ISINGLASS, or Fish-glue, called in Latinichthyocolla, is a whitish, dry, tough, semi-transparentsubstance, twisted into different shapes, often in the form of a lyre, and consisting of membranes rolled together. Good isinglass is unchangeable in the air, has a leathery aspect, and a mawkish taste nearly insipid; when steeped in cold water it swells, softens, and separates in membranous laminæ. At the boiling heat it dissolves in water, and the solution, on cooling, forms a white jelly, which is semi-transparent, soluble in weak acids, but is precipitated from them by alkalies. It is gelatine nearly pure; and if not brittle, like other glue, this depends on its fibrous and elastic texture. The whitest and finest is preferred in commerce. Isinglass is prepared from the air-bladders of sturgeons, and especially the great sturgeon, theaccipenser huso; which is fished on the shores of the Caspian sea, and in the rivers flowing into it, for the sake chiefly of its swim bladder.The preparation of isinglass in this part of Russia, and particularly at Astracan, consists in steeping these bladders in water, removing carefully their external coat, and the blood which often covers them, putting them in a hempen bag, squeezing them, softening them between the hands, and twisting them into small cylinders, which are afterwards bent into the shape of a lyre. They are ready for the market immediately after being dried in the sun, and whitened with the fumes of burning sulphur.In some districts of Moldavia, another process is followed. The skin, the stomach, the intestines, and the swim bladder of the sturgeon are cut in small pieces, steeped in cold water, and then gently boiled. The jelly thus obtained is spread in thin layers to dry, when it assumes the appearance of parchment. This being softened in a little water, then rolled into cylinders, or extended into plates, constitutes an inferior article.The swim bladder of the cod and many other fishes, also furnishes a species of isinglass, but it is much more membranous, and less soluble than that of the sturgeon.The properties of isinglass are the same as those of gelatine or pure glue; and its uses are very numerous. It is employed in considerable quantities to clarify ale, wine, liqueurs, and coffee. As an article of food to the luxurious in the preparation of creams and jellies, it is in great request. Four parts of it convert 100 of water into a tremulous jelly, which is employed to enrich many soups and sauces. It is used along with gum as a dressing to give lustre to ribbons and other silk articles. The makers of artificial pearls employ it to fix theessence d’Orienton the glass globules which form these pearls, and the Turks set their precious stones or jewellery by means of isinglass dissolved in alcohol along with gum ammoniac; a combination which is also employed in this country to join broken pieces of china and glass, under the name of diamond cement. That setting preserves its transparency after it solidifies, if it be well made.It is by covering taffety or thin silk with a coat of isinglass that court plaster is made. A solution of isinglass coloured with carmine forms an excellent injection liquor to the anatomist. M. Rochen has made another pretty application of isinglass. He plunges into a limpid solution of it, made by means of a water bath, sheets of wire gauze set in window or lamp frames, which, when cold, have the appearance of glass, and answer instead of it for shades and other purposes. If one dip be not sufficient to make a proper transparent plate of isinglass, several may be given in succession, allowing each film to harden in the interval between the dips. The outer surface should be varnished to protect it from damp air. These panes of gelatine are now generally used for lamps instead of horn, in the maritime arsenals of France.Isinglass imported for home consumption; and duties paid in1835.1836.1835.1836.1,814 cwts.1,735 cwts.£4,290£4,125
ISINGLASS, or Fish-glue, called in Latinichthyocolla, is a whitish, dry, tough, semi-transparentsubstance, twisted into different shapes, often in the form of a lyre, and consisting of membranes rolled together. Good isinglass is unchangeable in the air, has a leathery aspect, and a mawkish taste nearly insipid; when steeped in cold water it swells, softens, and separates in membranous laminæ. At the boiling heat it dissolves in water, and the solution, on cooling, forms a white jelly, which is semi-transparent, soluble in weak acids, but is precipitated from them by alkalies. It is gelatine nearly pure; and if not brittle, like other glue, this depends on its fibrous and elastic texture. The whitest and finest is preferred in commerce. Isinglass is prepared from the air-bladders of sturgeons, and especially the great sturgeon, theaccipenser huso; which is fished on the shores of the Caspian sea, and in the rivers flowing into it, for the sake chiefly of its swim bladder.
The preparation of isinglass in this part of Russia, and particularly at Astracan, consists in steeping these bladders in water, removing carefully their external coat, and the blood which often covers them, putting them in a hempen bag, squeezing them, softening them between the hands, and twisting them into small cylinders, which are afterwards bent into the shape of a lyre. They are ready for the market immediately after being dried in the sun, and whitened with the fumes of burning sulphur.
In some districts of Moldavia, another process is followed. The skin, the stomach, the intestines, and the swim bladder of the sturgeon are cut in small pieces, steeped in cold water, and then gently boiled. The jelly thus obtained is spread in thin layers to dry, when it assumes the appearance of parchment. This being softened in a little water, then rolled into cylinders, or extended into plates, constitutes an inferior article.
The swim bladder of the cod and many other fishes, also furnishes a species of isinglass, but it is much more membranous, and less soluble than that of the sturgeon.
The properties of isinglass are the same as those of gelatine or pure glue; and its uses are very numerous. It is employed in considerable quantities to clarify ale, wine, liqueurs, and coffee. As an article of food to the luxurious in the preparation of creams and jellies, it is in great request. Four parts of it convert 100 of water into a tremulous jelly, which is employed to enrich many soups and sauces. It is used along with gum as a dressing to give lustre to ribbons and other silk articles. The makers of artificial pearls employ it to fix theessence d’Orienton the glass globules which form these pearls, and the Turks set their precious stones or jewellery by means of isinglass dissolved in alcohol along with gum ammoniac; a combination which is also employed in this country to join broken pieces of china and glass, under the name of diamond cement. That setting preserves its transparency after it solidifies, if it be well made.
