcohol, pretty frequently sulphurous acid, and sweet oil of wine, impurities from which it must be freed. Being agitated with its bulk of milk of lime, both the acid and the alcohol are removed at the same time; and if it be then decanted and agitated, first with its bulk of water, next decanted into a retort containing chloride of calcium in coarse powder and distilled, one third of perfectly pure ether may be drawn over. Gay Lussac recommends to agitate the ether, first with twice its volume of water, to mix it, and leave it in contact with powdered unslaked lime for 12 or 14 hours, and then to distil off one third of pure ether. The remaining two thirds consist of ether containing a little alcohol. If in preparing ether by Boullay’s method, the alcohol be too rapidly introduced, much of this liquid will come over unchanged. If in this state the ether be shaken with water, a notable quantity of it will be absorbed, because weak alcohol dissolves it very copiously. The above product should therefore be re-distilled, and the first half that comes over may be considered as ether, and treated with water and lime. The other half must be exposed afresh to the action of sulphuric acid.

Pure ether possesses the following properties. It is limpid, of spec. grav. 0·713, or 0·715 at 60°; has a peculiar penetrating strong smell; a taste at first acrid, burning, sweetish, and finally cooling. It has neither an acid nor alkaline reaction; is a non-conductor of electricity, and refracts light strongly. It is very volatile, boiling at 96° or 97° F., and produces by its evaporation a great degree of cold. At the temperature of 62·4, the vapour of ether balances a column of mercury 15 inches high, or half the weight of the atmosphere. When ether is cooled to -24° F. it begins to crystallize in brilliant white plates, and at -47° it becomes a white crystalline solid. When vapour of ether is made to traverse a red hot porcelain tube, it deposits within it one half per cent. of charcoal, and there are condensed in the receiver one and two thirdsper cent. of a brown oil, partly in crystalline scales, and partly viscid. The crystalline portion is soluble in alcohol, but the viscid only in ether. The remainder of the decomposed ether consists of bi-carburetted hydrogen gas, tetrahydric carburet, carbonic oxide gas, and one per cent. at most of gaseous carbonic acid.

Ether takes fire readily, even at some distance from a flame, and it should not therefore be poured from one vessel to another in the neighbourhood of a lighted candle. It may be likewise set on fire by the electric spark. It burns all away with a bright fuliginous flame. When the vapour of ether is mixed with 10 times its volume of oxygen, it burns with a violent explosion, absorbs 6 times its bulk of oxygen, and produces 4 times its volume of carbonic acid gas.

Ether alters gradually with contact of air; absorbing oxygen, and progressively changing into acetic acid and water. This conversion takes place very rapidly when the ether is boiled in an open vessel, while the acid enters into a new combination forming acetic ether. Ether should be preserved in bottles perfectly full and well corked, and kept in a cool place, otherwise it becomes sour, and is destroyed. It contains in this state 15 per cent. of its bulk of azote, but no oxygen gas, as this has combined with its elements. Ether is composed of oxygen 21·24; hydrogen 13·85; carbon 65·05. This composition may be represented by 1 prime equivalent of water, and 4 primes of bi-carburetted hydrogen gas; in other words, ether contains for 1 prime of water, once as much olefiant gas as alcohol, and its prime equivalent is therefore 468·15 to oxygen 100. By my analysis, as published in the Phil. Trans. for 1822, ether is composed of oxygen 27·10; hydrogen 13·3; and carbon 59·6 in 100 parts. The density of my ether was 0·700. One volume of vapour of ether consists of one volume of aqueous vapour and two volumes of olefiant gas (bi-carburetted hydrogen,) while alcohol consists of two volumes of each.

ETHER, ACETIC, is used to flavour silent corn spirits in making imitation brandy. It may be prepared by mixing 20 parts of acetate of lead, 10 parts of alcohol, and 111⁄2of concentrated sulphuric acid; or 16 of the anhydrous acetate, 5 of the acid, and 41⁄2of absolute alcohol; distilling the mixture in a glass retort into a very cold receiver, agitating along with weak potash lye the liquor which comes over, decanting the supernatant ether, and rectifying it by re-distillation over magnesia and ground charcoal.Acetic ether is a colourless liquid of a fragrant smell and pungent taste, of spec. grav. 0·866 at 45° F., boiling at 166° F, burning with a yellowish flame, and disengaging fumes of acetic acid. It is soluble in 8 parts of water.Acetic ether may be economically made with 3 parts of acetate of potash, 3 of very strong alcohol, and 2 of the strongest sulphuric acid, distilled together. The first product must be re-distilled along with one fifth of its weight of sulphuric acid; as much ether will be obtained as there was alcohol employed.

Acetic ether is a colourless liquid of a fragrant smell and pungent taste, of spec. grav. 0·866 at 45° F., boiling at 166° F, burning with a yellowish flame, and disengaging fumes of acetic acid. It is soluble in 8 parts of water.

Acetic ether may be economically made with 3 parts of acetate of potash, 3 of very strong alcohol, and 2 of the strongest sulphuric acid, distilled together. The first product must be re-distilled along with one fifth of its weight of sulphuric acid; as much ether will be obtained as there was alcohol employed.

ETHIOPS, is the absurd name given by the alchemists to certain black metallic preparations. Martial ethiops was the black oxide of iron; mineral ethiops, the black sulphuret of mercury; and ethiopsper se, the black oxide of mercury.

EVAPORATION, (Eng. and Fr.;Abdampfen;Abdunsten, Germ.) is the process by which any substance is converted into, and carried off in, vapour. Though ice, camphor, and many other solids evaporate readily in dry air, I shall consider, at present, merely the vaporization of water by heat artificially applied.The vapour of water is an elastic fluid, whose tension and density depend upon the temperature of the water with which it is in contact. Thus the vapour rising from water heated to 165° F. possesses an elastic force capable of supporting a column of mercury 10·8 high; and its density is such that 80 cubic feet of such vapour contain one pound weight of water; whereas 321⁄2cubic feet of steam of the density corresponding to a temperature of 212° and a pressure of 30 inches of mercury, weigh one pound. When the temperature of the water is given, the elasticity and specific gravity of the vapour emitted by it, may be found.Since the vapour rises from the water only in virtue of the elasticity due to its gaseous nature, it is obvious that no more can be produced, unless what is already incumbent upon the liquid have its tension abated, or be withdrawn by some means. Suppose the temperature of the water to be midway between freezing and boiling, viz. 122° Fahr., as also that of the air in contact with it, to be the same but replete with moisture, so that its interstitial spaces are filled with vapour of corresponding elasticity and specific gravity with that given off by the water, it is certain that no fresh formation of vapour can take place in these circumstances. But the moment a portion of vapour is allowed to escape, or is drawn off by condensation to another vessel, an equivalent portion of vapour will be immediately exhaled from the water.The pressure of the air and of other vapours upon the surface of water in an open vessel, does not prevent evaporation of the liquid; it merely retards its progress. Experience shows that the space filled with an elastic fluid, as air or other gaseous body, is capable of receiving as much aqueous vapour as if it were vacuous, only the repletion of thatspace with the vapour proceeds more slowly in the former predicament than in the latter, but in both cases it arrives eventually at the same pitch. Dr. Dalton has very ingeniously proved, that the particles of aeriform bodies present no permanent obstacle to the introduction of a gaseous atmosphere of another kind among them, but merely obstruct its diffusion momentarily, as if by a species of friction. Hence, exhalation at atmospheric temperatures is promoted by the mechanical diffusion of the vapours through the air with ventilating fans or chimney draughts; though under brisk ebullition, the force of the steam readily overcomes that mechanical obstruction.The quantities of water evaporated under different temperatures in like times, are proportional to the elasticities of the steam corresponding to these temperatures. A vessel of boiling water exposing a square foot of surface to the fire, evaporates 725 grains in the minute; the elasticity of the vapour is equivalent to 30 inches of mercury. To find the quantity that would be evaporated from the same surface per minute at a heat of 88° F. At this temperature the steam incumbent upon water is capable of supporting 1·28 inch of mercury; whence the rule of proportion is 30 : 1·28 ∷ 725 : 30·93; showing that about 31 grains of water would be evaporated in the minute. If the air contains already some aqueous vapour, as it commonly does, then the quantity of evaporation will be proportional to the difference between the elastic force of that vapour, and what rises from the water.Suppose the air to be in the hygrometric state denoted by 0·38 of an inch of mercury, then the above formula will become: 30 : 1·28 - 0·38 ∷ 725 : 21·41; showing that not more than 211⁄2grains would be evaporated per minute under these circumstances.The elastic tension of the atmospheric vapour is readily ascertained by the old experiment of Le Roi, which consists in filling a glass cylinder (a narrow tumbler for example) with cool spring water, and noting its temperature at the instant it becomes so warm that dew ceases to be deposited upon it. This temperature is that which corresponds to the elastic tension of the atmospheric vapour. SeeVapour, Table of.Whenever the elasticity of the vapour, corresponding to the temperature of the water, is greater than the atmospheric pressure, the evaporation will take place not only from its surface, but from every point in its interior; the liquid particles throughout the mass assuming the gaseous form, as rapidly as they are actuated by the caloric, which subverts the hydrostatic equilibrium among them, to constitute the phenomena of ebullition. This turbulent vaporization takes place at any temperature, even down to the freezing point, provided the pneumatic pressure be removed from the liquid by the air pump, or any other means. Ebullition always accelerates evaporation, as it serves to carry off the aqueous particles not simply from the surface, but from the whole body of the water.The vapours, exhaled from a liquid at any temperature, contain more heat than the fluid from which they spring; and they cease to form whenever the supply of heat into the liquid is stopped. Any volume of water requires for its conversion into vapourfive and a half timesas much heat as is sufficient to heat it from the freezing to the boiling temperature. The heat, in the former case, seems to be absorbed, being inappreciable by the thermometer; for steam is no hotter than the boiling water from which it rises. It has been therefore calledlatent heat; in contradistinction to that perceived by the touch and measured by the thermometer, which is calledsensible heat. The quantity of heat absorbed by one volume of water in its conversion into steam, is about 1000° Fahr.; it would be adequate to heat 1000 volumes of water, one degree of the same scale; or to raise one volume of boiling water, confined in a non-conducting vessel, to 1180°. Were the vessel charged with water so heated, opened, it would be instantaneously emptied by vaporization, since the whole caloric equivalent to its constitution as steam, is present. When, upon the other hand, steam is condensed by contact with cold substances, so much heat is set free as is capable of heating five and a half times its weight of water, from 32° to 212° F. If the supply of heat to a copper be uniform, five hours and a half will be required to drive off its water in steam, provided one hour was taken in heating the water, from the freezing to the boiling pitch, under the atmospherical pressure.Equal weights of vapour of any temperature contain equal quantities of heat; for example, the vapour exhaled from one pound of water, at 77° F., absorbs during its formation, and will give out in its condensation, as much heat as the steam produced by one pound of water, at 212° F. The first portion of vapour with a tension = 30 inches, occupies a space of 27·31 cubic feet; the second, with a tension of 0·92 inch, occupies a space of 890 cubic feet.