It is by covering taffety or thin silk with a coat of isinglass that court plaster is made. A solution of isinglass coloured with carmine forms an excellent injection liquor to the anatomist. M. Rochen has made another pretty application of isinglass. He plunges into a limpid solution of it, made by means of a water bath, sheets of wire gauze set in window or lamp frames, which, when cold, have the appearance of glass, and answer instead of it for shades and other purposes. If one dip be not sufficient to make a proper transparent plate of isinglass, several may be given in succession, allowing each film to harden in the interval between the dips. The outer surface should be varnished to protect it from damp air. These panes of gelatine are now generally used for lamps instead of horn, in the maritime arsenals of France.
Isinglass imported for home consumption; and duties paid in
ISLAND MOSS (Lichen d’Islande, Fr.;Flechte Isl., Germ.); is a lichen, theCetraria islandica, which contains a substance soluble in hot water, but forming a jelly when it cools, styledlichenineby M. Guerin. Lichenine has a yellowish tint in the dry state, is transparent in thin plates, insipid, inodorous, and difficult to pulverize. Cold water makes it swell, but does not dissolve it. It is precipitated in white flocks by alcohol and ether. Iodine tinges it of a brownish green. Sulphuric acid converts it into sugar; and the nitric into oxalic acid. Lichenine is prepared by extracting first of all from the plant a bitter colouring matter, by digesting 1 pound of it in 16 pounds of cold water containing 1 ounce of pearl-ash; then draining the lichen, edulcorating with cold water, and boiling it in 9 pounds of boiling water, till 3 pounds be evaporated. The jelly which forms, upon cooling the filtered solution, is dark coloured, but, being dried and redissolved in hot water, it becomes clear and colourless. Lichenine consists of 39·33 carbon, 7·24 hydrogen, and 55·43 oxygen. With potash, lime, oxide of lead, and tincture of galls, the habitudes of lichenine and starch are the same. The mucilage of island moss is preferred in Germany to common paste for dressing the warp of webs in the loom, because it remains soft, from its hygrometric quality. It is also mixed with the pulp for sizing paper in the vat.
ISLAND MOSS (Lichen d’Islande, Fr.;Flechte Isl., Germ.); is a lichen, theCetraria islandica, which contains a substance soluble in hot water, but forming a jelly when it cools, styledlichenineby M. Guerin. Lichenine has a yellowish tint in the dry state, is transparent in thin plates, insipid, inodorous, and difficult to pulverize. Cold water makes it swell, but does not dissolve it. It is precipitated in white flocks by alcohol and ether. Iodine tinges it of a brownish green. Sulphuric acid converts it into sugar; and the nitric into oxalic acid. Lichenine is prepared by extracting first of all from the plant a bitter colouring matter, by digesting 1 pound of it in 16 pounds of cold water containing 1 ounce of pearl-ash; then draining the lichen, edulcorating with cold water, and boiling it in 9 pounds of boiling water, till 3 pounds be evaporated. The jelly which forms, upon cooling the filtered solution, is dark coloured, but, being dried and redissolved in hot water, it becomes clear and colourless. Lichenine consists of 39·33 carbon, 7·24 hydrogen, and 55·43 oxygen. With potash, lime, oxide of lead, and tincture of galls, the habitudes of lichenine and starch are the same. The mucilage of island moss is preferred in Germany to common paste for dressing the warp of webs in the loom, because it remains soft, from its hygrometric quality. It is also mixed with the pulp for sizing paper in the vat.
IVORY (Ivoire, Fr.;Elfenbein, Germ.); is the osseous matter of the tusksteeth of the elephant, the hippopotamus, or morse, wild boar, several species of phocæ, as well as the horn or tooth of the narwhal. Ivory is a white, fine-grained, dense substance, of considerable elasticity, in thin plates, and more transparent than paper of equal thickness. The outside of the tusk is covered by the cortical part, which is softer and less compact than the interior substance, with the exception of the brown plate that sometimes lines the interior cavity. The hardest, toughest, whitest, and most translucent ivory, has the preference in the market; and the tusks of the sea-horse are considered to afford the best. In these, a rough glassy enamel covers the cortical part, of such hardness, as to strike sparks with steel. The horn of the narwhal is sometimes ten feet long, and consists of an ivory of the finest description, as hard as that of the elephant, and susceptible of a better polish; but it is not in general so much esteemed as the latter.Ivory has the same constituents as the teeth of animals, three-fourths being phosphate, with a little carbonate of lime; one-fourth cartilage. SeeBones.It is extensively employed by miniature painters for their tablets; by turners, in making numberless useful and ornamental objects; by cutlers, for the handles of knives and forks; by comb-makers; as also by philosophical instrument makers, for constructing the scales of thermometers, &c. The ivory of the sea-horse is preferred by dentists for making artificial teeth; that of the East India elephant is better than of the African. When it shows cracks or fissures in its substance, and when a splinter broken off has a dull aspect, it is reckoned of inferior value. Ivory is distinguishable from bone by its peculiar semi-transparent rhombohedral net-work, which may be readily seen in slips of ivory cut transversely.Ivory is very apt to take a yellow-brown tint by exposure to air. It may be whitened or bleached, by rubbing it first with pounded pumice-stone and water, then placing it moist under a glass shade luted to the sole at the bottom, and exposing it to sunshine. The sunbeams without the shade would be apt to occasion fissures in the ivory. The moist rubbing and exposure may be repeated several times.For etching ivory, a ground made by the following recipe is to be applied to the polished surface:—Take of pure white wax, and transparent tears of mastick, each one ounce; asphalt, half an ounce. The mastick and asphalt having been separately reduced to fine powder, and the wax being melted in an earthenware vessel over the fire, the mastick is to be first slowly strewed in and dissolved by stirring; and then the asphalt in like manner. This compound is to be poured out into lukewarm water, well kneaded, as it cools, by the hand, into rolls or balls about one inch in diameter. These should be kept wrapped round with taffety. If white rosin be substituted for the mastick, a cheaper composition will be obtained, which answers nearly as well; 2 oz. asphalt, 1 oz. rosin,1â„2oz. white wax; being good proportions. Callot’s etching ground for copper plates, is made by dissolving with heat 4 oz. of mastick in 4 oz. of very fine linseed oil; filtering the varnish through a rag, and bottling it for use.Either of the two first grounds being applied to the ivory, the figured design is to be traced through it in the usual way, a ledge of wax is to be applied, and the surface is to be then covered with strong sulphuric acid. The effect comes better out with the aid of a little heat; and by replacing the acid, as it becomes dilute by absorption of moisture, with concentrated oil of vitriol. Simple wax may be employed instead of the copperplate engravers’ ground; and strong muriatic acid instead of sulphuric. If an acid solution of silver or gold be used for etching, the design will become purple or black, on exposure to sunshine. The wax may be washed away with oil of turpentine. Acid nitrate of silver affords the easiest means of tracing permanent black lines upon ivory.Ivory may be dyed by using the following prescriptions:—1.Black dye.—If the ivory be laid for several hours in a dilute solution of neutral nitrate of pure silver, with access of light, it will assume a black colour, having a slightly green cast. A still finer and deeper black may be obtained by boiling the ivory for some time in a strained decoction of logwood, and then steeping it in a solution of red sulphate or red acetate of iron.2.Blue dye.—When ivory is kept immersed for a longer or shorter time in a dilute solution of sulphate of indigo (partly saturated with potash), it assumes a blue tint of greater or less intensity.3.Green dye.—This is given by dipping blued ivory for a little while in solution of nitromuriate of tin, and then in a hot decoction of fustic.4.Yellow dye—is given by impregnating the ivory first with the above tin mordant, and then digesting it with heat in a strained decoction of fustic. The colour passes into orange, if some brazil wood has been mixed with the fustic. A very fine unchangeable yellow may be communicated to ivory by steeping it 18 or 24 hours in a strong solution of the neutral chromate of potash, and then plunging it for some time in a boiling hot solution of acetate of lead.5.Red dye—may be given by imbuing the ivory first with the tin mordant, then plunging it in a bath of brazil wood, cochineal, or a mixture of the two. Lac-dye may be used with still more advantage, to produce a scarlet tint. If the scarlet ivory be plunged for a little in a solution of potash, it will become cherry red.6.Violet dye—is given in the logwood bath, to ivory previously mordanted for a short time with solution of tin. When the bath becomes exhausted, it imparts a lilac hue. Violet ivory is changed to purple-red by steeping it a little while in water containing a few drops of nitro-muriatic acid.With regard to dyeing ivory, it may in general be observed, that the colours penetrate better before the surface is polished than afterwards. Should any dark spots appear, they may be cleared up by rubbing them with chalk; after which the ivory should be dyed once more to produce perfect uniformity of shade. On taking it out of the boiling hot dye bath, it ought to be immediately plunged into cold water, to prevent the chance of fissures being caused by the heat.If the borings and chips of the ivory-turner, called ivory dust, be boiled in water, a kind of fine size is obtained.The importation of elephants’ teeth for home consumption was, in 1834, 4,282 cwts.; in 1835, 3,698, and in 1836, 4,584 cwts.; duty, 1l.per cwt.
IVORY (Ivoire, Fr.;Elfenbein, Germ.); is the osseous matter of the tusksteeth of the elephant, the hippopotamus, or morse, wild boar, several species of phocæ, as well as the horn or tooth of the narwhal. Ivory is a white, fine-grained, dense substance, of considerable elasticity, in thin plates, and more transparent than paper of equal thickness. The outside of the tusk is covered by the cortical part, which is softer and less compact than the interior substance, with the exception of the brown plate that sometimes lines the interior cavity. The hardest, toughest, whitest, and most translucent ivory, has the preference in the market; and the tusks of the sea-horse are considered to afford the best. In these, a rough glassy enamel covers the cortical part, of such hardness, as to strike sparks with steel. The horn of the narwhal is sometimes ten feet long, and consists of an ivory of the finest description, as hard as that of the elephant, and susceptible of a better polish; but it is not in general so much esteemed as the latter.
Ivory has the same constituents as the teeth of animals, three-fourths being phosphate, with a little carbonate of lime; one-fourth cartilage. SeeBones.
It is extensively employed by miniature painters for their tablets; by turners, in making numberless useful and ornamental objects; by cutlers, for the handles of knives and forks; by comb-makers; as also by philosophical instrument makers, for constructing the scales of thermometers, &c. The ivory of the sea-horse is preferred by dentists for making artificial teeth; that of the East India elephant is better than of the African. When it shows cracks or fissures in its substance, and when a splinter broken off has a dull aspect, it is reckoned of inferior value. Ivory is distinguishable from bone by its peculiar semi-transparent rhombohedral net-work, which may be readily seen in slips of ivory cut transversely.
Ivory is very apt to take a yellow-brown tint by exposure to air. It may be whitened or bleached, by rubbing it first with pounded pumice-stone and water, then placing it moist under a glass shade luted to the sole at the bottom, and exposing it to sunshine. The sunbeams without the shade would be apt to occasion fissures in the ivory. The moist rubbing and exposure may be repeated several times.
For etching ivory, a ground made by the following recipe is to be applied to the polished surface:—Take of pure white wax, and transparent tears of mastick, each one ounce; asphalt, half an ounce. The mastick and asphalt having been separately reduced to fine powder, and the wax being melted in an earthenware vessel over the fire, the mastick is to be first slowly strewed in and dissolved by stirring; and then the asphalt in like manner. This compound is to be poured out into lukewarm water, well kneaded, as it cools, by the hand, into rolls or balls about one inch in diameter. These should be kept wrapped round with taffety. If white rosin be substituted for the mastick, a cheaper composition will be obtained, which answers nearly as well; 2 oz. asphalt, 1 oz. rosin,1â„2oz. white wax; being good proportions. Callot’s etching ground for copper plates, is made by dissolving with heat 4 oz. of mastick in 4 oz. of very fine linseed oil; filtering the varnish through a rag, and bottling it for use.