[29]Suppose that these 890 volumes were to be compressed into 27·31 in a cylinder capable of confining the heat, the temperature of the vapour would rise from 77° to 212°, in virtue of the condensation, as air becomes so hot by compressionin a syringe, as to igniteamadou. The latent heat of steam at 212° F. is 1180° - 180 = 1000; that of vapour, at 77°, is 1180 - 45 = 1135°; so that, in fact, the lower the temperature at which the vapour is exhaled, the greater is its latent heat, as Joseph Black and James Watt long ago proved by experiments upon distillation and the steam engine.[29]One pound avoirdupois of water contains 27·72 cubic inches; one cubic inch of water forms 1696 cubic inches of steam at 212° F.: therefore one pound of water will form 27·31 cubic feet of such steam: and 0·92 : 30 ∷ 27·31 : 890 cubic feet.From the preceding researches it follows, that evaporation may be effected upon two different plans:—1. Under the ordinary pressure of the atmosphere; and that either,A, by external application of heat to boilers, witha, an open fire;b, steam;c, hot liquidmedia.B, by evaporation with air;a, at the ordinary temperature of the atmosphere;b, by currents of warm air.2. Under progressively lower degrees of pressure than the atmospheric, down to evaporation in as perfect a vacuum as can be made.It is generally affirmed, that a thick metallic boiler obstructs the passage of the heat through it so much more than a thin one, as to make a considerable difference in their relative powers of evaporating liquids. Many years ago, I made a series of experiments upon this subject. Two cylindrical copper pans, of equal dimensions, were provided; but the metal of the one was twelve times thicker than that of the other. Each being charged with an equal volume of water, and placed either upon the same hot plate of iron, or immersed, to a certain depth, in a hot solution of muriate of lime, I found that the ebullition was greatly more vigorous in the thick than in the thin vessel, which I ascribed to the conducting substance up the sides, above the contact of the source of heat, being 12 times greater in the former case than in the latter.If the bottom of a pan, and the portions of the sides, immersed in a hot fluid medium, solution of caustic potash or muriate of lime, for example, be corrugated, so as to contain a double expanse of metallic surface, that pan will evaporate exactly double the quantity of water, in a given time, which a like pan, with smooth bottom and sides, will do immersed equally deep in the same bath. If the corrugations contain three times the quantity of metallic surface, the evaporation will be threefold in the above circumstances. But if the pan, with the same corrugated bottom and sides, be set over a fire, or in an oblong flue, so that the current of flame may sweep along the corrugations, it will evaporate no more water from its interior than a smooth pan of like shape and dimensions placed alongside in the same flue, or over the same fire. This curious fact I have verified upon models constructed with many modifications. Among others, I caused a cylindrical pan, 10 inches diameter, and 6 inches deep, to be made of tin-plate, with a vertical plate soldered across its diameter; dividing it into two equal semi-cylindrical compartments. One of these was smooth at the bottom, the other corrugated; the former afforded as rapid an evaporation over the naked fire as the latter, but it was far outstripped by its neighbour when plunged into the heated liquid medium.If a shallow pan of extensive surface be heated by a subjacent fire, by a liquid medium, or a series of steam pipes upon its bottom; it will give off less vapour in the same time when it is left open, than when partially covered. In the former case, the cool incumbent air precipitates by condensation a portion of the steam, and also opposes considerable mechanical resistance to the diffusion of the vaporous particles. In the latter case, as the steam issues with concentrated force and velocity from the contracted orifice, the air must offer less proportional resistance, upon the known hydrostatic principle of the pressure being as the areas of the respective bases, in communicating vessels.In evaporating by surfaces heated with ordinary steam, it must be borne in mind that a surface of 10 square feet will evaporate fully one pound of water per minute, or 725 × 10 = 7250 gr., the same as over a naked fire; consequently the condensing surface must be equally extensive. Suppose that the vessel is to receive of water 2500 libs, which corresponds to a boiler 5 feet long, 4 broad, and 2 deep, being 40 cubic feet by measure, and let there be laid over the bottom of this vessel 8 connected tubes, each 5 inches in diameter and 5 feet long, possessing therefore a surface of 5 feet square. If charged with steam, they will cause the evaporation of half a pound of water per minute. The boiler to supply the steam for this purpose must expose a surface of 5 square feet to the fire. It has been proved experimentally that 10 square feet surface of thin copper can condense 3 libs of steam per minute, with a difference of temperature of 90 degrees Fahr. In the above example, 10 square feet evaporate 1 lib. of water per minute; the temperature of the evaporating fluid being 212° F., consequently 3 : 1 ∷ 90 :903. During this evaporation the difference of the temperature is therefore = 30°. Consequently the heat of the steam placed in connection with the interior of the boiler, to produce the calculated evaporation should be, 212 + 30 = 242°, corresponding to an elastic force of 53·6 inches of mercury. Were the temperature ofthe steam only 224, the same boiler in the same time would produce a diminished quantity of steam, in the proportion of 12 to 30; or to produce the same quantity the boiler or tubular surface should be enlarged in the proportion of 30 to 12. In general, however, steam boilers employed for this mode of evaporation are of such capacity as to give an unfailing supply of steam.Evaporation in vacuoI shall now illustrate by some peculiar forms of apparatus, different systems of evaporation.Fig.381.explains the principles of evaporating in vacuo.A Brepresents a pan or kettle charged with the liquor to be evaporated. The somewhat wide orificec, secured with a screw-plug, serves to admit the hand for the purpose of cleaning it thoroughly out when the operation is finished;his the pipe of communication with the steam boiler;bis a tube prolonged and then bent down with its end plunged into the liquor to be evaporated, contained in the charging back, (not shown in the figure).His a glass tube communicating with the vacuum pan at the top and bottom, to shew by the height of the column the quantity of liquid within. The eduction evaporating pipecis provided with a stop-cock to cut off the communication when required.iis a tube