Either of the two first grounds being applied to the ivory, the figured design is to be traced through it in the usual way, a ledge of wax is to be applied, and the surface is to be then covered with strong sulphuric acid. The effect comes better out with the aid of a little heat; and by replacing the acid, as it becomes dilute by absorption of moisture, with concentrated oil of vitriol. Simple wax may be employed instead of the copperplate engravers’ ground; and strong muriatic acid instead of sulphuric. If an acid solution of silver or gold be used for etching, the design will become purple or black, on exposure to sunshine. The wax may be washed away with oil of turpentine. Acid nitrate of silver affords the easiest means of tracing permanent black lines upon ivory.
Ivory may be dyed by using the following prescriptions:—
1.Black dye.—If the ivory be laid for several hours in a dilute solution of neutral nitrate of pure silver, with access of light, it will assume a black colour, having a slightly green cast. A still finer and deeper black may be obtained by boiling the ivory for some time in a strained decoction of logwood, and then steeping it in a solution of red sulphate or red acetate of iron.
2.Blue dye.—When ivory is kept immersed for a longer or shorter time in a dilute solution of sulphate of indigo (partly saturated with potash), it assumes a blue tint of greater or less intensity.
3.Green dye.—This is given by dipping blued ivory for a little while in solution of nitromuriate of tin, and then in a hot decoction of fustic.
4.Yellow dye—is given by impregnating the ivory first with the above tin mordant, and then digesting it with heat in a strained decoction of fustic. The colour passes into orange, if some brazil wood has been mixed with the fustic. A very fine unchangeable yellow may be communicated to ivory by steeping it 18 or 24 hours in a strong solution of the neutral chromate of potash, and then plunging it for some time in a boiling hot solution of acetate of lead.
5.Red dye—may be given by imbuing the ivory first with the tin mordant, then plunging it in a bath of brazil wood, cochineal, or a mixture of the two. Lac-dye may be used with still more advantage, to produce a scarlet tint. If the scarlet ivory be plunged for a little in a solution of potash, it will become cherry red.
6.Violet dye—is given in the logwood bath, to ivory previously mordanted for a short time with solution of tin. When the bath becomes exhausted, it imparts a lilac hue. Violet ivory is changed to purple-red by steeping it a little while in water containing a few drops of nitro-muriatic acid.
With regard to dyeing ivory, it may in general be observed, that the colours penetrate better before the surface is polished than afterwards. Should any dark spots appear, they may be cleared up by rubbing them with chalk; after which the ivory should be dyed once more to produce perfect uniformity of shade. On taking it out of the boiling hot dye bath, it ought to be immediately plunged into cold water, to prevent the chance of fissures being caused by the heat.
If the borings and chips of the ivory-turner, called ivory dust, be boiled in water, a kind of fine size is obtained.
The importation of elephants’ teeth for home consumption was, in 1834, 4,282 cwts.; in 1835, 3,698, and in 1836, 4,584 cwts.; duty, 1l.per cwt.
IVORY BLACK (Noir d’ivoire, Fr.;Kohle von Elfenbein, Germ.); is prepared from ivory dust, by calcination in the very same way as is described underBone Black.The calcined matter being ground and levigated on a porphyry slab, affords a beautiful velvety black, much used in copperplate printing. Ivory black may be prepared upon the small scale, by a well regulated ignition of the ivory dust in a covered crucible.
IVORY BLACK (Noir d’ivoire, Fr.;Kohle von Elfenbein, Germ.); is prepared from ivory dust, by calcination in the very same way as is described underBone Black.
The calcined matter being ground and levigated on a porphyry slab, affords a beautiful velvety black, much used in copperplate printing. Ivory black may be prepared upon the small scale, by a well regulated ignition of the ivory dust in a covered crucible.
KALI. The Arabs gave this name to an annual plant which grows near the sea-shore; now known under the name ofsalsola soda, and from whose ashes they extracted a substance, which they calledalkali, for making soap. The termkaliis used by German chemists to denote caustic potash; andkalium, its metallic basis; instead of ourpotassaandpotassium, of preposterous pedigree, being derived from the wordspot ashes, that is ashes prepared in a pot.
KALI. The Arabs gave this name to an annual plant which grows near the sea-shore; now known under the name ofsalsola soda, and from whose ashes they extracted a substance, which they calledalkali, for making soap. The termkaliis used by German chemists to denote caustic potash; andkalium, its metallic basis; instead of ourpotassaandpotassium, of preposterous pedigree, being derived from the wordspot ashes, that is ashes prepared in a pot.
KAOLIN, (Terre à porcelaine, Fr.;Porzellanerde, Germ.), is the name given by the Chinese to the fine white clay with which they fabricate the biscuit of their porcelains. SeeClay. Berthier’s analyses of two porcelain earths are as follows:—Analyses.From Passau.From Saint Yriex.Silica45·0646·8Alumina32·0037·3Lime0·74—Oxide of iron0·90—Potass—2·5Water18·013·096·799·6
KAOLIN, (Terre à porcelaine, Fr.;Porzellanerde, Germ.), is the name given by the Chinese to the fine white clay with which they fabricate the biscuit of their porcelains. SeeClay. Berthier’s analyses of two porcelain earths are as follows:—
KARABÉ, a name of amber, of Arabic origin, in use upon the Continent.
KARABÉ, a name of amber, of Arabic origin, in use upon the Continent.