for the discharge of the air and the water from the steam-case or jacket; the refrigeratorEis best formed of thin copper tubes about 1 inch in diameter, arranged zig-zag or spirally like the worm of a still in a cylinder. The small air-tight condenserF, connected with the efflux pipefof the refrigerator, is furnished below with a discharge cockg, and surrounded by a cooling case, for the collection of the water condensed by the refrigerator. In its upper part there is a tubek, also furnished with a cock, which communicates with the steam boiler, and through which the panA Bis heated.The operation of this apparatus is as follows: after opening the cocksC,f,g, and before admitting the cold water into the condenserE, the cock of the pipekis opened, in order that by injecting steam it may expel the included air; after which the cockskandgare to be shut. The water must now be introduced into the condenser, and the cockbopened, whereon the liquid to be evaporated rises from the charging back, through the tubeb, and replenishes the vacuum pan to the proper height, as shown by the register glass tubeH. Whenever the desired evaporation or concentration is effected, the cockCmust be closed, the pipekopened, so as to fill the pan with steam, and then the efflux cockais opened to discharge the residuary liquor. By shutting the cocksaandk, and opening the cockb, the pan will charge itself afresh with liquor, and the operation will be begun anew, afterbhas been shut andCopened.The contents of the close water cisternF, may be drawn off during each operation. For this purpose, the cockfmust first be shut, the cold water is to be then run out of the condenserG, andkandgare to be opened. The steam entering bykmakes the water flow, but whenever the steam itself issues from the cockg, this orifice must be immediately shut, the cockfopened, and the cold water again introduced, whereupon the condensed water that had meanwhile collected in the under part of the refrigerator, flows off into the condenser vesselF. Since some air always enters with the liquorsucked into the pan, it must be removed at the time of drawing off the water from the two condensers, by driving steam through the apparatus. This necessity will be less urgent if the liquor be made to boil before being introduced into the vacuum pan.Such an apparatus may be modified in size and arrangement to suit the peculiar object in view, when it will be perfectly adapted for the concentration of extracts of every kind, as well as saline solutions containing vegetable acids or alkalis. The interior vessel ofA Bshould be made of tinned or plated copper. For an account of Howard’s vacuum pan, made upon the same principle, seeSugar.When a boiler is set over a fire, its bottom should not be placed too near the grate, lest it refrigerate the flame, and prevent that vivid combustion of the fuel essential to the maximum production of heat by its means. The evil influence of leaving too little room between the grate and the copper may be illustrated by a very simple experiment. If a small copper or porcelain capsule containing water be held over the flame of a candle a little way above its apex, the flame will suffer no abatement of brightness or size, but will continue to keep the water briskly boiling. If the capsule be now lowered into the middle of the flame, this will immediately lose its brightness, becoming dull and smoky covering the bottom of the capsule with soot; and, owing to the imperfect combustion, though the water is now surrounded by the flame, its ebullition will cease.Fuel-efficient evaporating coppersFig.382.is a section of two evaporating coppersen suite, so mounted as to favour the full combustion of the fuel.Ais the hearth, in which wood or coal may be burned. For coal, the grate should be set higher and be somewhat smaller,ais the door for feeding the fire;d, an arch of fire-bricks over the hearth;c, a grate through which the ashes fall into the pit beneath, capable of being closed in front to any extent by a sliding doorb.BandCare two coppers encased in brickwork;fthe flue. At the end of the hearth nearm, where the fire plays first upon the copper, the sole is made somewhat lower and wider, to promote the spreading of the flame under the vessel. The second copper,C, receives the benefit of the waste heat; it may be placed upon a higher level, so as to discharge its concentrated liquor by a stop-cock or syphon into the first. When coals are burned for heating such boilers, the grate should be constructed as shown in the figure of thebrewing copper,page 116.Fig.383.represents a pan for evaporating liquids, which are apt, during concentration, to let fall crystals or other sediment. These would be injured either by the fire playing upon the bottom of the pan, or, by adhesion to it, they would allow the metal to get red hot, and in that state run every risk of being burnt or rent on the sudden intrusion of a little liquor through the incrustation. When large coppers have their bottoms planted in loam, so that the flame circulates in flues round their sides, they are said to becold-set.Evaporating panAis a pear-shaped pan, charged with the liquid to be evaporated; it is furnished with a dome cover, in which there is an opening with a flangef, for attaching a tube, to conduct the steam wherever it may be required.ais the fire-place;b, the ash-pit. The conical part terminates below in the tubeg, furnished with a stop-cock at its nozzleh. Through the tubec dc′, furnished above and below with the stop-cockscandc′, the liquid is run from thecharging back or reservoir. During the operation, the upper cockcis kept partially open, to replace the fluid as it evaporates; but the under cockc′is shut. The flame from the fire-place plays round the kettle in the spacee, and the smoke escapes downwards through the flueiinto the chimney. The lower cylindrical partg, remains thus comparatively cool, and collects the crystalline or other solid matter. After some time, the under stop-cockc′, upon the supply-pipe, is to be opened to admit some of the cold liquor into the cylindrical neck. That cock being again shut, the sediment settled, and the large stop-cock (a horizontal slide-valve would be preferable)hopened, the crystals are suffered to descend into the subjacent receiver; after which the stop-cockhis shut, and the operation is continued. A construction upon this principle is well adapted for heating dyeing coppers, in which the sediment should not be disturbed, or exposed to the action of the fire. The fire-place should be built as for thebrewing copper.Another evaporating panFig.384.represents an oblong evaporating pan, in which the flame, after beating along its bottom, turns up at its further end, plays back along its surface, and passes off into the chimney.Ais a rectangular vessel, from 10 to 15 feet long, 4 to 6 feet broad, and 1 or 11⁄2feet deep. The fire-bricks, upon which the pan rests, are so arranged as to distribute the flame equably along its bottom.