KELP; (Varec, Fr.;Wareck, Germ.), is the crude alkaline matter produced by incinerating various species of fuci, orsea-weed. They are cut with sickles from the rocks in the summer season, dried and then burned, with much stirring of the pasty ash. I have analyzed many specimens of kelp, and found the quantity of soluble matter in 100 parts of the best to be from 53 to 62, while the insoluble was from 47 to 38. The soluble consisted of—Sulphate of Soda8·019·0Soda in carbonate and sulphuret8·55·5Muriate of soda and potash36·537·553·062·0The insoluble matter consisted of—Carbonate of lime24·010·0Silica8·00·0Alumina tinged with iron oxide9·010·0Sulphate of lime0·09·5Sulphur and loss6·08·5100·0100·0The first of these specimens was from Heisker, the second from Rona, both in the isle of Skye, upon the property of Lord Macdonald. From these, and many other analyses which I have made, it appears that kelp is a substance of very variable composition, and hence it was very apt to produce anomalous results, when employed as the chief alkaline flux of crown glass, which it was for a very long period. Thefucus vesiculosusandfucus nodosusare reckoned to afford the best kelp by incineration; but all the species yield a better product when they are of two or three years growth, than when cut younger. Thevarec, made on the shores of Normandy, contains almost no carbonate of soda, but much sulphate of soda and potash, some hyposulphate of potash, chloride of sodium, iodide of potassium, and chloride of potassium; the average composition of the soluble salts being, according to M. Gay Lussac, 56 of chloride of sodium, 25 of chloride of potassium, and a little sulphate of potash. The very low price at which soda ash, the dry crude carbonate from the decomposition of sea salt, is now sold, has nearly superseded the use of kelp, and rendered its manufacture utterly unprofitable—a great misfortune to the Highlands and Islands of Scotland.
KELP; (Varec, Fr.;Wareck, Germ.), is the crude alkaline matter produced by incinerating various species of fuci, orsea-weed. They are cut with sickles from the rocks in the summer season, dried and then burned, with much stirring of the pasty ash. I have analyzed many specimens of kelp, and found the quantity of soluble matter in 100 parts of the best to be from 53 to 62, while the insoluble was from 47 to 38. The soluble consisted of—
The insoluble matter consisted of—
The first of these specimens was from Heisker, the second from Rona, both in the isle of Skye, upon the property of Lord Macdonald. From these, and many other analyses which I have made, it appears that kelp is a substance of very variable composition, and hence it was very apt to produce anomalous results, when employed as the chief alkaline flux of crown glass, which it was for a very long period. Thefucus vesiculosusandfucus nodosusare reckoned to afford the best kelp by incineration; but all the species yield a better product when they are of two or three years growth, than when cut younger. Thevarec, made on the shores of Normandy, contains almost no carbonate of soda, but much sulphate of soda and potash, some hyposulphate of potash, chloride of sodium, iodide of potassium, and chloride of potassium; the average composition of the soluble salts being, according to M. Gay Lussac, 56 of chloride of sodium, 25 of chloride of potassium, and a little sulphate of potash. The very low price at which soda ash, the dry crude carbonate from the decomposition of sea salt, is now sold, has nearly superseded the use of kelp, and rendered its manufacture utterly unprofitable—a great misfortune to the Highlands and Islands of Scotland.
KERMES. There are two substances so called, of totally different natures.Kermes mineralis merely a factitious sulphuret of antimony in a state of impalpable comminution, prepared in the moist way. Its minute examination belongs to pharmaceutical chemistry. It may be obtained perfectly pure, by diluting the proto-chloride of antimony with solution of tartaric acid, and precipitating the metal with sulphuretted hydrogen; or by exposing the finely levigated native sulphuret to a boiling solution of carbonate of potash for some time, and filtering the liquor while boiling hot. The kermes falls down in a brown-red powder, as the liquor cools.Kermes-grains,alkermes, are the dried bodies of the female insects of the speciescoccus ilicis, which lives upon the leaves of thequercus ilex(prickly oak). The wordkermesis Arabic, signifies little worm. In the middle ages, this dye stuff was therefore calledvermiculusin Latin, andvermillionin French. It is curious to consider how the namevermillionhas been since transferred to red sulphuret of mercury.Kermes has been known in the East since the days of Moses; it has been employed from time immemorial in India to dye silk; and was used also by the ancient Greek and Roman dyers. Pliny speaks of it under the name ofcoccigranum, and says that there grew upon the oak in Africa, Sicily, &c. a small excrescence like a bud, calledcusculium; that the Spaniards paid with these grains, half of their tribute to the Romans; that those produced in Sicily were the worst; that they served to dye purple; and that those from the neighbourhood of Emerita in Lusitania (Portugal) were the best.In Germany, during the ninth, twelfth, thirteenth, and fourteenth centuries, the rural serfs were bound to deliver annually to the convents, a certain quantity of kermes, thecoccus polonicus, among the other products of husbandry. It was collected from the trees upon Saint John’s day, between eleven o’clock and noon, with religious ceremonies, and was therefore calledJohannisblut, (Saint John’s blood), as also German cochineal. At the above period, a great deal of the German kermes was consumed in Venice, for dyeing the scarlet to which that city gives its name. After the discovery of America, cochineal having been introduced, began to supersede kermes for all brilliant red dyes.The principal varieties of kermes are thecoccus quercus, thecoccus polonicus, thecoccus fragariæ, and thecoccus uva ursi.Thecoccus quercusinsect lives in the south of Europe upon the kermes oak. The female has no wings, is of the size of a small pea, of a brownish-red colour, and is covered with a whitish dust. From the middle of May to the middle of June the eggs are collected, and exposed to the vapour of vinegar, to prevent their incubation. A portion of eggs is left upon the tree for the maintenance of the brood. In the department of the Bouches-du-Rhone, one half of the kermes crop is dried. It amounts annually to about 60 quintals or cwts., and is warehoused at Avignon.The kermes of Poland, orcoccus polonicus, is found upon the roots of thescleranthus perennisand thescleranthus annuus, in sandy soils of that country and the Ukraine. This species has the same properties as the preceding; one pound of it, according to Wolfe, being capable of dyeing 10 pounds of wool; but Hermstaedt could not obtain a fine colour, although he employed 5 times as much of it as of cochineal. The Turks, Armenians,and Cossacks, dye with kermes, their morocco leather, cloth, silk, as well as the manes and tails of their horses.The kermes calledcoccus fragariæ, is found principally in Siberia, upon the root of the common strawberry.Thecoccus uva ursiis twice the size of the Polish kermes, and dyes with alum a fine red. It occurs in Russia.Kermes is found not only upon thelycopodium complanatumin the Ukraine, but upon a great many other plants.Good kermes is plump, of a deep red colour, of an agreeable smell, and a rough and pungent taste. Its colouring matter is soluble in water and alcohol; it becomes yellowish or brownish with acids, and violet or crimson with alkalis. Sulphate of iron blackens it. With alum it dyes a blood-red; with copperas an agate gray; with copperas and tartar, a lively gray; with sulphate of copper and tartar, an olive green; with tartar and salt of tin, a lively cinnamon yellow; with more alum and tartar, a lilac; with sulphate of zinc and tartar, a violet. Scarlet and crimson dyed with kermes, were calledgrain colours; and they are reckoned to be more durable than those of cochineal, as is proved by the brilliancy of the old Brussels tapestry.Hellot says that previous to dyeing in the kermes bath, he threw a handful of wool into it, in order to extract a blackish matter, which would have tarnished the colour. The red caps for the Levant are dyed at Orleans with equal parts of kermes and madder; and occasionally with the addition of some Brazil wood.Cochinealandlac-dyehave now nearly superseded the use of kermes as a tinctorial substance, in England.
KERMES. There are two substances so called, of totally different natures.Kermes mineralis merely a factitious sulphuret of antimony in a state of impalpable comminution, prepared in the moist way. Its minute examination belongs to pharmaceutical chemistry. It may be obtained perfectly pure, by diluting the proto-chloride of antimony with solution of tartaric acid, and precipitating the metal with sulphuretted hydrogen; or by exposing the finely levigated native sulphuret to a boiling solution of carbonate of potash for some time, and filtering the liquor while boiling hot. The kermes falls down in a brown-red powder, as the liquor cools.
Kermes-grains,alkermes, are the dried bodies of the female insects of the speciescoccus ilicis, which lives upon the leaves of thequercus ilex(prickly oak). The wordkermesis Arabic, signifies little worm. In the middle ages, this dye stuff was therefore calledvermiculusin Latin, andvermillionin French. It is curious to consider how the namevermillionhas been since transferred to red sulphuret of mercury.
Kermes has been known in the East since the days of Moses; it has been employed from time immemorial in India to dye silk; and was used also by the ancient Greek and Roman dyers. Pliny speaks of it under the name ofcoccigranum, and says that there grew upon the oak in Africa, Sicily, &c. a small excrescence like a bud, calledcusculium; that the Spaniards paid with these grains, half of their tribute to the Romans; that those produced in Sicily were the worst; that they served to dye purple; and that those from the neighbourhood of Emerita in Lusitania (Portugal) were the best.
In Germany, during the ninth, twelfth, thirteenth, and fourteenth centuries, the rural serfs were bound to deliver annually to the convents, a certain quantity of kermes, thecoccus polonicus, among the other products of husbandry. It was collected from the trees upon Saint John’s day, between eleven o’clock and noon, with religious ceremonies, and was therefore calledJohannisblut, (Saint John’s blood), as also German cochineal. At the above period, a great deal of the German kermes was consumed in Venice, for dyeing the scarlet to which that city gives its name. After the discovery of America, cochineal having been introduced, began to supersede kermes for all brilliant red dyes.
The principal varieties of kermes are thecoccus quercus, thecoccus polonicus, thecoccus fragariæ, and thecoccus uva ursi.
Thecoccus quercusinsect lives in the south of Europe upon the kermes oak. The female has no wings, is of the size of a small pea, of a brownish-red colour, and is covered with a whitish dust. From the middle of May to the middle of June the eggs are collected, and exposed to the vapour of vinegar, to prevent their incubation. A portion of eggs is left upon the tree for the maintenance of the brood. In the department of the Bouches-du-Rhone, one half of the kermes crop is dried. It amounts annually to about 60 quintals or cwts., and is warehoused at Avignon.
The kermes of Poland, orcoccus polonicus, is found upon the roots of thescleranthus perennisand thescleranthus annuus, in sandy soils of that country and the Ukraine. This species has the same properties as the preceding; one pound of it, according to Wolfe, being capable of dyeing 10 pounds of wool; but Hermstaedt could not obtain a fine colour, although he employed 5 times as much of it as of cochineal. The Turks, Armenians,and Cossacks, dye with kermes, their morocco leather, cloth, silk, as well as the manes and tails of their horses.
The kermes calledcoccus fragariæ, is found principally in Siberia, upon the root of the common strawberry.
Thecoccus uva ursiis twice the size of the Polish kermes, and dyes with alum a fine red. It occurs in Russia.
Kermes is found not only upon thelycopodium complanatumin the Ukraine, but upon a great many other plants.
Good kermes is plump, of a deep red colour, of an agreeable smell, and a rough and pungent taste. Its colouring matter is soluble in water and alcohol; it becomes yellowish or brownish with acids, and violet or crimson with alkalis. Sulphate of iron blackens it. With alum it dyes a blood-red; with copperas an agate gray; with copperas and tartar, a lively gray; with sulphate of copper and tartar, an olive green; with tartar and salt of tin, a lively cinnamon yellow; with more alum and tartar, a lilac; with sulphate of zinc and tartar, a violet. Scarlet and crimson dyed with kermes, were calledgrain colours; and they are reckoned to be more durable than those of cochineal, as is proved by the brilliancy of the old Brussels tapestry.
Hellot says that previous to dyeing in the kermes bath, he threw a handful of wool into it, in order to extract a blackish matter, which would have tarnished the colour. The red caps for the Levant are dyed at Orleans with equal parts of kermes and madder; and occasionally with the addition of some Brazil wood.
Cochinealandlac-dyehave now nearly superseded the use of kermes as a tinctorial substance, in England.
KILLAS, is the name by which clay-slate is known among the Cornish miners.
KILLAS, is the name by which clay-slate is known among the Cornish miners.