The vapour of water is an elastic fluid, whose tension and density depend upon the temperature of the water with which it is in contact. Thus the vapour rising from water heated to 165° F. possesses an elastic force capable of supporting a column of mercury 10·8 high; and its density is such that 80 cubic feet of such vapour contain one pound weight of water; whereas 321⁄2cubic feet of steam of the density corresponding to a temperature of 212° and a pressure of 30 inches of mercury, weigh one pound. When the temperature of the water is given, the elasticity and specific gravity of the vapour emitted by it, may be found.

Since the vapour rises from the water only in virtue of the elasticity due to its gaseous nature, it is obvious that no more can be produced, unless what is already incumbent upon the liquid have its tension abated, or be withdrawn by some means. Suppose the temperature of the water to be midway between freezing and boiling, viz. 122° Fahr., as also that of the air in contact with it, to be the same but replete with moisture, so that its interstitial spaces are filled with vapour of corresponding elasticity and specific gravity with that given off by the water, it is certain that no fresh formation of vapour can take place in these circumstances. But the moment a portion of vapour is allowed to escape, or is drawn off by condensation to another vessel, an equivalent portion of vapour will be immediately exhaled from the water.

The pressure of the air and of other vapours upon the surface of water in an open vessel, does not prevent evaporation of the liquid; it merely retards its progress. Experience shows that the space filled with an elastic fluid, as air or other gaseous body, is capable of receiving as much aqueous vapour as if it were vacuous, only the repletion of thatspace with the vapour proceeds more slowly in the former predicament than in the latter, but in both cases it arrives eventually at the same pitch. Dr. Dalton has very ingeniously proved, that the particles of aeriform bodies present no permanent obstacle to the introduction of a gaseous atmosphere of another kind among them, but merely obstruct its diffusion momentarily, as if by a species of friction. Hence, exhalation at atmospheric temperatures is promoted by the mechanical diffusion of the vapours through the air with ventilating fans or chimney draughts; though under brisk ebullition, the force of the steam readily overcomes that mechanical obstruction.

The quantities of water evaporated under different temperatures in like times, are proportional to the elasticities of the steam corresponding to these temperatures. A vessel of boiling water exposing a square foot of surface to the fire, evaporates 725 grains in the minute; the elasticity of the vapour is equivalent to 30 inches of mercury. To find the quantity that would be evaporated from the same surface per minute at a heat of 88° F. At this temperature the steam incumbent upon water is capable of supporting 1·28 inch of mercury; whence the rule of proportion is 30 : 1·28 ∷ 725 : 30·93; showing that about 31 grains of water would be evaporated in the minute. If the air contains already some aqueous vapour, as it commonly does, then the quantity of evaporation will be proportional to the difference between the elastic force of that vapour, and what rises from the water.

Suppose the air to be in the hygrometric state denoted by 0·38 of an inch of mercury, then the above formula will become: 30 : 1·28 - 0·38 ∷ 725 : 21·41; showing that not more than 211⁄2grains would be evaporated per minute under these circumstances.

The elastic tension of the atmospheric vapour is readily ascertained by the old experiment of Le Roi, which consists in filling a glass cylinder (a narrow tumbler for example) with cool spring water, and noting its temperature at the instant it becomes so warm that dew ceases to be deposited upon it. This temperature is that which corresponds to the elastic tension of the atmospheric vapour. SeeVapour, Table of.

Whenever the elasticity of the vapour, corresponding to the temperature of the water, is greater than the atmospheric pressure, the evaporation will take place not only from its surface, but from every point in its interior; the liquid particles throughout the mass assuming the gaseous form, as rapidly as they are actuated by the caloric, which subverts the hydrostatic equilibrium among them, to constitute the phenomena of ebullition. This turbulent vaporization takes place at any temperature, even down to the freezing point, provided the pneumatic pressure be removed from the liquid by the air pump, or any other means. Ebullition always accelerates evaporation, as it serves to carry off the aqueous particles not simply from the surface, but from the whole body of the water.

The vapours, exhaled from a liquid at any temperature, contain more heat than the fluid from which they spring; and they cease to form whenever the supply of heat into the liquid is stopped. Any volume of water requires for its conversion into vapourfive and a half timesas much heat as is sufficient to heat it from the freezing to the boiling temperature. The heat, in the former case, seems to be absorbed, being inappreciable by the thermometer; for steam is no hotter than the boiling water from which it rises. It has been therefore calledlatent heat; in contradistinction to that perceived by the touch and measured by the thermometer, which is calledsensible heat. The quantity of heat absorbed by one volume of water in its conversion into steam, is about 1000° Fahr.; it would be adequate to heat 1000 volumes of water, one degree of the same scale; or to raise one volume of boiling water, confined in a non-conducting vessel, to 1180°. Were the vessel charged with water so heated, opened, it would be instantaneously emptied by vaporization, since the whole caloric equivalent to its constitution as steam, is present. When, upon the other hand, steam is condensed by contact with cold substances, so much heat is set free as is capable of heating five and a half times its weight of water, from 32° to 212° F. If the supply of heat to a copper be uniform, five hours and a half will be required to drive off its water in steam, provided one hour was taken in heating the water, from the freezing to the boiling pitch, under the atmospherical pressure.

Equal weights of vapour of any temperature contain equal quantities of heat; for example, the vapour exhaled from one pound of water, at 77° F., absorbs during its formation, and will give out in its condensation, as much heat as the steam produced by one pound of water, at 212° F. The first portion of vapour with a tension = 30 inches, occupies a space of 27·31 cubic feet; the second, with a tension of 0·92 inch, occupies a space of 890 cubic feet.[29]Suppose that these 890 volumes were to be compressed into 27·31 in a cylinder capable of confining the heat, the temperature of the vapour would rise from 77° to 212°, in virtue of the condensation, as air becomes so hot by compressionin a syringe, as to igniteamadou. The latent heat of steam at 212° F. is 1180° - 180 = 1000; that of vapour, at 77°, is 1180 - 45 = 1135°; so that, in fact, the lower the temperature at which the vapour is exhaled, the greater is its latent heat, as Joseph Black and James Watt long ago proved by experiments upon distillation and the steam engine.

[29]One pound avoirdupois of water contains 27·72 cubic inches; one cubic inch of water forms 1696 cubic inches of steam at 212° F.: therefore one pound of water will form 27·31 cubic feet of such steam: and 0·92 : 30 ∷ 27·31 : 890 cubic feet.

From the preceding researches it follows, that evaporation may be effected upon two different plans:—

1. Under the ordinary pressure of the atmosphere; and that either,

A, by external application of heat to boilers, witha, an open fire;b, steam;c, hot liquidmedia.

B, by evaporation with air;a, at the ordinary temperature of the atmosphere;b, by currents of warm air.

2. Under progressively lower degrees of pressure than the atmospheric, down to evaporation in as perfect a vacuum as can be made.

It is generally affirmed, that a thick metallic boiler obstructs the passage of the heat through it so much more than a thin one, as to make a considerable difference in their relative powers of evaporating liquids. Many years ago, I made a series of experiments upon this subject. Two cylindrical copper pans, of equal dimensions, were provided; but the metal of the one was twelve times thicker than that of the other. Each being charged with an equal volume of water, and placed either upon the same hot plate of iron, or immersed, to a certain depth, in a hot solution of muriate of lime, I found that the ebullition was greatly more vigorous in the thick than in the thin vessel, which I ascribed to the conducting substance up the sides, above the contact of the source of heat, being 12 times greater in the former case than in the latter.

If the bottom of a pan, and the portions of the sides, immersed in a hot fluid medium, solution of caustic potash or muriate of lime, for example, be corrugated, so as to contain a double expanse of metallic surface, that pan will evaporate exactly double the quantity of water, in a given time, which a like pan, with smooth bottom and sides, will do immersed equally deep in the same bath. If the corrugations contain three times the quantity of metallic surface, the evaporation will be threefold in the above circumstances. But if the pan, with the same corrugated bottom and sides, be set over a fire, or in an oblong flue, so that the current of flame may sweep along the corrugations, it will evaporate no more water from its interior than a smooth pan of like shape and dimensions placed alongside in the same flue, or over the same fire. This curious fact I have verified upon models constructed with many modifications. Among others, I caused a cylindrical pan, 10 inches diameter, and 6 inches deep, to be made of tin-plate, with a vertical plate soldered across its diameter; dividing it into two equal semi-cylindrical compartments. One of these was smooth at the bottom, the other corrugated; the former afforded as rapid an evaporation over the naked fire as the latter, but it was far outstripped by its neighbour when plunged into the heated liquid medium.

If a shallow pan of extensive surface be heated by a subjacent fire, by a liquid medium, or a series of steam pipes upon its bottom; it will give off less vapour in the same time when it is left open, than when partially covered. In the former case, the cool incumbent air precipitates by condensation a portion of the steam, and also opposes considerable mechanical resistance to the diffusion of the vaporous particles. In the latter case, as the steam issues with concentrated force and velocity from the contracted orifice, the air must offer less proportional resistance, upon the known hydrostatic principle of the pressure being as the areas of the respective bases, in communicating vessels.

In evaporating by surfaces heated with ordinary steam, it must be borne in mind that a surface of 10 square feet will evaporate fully one pound of water per minute, or 725 × 10 = 7250 gr., the same as over a naked fire; consequently the condensing surface must be equally extensive. Suppose that the vessel is to receive of water 2500 libs, which corresponds to a boiler 5 feet long, 4 broad, and 2 deep, being 40 cubic feet by measure, and let there be laid over the bottom of this vessel 8 connected tubes, each 5 inches in diameter and 5 feet long, possessing therefore a surface of 5 feet square. If charged with steam, they will cause the evaporation of half a pound of water per minute. The boiler to supply the steam for this purpose must expose a surface of 5 square feet to the fire. It has been proved experimentally that 10 square feet surface of thin copper can condense 3 libs of steam per minute, with a difference of temperature of 90 degrees Fahr. In the above example, 10 square feet evaporate 1 lib. of water per minute; the temperature of the evaporating fluid being 212° F., consequently 3 : 1 ∷ 90 :903. During this evaporation the difference of the temperature is therefore = 30°. Consequently the heat of the steam placed in connection with the interior of the boiler, to produce the calculated evaporation should be, 212 + 30 = 242°, corresponding to an elastic force of 53·6 inches of mercury. Were the temperature ofthe steam only 224, the same boiler in the same time would produce a diminished quantity of steam, in the proportion of 12 to 30; or to produce the same quantity the boiler or tubular surface should be enlarged in the proportion of 30 to 12. In general, however, steam boilers employed for this mode of evaporation are of such capacity as to give an unfailing supply of steam.

Evaporation in vacuo

I shall now illustrate by some peculiar forms of apparatus, different systems of evaporation.Fig.381.explains the principles of evaporating in vacuo.A Brepresents a pan or kettle charged with the liquor to be evaporated. The somewhat wide orificec, secured with a screw-plug, serves to admit the hand for the purpose of cleaning it thoroughly out when the operation is finished;his the pipe of communication with the steam boiler;bis a tube prolonged and then bent down with its end plunged into the liquor to be evaporated, contained in the charging back, (not shown in the figure).His a glass tube communicating with the vacuum pan at the top and bottom, to shew by the height of the column the quantity of liquid within. The eduction evaporating pipecis provided with a stop-cock to cut off the communication when required.iis a tube for the discharge of the air and the water from the steam-case or jacket; the refrigeratorEis best formed of thin copper tubes about 1 inch in diameter, arranged zig-zag or spirally like the worm of a still in a cylinder. The small air-tight condenserF, connected with the efflux pipefof the refrigerator, is furnished below with a discharge cockg, and surrounded by a cooling case, for the collection of the water condensed by the refrigerator. In its upper part there is a tubek, also furnished with a cock, which communicates with the steam boiler, and through which the panA Bis heated.

The operation of this apparatus is as follows: after opening the cocksC,f,g, and before admitting the cold water into the condenserE, the cock of the pipekis opened, in order that by injecting steam it may expel the included air; after which the cockskandgare to be shut. The water must now be introduced into the condenser, and the cockbopened, whereon the liquid to be evaporated rises from the charging back, through the tubeb, and replenishes the vacuum pan to the proper height, as shown by the register glass tubeH. Whenever the desired evaporation or concentration is effected, the cockCmust be closed, the pipekopened, so as to fill the pan with steam, and then the efflux cockais opened to discharge the residuary liquor. By shutting the cocksaandk, and opening the cockb, the pan will charge itself afresh with liquor, and the operation will be begun anew, afterbhas been shut andCopened.

The contents of the close water cisternF, may be drawn off during each operation. For this purpose, the cockfmust first be shut, the cold water is to be then run out of the condenserG, andkandgare to be opened. The steam entering bykmakes the water flow, but whenever the steam itself issues from the cockg, this orifice must be immediately shut, the cockfopened, and the cold water again introduced, whereupon the condensed water that had meanwhile collected in the under part of the refrigerator, flows off into the condenser vesselF. Since some air always enters with the liquorsucked into the pan, it must be removed at the time of drawing off the water from the two condensers, by driving steam through the apparatus. This necessity will be less urgent if the liquor be made to boil before being introduced into the vacuum pan.