KILN; (Four, Fr.;Ofen, Germ.) is the name given to various forms of furnaces and stoves, by which an attempered heat may be applied to bodies; thus there are brick-kilns, hop-kilns, lime-kilns, malt-kilns, pottery-kilns. Hop and malt kilns, being designed merely to expel the moisture of the vegetable matter, may be constructed in the same way. SeeBrick,Limestone,Malt,Pottery, for a description of their respective kilns.
KILN; (Four, Fr.;Ofen, Germ.) is the name given to various forms of furnaces and stoves, by which an attempered heat may be applied to bodies; thus there are brick-kilns, hop-kilns, lime-kilns, malt-kilns, pottery-kilns. Hop and malt kilns, being designed merely to expel the moisture of the vegetable matter, may be constructed in the same way. SeeBrick,Limestone,Malt,Pottery, for a description of their respective kilns.
KINIC ACID; a peculiar acid extracted by Vauquelin from cinchona.
KINIC ACID; a peculiar acid extracted by Vauquelin from cinchona.
KINO, is an extractive matter obtained from thenauclea gambir, a shrub which grows at Bancoul and Sumatra, but principally in Prince of Wales’ Island. It is of a reddish-brown colour, has a bitter styptic taste, and consists chiefly of tannin. It is used only as an astringent in medicine. Kino is often called a gum, but most improperly.
KINO, is an extractive matter obtained from thenauclea gambir, a shrub which grows at Bancoul and Sumatra, but principally in Prince of Wales’ Island. It is of a reddish-brown colour, has a bitter styptic taste, and consists chiefly of tannin. It is used only as an astringent in medicine. Kino is often called a gum, but most improperly.
KIRSCHWASSER, is an alcoholic liquor obtained by fermenting and distilling bruised cherries, calledkirschenin German. The cherry usually employed in Switzerland and Germany is a kind of morello, which on maturation becomes black, and has a kernel very large in proportion to its pulp. When ripe, the fruit being made to fall by switching the trees, is gathered by children, thrown promiscuously, unripe, ripe, and rotten into tubs, and crushed either by hand, or with a wooden beater. The mashed materials are set to ferment, and whenever this process is complete, the whole is transferred to an old still covered with verdigris, and the spirit is run off in the rudest manner possible, by placing the pot over the common fire-place.The fermented mash is usually mouldy before it is put into the alembic, the capital of which is luted on with a mixture of mud and dung. The liquor has accordingly, for the most part, a rank smell, and is most dangerous to health, not only from its own crude essential oil, but from the prussic acid, derived from the distillation of the cherry-stones.There is a superior kind ofkirschwassermade in the Black Forest, prepared with fewer kernels, from choice fruit, properly pressed, fermented, and distilled.
KIRSCHWASSER, is an alcoholic liquor obtained by fermenting and distilling bruised cherries, calledkirschenin German. The cherry usually employed in Switzerland and Germany is a kind of morello, which on maturation becomes black, and has a kernel very large in proportion to its pulp. When ripe, the fruit being made to fall by switching the trees, is gathered by children, thrown promiscuously, unripe, ripe, and rotten into tubs, and crushed either by hand, or with a wooden beater. The mashed materials are set to ferment, and whenever this process is complete, the whole is transferred to an old still covered with verdigris, and the spirit is run off in the rudest manner possible, by placing the pot over the common fire-place.
The fermented mash is usually mouldy before it is put into the alembic, the capital of which is luted on with a mixture of mud and dung. The liquor has accordingly, for the most part, a rank smell, and is most dangerous to health, not only from its own crude essential oil, but from the prussic acid, derived from the distillation of the cherry-stones.
There is a superior kind ofkirschwassermade in the Black Forest, prepared with fewer kernels, from choice fruit, properly pressed, fermented, and distilled.
KNOPPERN, are excrescences produced by the puncture of an insect upon the flower-cups of several species of oak. They are compressed or flat, irregularly pointed, generally prickly and hard; brown when ripe. They abound in Styria, Croatia, Sclavonia, and Natolia; those from the latter country being the best. They contain a great deal of tannin, are much employed in Austria for tanning, and in Germany for dyeing fawn, gray, and black. Wool, with a mordant of sulphate of zinc, takes a grayish nankeen colour. SeeGalls.
KNOPPERN, are excrescences produced by the puncture of an insect upon the flower-cups of several species of oak. They are compressed or flat, irregularly pointed, generally prickly and hard; brown when ripe. They abound in Styria, Croatia, Sclavonia, and Natolia; those from the latter country being the best. They contain a great deal of tannin, are much employed in Austria for tanning, and in Germany for dyeing fawn, gray, and black. Wool, with a mordant of sulphate of zinc, takes a grayish nankeen colour. SeeGalls.
KOUMISS, is the name of a liquor which the Calmucs make by fermenting mare’s milk, and from which they distil a favourite intoxicating spirit, calledrackorracky. Cow’s milk is said to produce only one third as much spirit, from its containing probably less saccharine matter.The milk is kept in bottles made of hides, till it becomes sour, is shaken till it casts up its cream, and is then set aside in earthen vessels in a warm place to ferment, no yeast being required, though sometimes a little old koumiss is added. 21 pounds of milk put into the still afford 14 ounces of low wines, from which 6 ounces of pretty strong alcohol, of an unpleasant flavour, are obtained by rectification.
KOUMISS, is the name of a liquor which the Calmucs make by fermenting mare’s milk, and from which they distil a favourite intoxicating spirit, calledrackorracky. Cow’s milk is said to produce only one third as much spirit, from its containing probably less saccharine matter.
The milk is kept in bottles made of hides, till it becomes sour, is shaken till it casts up its cream, and is then set aside in earthen vessels in a warm place to ferment, no yeast being required, though sometimes a little old koumiss is added. 21 pounds of milk put into the still afford 14 ounces of low wines, from which 6 ounces of pretty strong alcohol, of an unpleasant flavour, are obtained by rectification.