Such an apparatus may be modified in size and arrangement to suit the peculiar object in view, when it will be perfectly adapted for the concentration of extracts of every kind, as well as saline solutions containing vegetable acids or alkalis. The interior vessel ofA Bshould be made of tinned or plated copper. For an account of Howard’s vacuum pan, made upon the same principle, seeSugar.

When a boiler is set over a fire, its bottom should not be placed too near the grate, lest it refrigerate the flame, and prevent that vivid combustion of the fuel essential to the maximum production of heat by its means. The evil influence of leaving too little room between the grate and the copper may be illustrated by a very simple experiment. If a small copper or porcelain capsule containing water be held over the flame of a candle a little way above its apex, the flame will suffer no abatement of brightness or size, but will continue to keep the water briskly boiling. If the capsule be now lowered into the middle of the flame, this will immediately lose its brightness, becoming dull and smoky covering the bottom of the capsule with soot; and, owing to the imperfect combustion, though the water is now surrounded by the flame, its ebullition will cease.

Fuel-efficient evaporating coppers

Fig.382.is a section of two evaporating coppersen suite, so mounted as to favour the full combustion of the fuel.Ais the hearth, in which wood or coal may be burned. For coal, the grate should be set higher and be somewhat smaller,ais the door for feeding the fire;d, an arch of fire-bricks over the hearth;c, a grate through which the ashes fall into the pit beneath, capable of being closed in front to any extent by a sliding doorb.BandCare two coppers encased in brickwork;fthe flue. At the end of the hearth nearm, where the fire plays first upon the copper, the sole is made somewhat lower and wider, to promote the spreading of the flame under the vessel. The second copper,C, receives the benefit of the waste heat; it may be placed upon a higher level, so as to discharge its concentrated liquor by a stop-cock or syphon into the first. When coals are burned for heating such boilers, the grate should be constructed as shown in the figure of thebrewing copper,page 116.

Fig.383.represents a pan for evaporating liquids, which are apt, during concentration, to let fall crystals or other sediment. These would be injured either by the fire playing upon the bottom of the pan, or, by adhesion to it, they would allow the metal to get red hot, and in that state run every risk of being burnt or rent on the sudden intrusion of a little liquor through the incrustation. When large coppers have their bottoms planted in loam, so that the flame circulates in flues round their sides, they are said to becold-set.

Evaporating pan

Ais a pear-shaped pan, charged with the liquid to be evaporated; it is furnished with a dome cover, in which there is an opening with a flangef, for attaching a tube, to conduct the steam wherever it may be required.ais the fire-place;b, the ash-pit. The conical part terminates below in the tubeg, furnished with a stop-cock at its nozzleh. Through the tubec dc′, furnished above and below with the stop-cockscandc′, the liquid is run from thecharging back or reservoir. During the operation, the upper cockcis kept partially open, to replace the fluid as it evaporates; but the under cockc′is shut. The flame from the fire-place plays round the kettle in the spacee, and the smoke escapes downwards through the flueiinto the chimney. The lower cylindrical partg, remains thus comparatively cool, and collects the crystalline or other solid matter. After some time, the under stop-cockc′, upon the supply-pipe, is to be opened to admit some of the cold liquor into the cylindrical neck. That cock being again shut, the sediment settled, and the large stop-cock (a horizontal slide-valve would be preferable)hopened, the crystals are suffered to descend into the subjacent receiver; after which the stop-cockhis shut, and the operation is continued. A construction upon this principle is well adapted for heating dyeing coppers, in which the sediment should not be disturbed, or exposed to the action of the fire. The fire-place should be built as for thebrewing copper.

Another evaporating pan

Fig.384.represents an oblong evaporating pan, in which the flame, after beating along its bottom, turns up at its further end, plays back along its surface, and passes off into the chimney.Ais a rectangular vessel, from 10 to 15 feet long, 4 to 6 feet broad, and 1 or 11⁄2feet deep. The fire-bricks, upon which the pan rests, are so arranged as to distribute the flame equably along its bottom.

EUDIOMETER, is the name of any apparatus subservient to the chemical examination of the atmospheric air. It means ameasure of purity, but it is employed merely to determine the proportion of oxygen which it may contain. The explosive eudiometer, in which about two measures of hydrogen are introduced into a graduated glass tube, containing five measures of atmospheric air, and an electric spark is passed across the mixture, is the best of all eudiometers; and of these the syphon form, proposed by me in a paper published by the Royal Society of Edinburgh in 1819, is probably the surest and most convenient. Volta’s explosive eudiometer as made in Paris, costs 3 guineas; mine may be had nicely graduated for 6 or 8 shillings.

EXPANSION (Eng. and Fr.;Ausdehnung, Germ.), is the increase of bulk experienced by all bodies when heated, unless a change of chemical texture takes place, as in the case of clays in the potter’s kiln.Table I.exhibits the linear expansion of several solids by an increase of temperature from 32° to 212° Fahr.;Table II.exhibits the expansion in bulk of certain liquids.TABLE I.—Linear Dilatation of Solids by Heat.Dimensions which a bar takes at 212°, whose length at 32° is 1·000000.Substances.Authority.DilatationinDecimals.Dilatationin VulgarFractions.Glass tube,Smeaton,1·00083333Glasdo.Roy,1·00077615Glasdo.Deluc’s mean,1·000828001⁄1116Glasdo.Dulong and Petit,1·000861301⁄1148Glasdo.Lavoisier and Laplace,1·000811661⁄1122Plate glass,do. do.1·0008908901⁄1142Pldo. crown glass,do. do.1·000875721⁄1114Pldo.crowdo.do. do.1·000897601⁄1090Pldo.crowdo.do. do.1·00091751Pldo. rod,Roy,1·00080787Deal,Roy, as glass,—Platina,Borda,1·00085655Pldo.Dulong and Petit,1·000884201⁄1131Pldo.Troughton,1·00099180Pldo.naand glass,Berthoud,1·00110000Palladium,Wollaston,1·00100000Antimony,Smeaton,1·00108300Cast-iron prism,Roy,1·00110940Cast-iron,Lavoisier, by Dr Young1·00111111Steel,Troughton,1·00118990Steel rod,Roy,1·00114470Blistered Steel,Phil. Trans. 1795, 428,1·00112500Blistedo.Smeaton,1·00115000Steel not tempered,Lavoisier and Laplace,1·001078751⁄927Stdo. do.tedo.do. do.1·001079561⁄926Stdo. tempered yellow,do. do.1·00136900Stdo.temdo.ed yedo.do. do.1·00138600Stdo.temdo.edat a higher heat,do. do.1·001239561⁄807Steel,Troughton,1·00118980Hard Steel,Smeaton,1·00122500Annealed steel,Muschenbroek,1·00122000Tempered steel,do.1·00137000Iron,Borda,1·00115600Ido.Smeaton,1·00125800Soft iron, forged,Lavoisier and Laplace,1·00122045Round iron, wire drawn,do. do.1·00123504Iron wire,Troughton,1·00144010Iron,Dulong and Petit,1·001182031⁄846Bismuth,Smeaton,1·00139200Annealed gold,Muschenbroek,1·00146000Gold,Ellicot, by comparison,1·00150000Gdo. procured by parting,Lavoisier and Laplace,1·001466061⁄682Gdo. Paris standard, unannealed,do. do.1·001551551⁄645Gdo.Paris sdo.dardannealed,do. do.1·001513611⁄661Copper,Muschenbroek,1·0019100Codo.Lavoisier and Laplace,1·001722441⁄581Codo.do. do.1·001712221⁄584Codo.Troughton,1·00191880Codo.Dulong and Petit,1·001718211⁄582Brass,Borda,1·00178300Bdo.Lavoisier and Laplace,1·00186671Bdo.do. do.1·00188971Brass scale, supposed from Hamburg,Roy,1·00185540Cast brass,Smeaton,1·00187500English plate-brass, in rod,Roy,1·00189280Endo.h plado.rass,in a trough form,do.1·00189490Brass,Troughton,1·00191880Brass wire,Smeaton,1·00193000Brass,Muschenbroek,1·00216000Copper 8, tin 1,Smeaton,1·00181700Silver,Herbert,1·00189000Sido.Ellicot, by comparison,1·0021000Sido.Muschenbroek,1·00212000Sido.r,of cupel,Lavoisier and Laplace,1·001909741⁄524Sido.r,Paris standard,do. do.1·001908681⁄524Silver,Troughton,1·0020826Brass 16, tin 1,Smeaton,1·00190800Speculum metal,do.1·00193300Spelter solder; brass 2, zinc 1,do.1·00205800Malacca tin,Lavoisier and Laplace,1·001937651⁄516Tin from Falmouth,do. do.1·002172981⁄462Fine pewter,Smeaton,1·00228300Grain tin,do.1·00248300Tin,Muschenbroek,1·00284000Soft solder; lead 2, tin 1,Smeaton,1·00250800Zinc 8, tin 1, a little hammered,do.1·00269200Lead.Lavoisier and Laplace,1·002848361⁄351Ldo.Smeaton,1·00286700Zinc,do.1·00294200Zinc, hammered out1⁄2inch per foot,do.1·00301100Glass, from 32°, to 212°,Dulong and Petit,1·000861301⁄1161Gdo. from 212°, to 392°,do. do.1·000918271⁄1089Gdo. from 392°, to 572°,do. do.1·001011141⁄987The last two measurements by an air thermometer.TABLE II.Expansion of certain Liquids by being Heated from 32° to 212°.Substances.Authority.ExpansioninDecimals.Expansionin VulgarFractions.Mercury,Dulong and Petit.0·018018001⁄55·5Medo.ry,in glass,do. do.0·015432001⁄65Water, from its maximum density,Kirwan.0·043321⁄23Muriatic acid (sp. gr. 1·137),Dalton.0·06001⁄17Nitric acid (sp. gr. 1·40),do.0·11001⁄9Sulphuric acid (sp. gr. 1·85),do.0·06001⁄17Alcohol (to its boiling point)?do.0·11001⁄9Water,do.0·04601⁄22Water, saturated with common salt,do.0·05001⁄20Sulphuric ether (to its boiling point)?do.0·07001⁄14Fixed oils,do.0·08001⁄12·5Oil of turpentine,do.0·07001⁄14If the density of water at 39° be called1·00000,If the densityat 212° it becomes0·9548,If the densityand its volume has increased to1·04734;If the densityat 77° it becomes0·9973587,If the densityand its volume has increased to only1·00265,which, though one fourth of the whole range of temperature, is only1⁄18of the total expansion.If the densityWater at 60° F. has a specific gravity of0·9991953,If the densityand has increased in volume from 39° to1·00008,which is only about1⁄58of the total expansion to 212°, with1⁄64of the total range of temperature.All gases expand the same quantity by the same increase of temperature, which from 32° to 212° Fahr. =180°480=3⁄8, or 100 volumes become 137·5. For each degree of Fahr. the expansion is1⁄480.When dry air is saturated with moisture, its bulk increases, and its specific gravity diminishes, because aqueous vapour is less dense than air, at like temperatures.The following Table gives the multipliers to be employed for converting one volume of moist gas at the several temperatures, into a volume of dry gas.Temperature.Multiplier.53° F.0·9870540·9864550·9858560·9852570·9846580·9839590·9833600·9827610·9820620·9813630·9806640·9799650·9793660·9786670·9779680·9772690·9765700·9758710·9751720·9743730·9735

TABLE I.—Linear Dilatation of Solids by Heat.

Dimensions which a bar takes at 212°, whose length at 32° is 1·000000.

The last two measurements by an air thermometer.

TABLE II.

Expansion of certain Liquids by being Heated from 32° to 212°.

All gases expand the same quantity by the same increase of temperature, which from 32° to 212° Fahr. =180°480=3⁄8, or 100 volumes become 137·5. For each degree of Fahr. the expansion is1⁄480.

When dry air is saturated with moisture, its bulk increases, and its specific gravity diminishes, because aqueous vapour is less dense than air, at like temperatures.

The following Table gives the multipliers to be employed for converting one volume of moist gas at the several temperatures, into a volume of dry gas.

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