LABDANUM orLadanum, is an unctuous resin, of an agreeable odour, found besmearing the leaves and twigs of thecystus creticus, a plant which grows in the island of Candia, and in Syria. It is naturally a dark-brown soft substance, but it hardens on keeping. Its specific gravity is 1·186. It has a bitter taste. Its chief use is in surgery for making plasters.
LABDANUM orLadanum, is an unctuous resin, of an agreeable odour, found besmearing the leaves and twigs of thecystus creticus, a plant which grows in the island of Candia, and in Syria. It is naturally a dark-brown soft substance, but it hardens on keeping. Its specific gravity is 1·186. It has a bitter taste. Its chief use is in surgery for making plasters.
LABRADORITE; opaline or Labradore felspar, is a beautiful mineral, with brilliant changing colours, blue, red, and green, &c. Spec. grav. 2·70 to 2·75. Scratches glass; affords no water by calcination; fusible at the blow-pipe into a frothy bead; soluble in muriatic acid; solution affords a copious precipitate with oxalate of ammonia. Cleavages of 931â„2° and 861â„2°; one of which is brilliant and pearly. Its constituents are, silica, 55·75; alumina, 26·5; lime, 11; soda, 4; oxide of iron, 1·25; water, 0·5.
LABRADORITE; opaline or Labradore felspar, is a beautiful mineral, with brilliant changing colours, blue, red, and green, &c. Spec. grav. 2·70 to 2·75. Scratches glass; affords no water by calcination; fusible at the blow-pipe into a frothy bead; soluble in muriatic acid; solution affords a copious precipitate with oxalate of ammonia. Cleavages of 931â„2° and 861â„2°; one of which is brilliant and pearly. Its constituents are, silica, 55·75; alumina, 26·5; lime, 11; soda, 4; oxide of iron, 1·25; water, 0·5.
LABYRINTH, in metallurgy, means a series of canals distributed in the sequel of a stamping-mill; through which canals a stream of water is transmitted for suspending, carrying off, and depositing, at different distances, the ground ores. SeeMetallurgy.
LABYRINTH, in metallurgy, means a series of canals distributed in the sequel of a stamping-mill; through which canals a stream of water is transmitted for suspending, carrying off, and depositing, at different distances, the ground ores. SeeMetallurgy.
LAC, LAC-DYE. (Laque, Fr.;Lack,Lackfarben, Germ.)Stick-lacis produced by the puncture of a peculiar female insect, calledcoccus laccaorficus, upon the branches of several plants; as theficus religiosa, theficus indica, therhamnus jujuba, thecroton lacciferum, and thebutea frondosa, which grow in Siam, Assam, Pegu, Bengal, and Malabar. The twig becomes thereby encrusted with a reddish mammelated resin, having a crystalline-looking fracture.The female lac insect is of the size of a louse; red, round, flat, with 12 abdominal circles, a bifurcated tail, antennæ, and 6 claws, half the length of the body. The male is twice the above size, and has 4 wings; there is one of them to 5000 females. In November or December the young brood makes its escape from the eggs, lying beneath the dead body of the mother; they crawl about a little way, and fasten themselves to the bark of the shrubs. About this period the branches often swarm to such a degree with this vermin, that they seem covered with a red dust; in this case, they are apt to dry up, by being exhausted of their juices. Many of these insects, however, become the prey of others, or are carried off by the feet of birds, to which they attach themselves, and are transplanted to other trees. They soon produce small nipple-like incrustations upon the twigs, their bodies being apparently glued, by means of a transparent liquor, which goes on increasing to the end of March, so as to form a cellular texture. At this time, the animal resembles a small oval bag, without life, of the size of cochineal. At the commencement, a beautiful red liquor only is perceived, afterwards eggs make their appearance; and in October or November, when the red liquor gets exhausted, 20 or 30 young ones bore a hole through the back of their mother, and come forth. The empty cells remain upon the branches. These are composed of the milky juice of the plant, which serves as nourishment to the insects, and which is afterwards transformed or elaborated into the red colouring matter that is found mixed with the resin, but in greater quantity in the bodies of the insects, in their eggs, and still more copiously in the red liquor secreted for feeding the young. After the brood escapes, the cells contain much less colouring matter. On this account, the branches should be broken off before this happens, and dried in the sun. In the East Indies this operation is performed twice in the year; the first time in March, the second in October. The twigs encrusted with the radiated cellular substance, constitute thestick-lacof commerce. It is of a red colour more or less deep, nearly transparent, and hard, with a brilliant conchoidal fracture. The stick-lac of Siam is the best; a piece of it presented to me by Mr. Rennie, of Fenchurch-street, having an incrustation fully one quarter of an inch thick all round the twig. The stick-lac of Assam ranks next; and, last, that of Bengal, in which the resinous coat is scanty, thin, and irregular. According to the analysis of Dr. John, stick-lac consists, in 120 parts, ofAn odorous common resin80·00A resin insoluble in ether20·00Colouring matter analogous to that of cochineal4·50Bitter balsamic matter3·00Dun yellow extract0·50Acid of the stick-lac (laccic acid)0·75Fatty matter, like wax3·00Skins of the insects, and colouring matter2·50Salts1·25Earths0·75Loss4·75120·00According to Franke, the constituents of stick-lac are, resin, 65·7; substance of the lac, 28·3; colouring matter, 0·6.Seed-lac.—When the resinous concretion is taken off the twigs, coarsely pounded, and triturated with water in a mortar, the greater part of the colouring matter is dissolved, and the granular portion which remains being dried in the sun, constitutesseed-lac. It contains of course less colouring matter than the stick-lac, and is much less soluble. John found in 100 parts of it, resin, 66·7; wax, 1·7; matter of the lac, 16·7; bitter balsamic matter, 2·5; colouring matter, 3·9; dun yellow extract, 0·4; envelopes of insects, 2·1; laccic acid, 0·0; salts of potash and lime, 1·0; earths, 6·6; loss, 4·2.In India theseed-lacis put into oblong bags of cotton cloth, which are held over a charcoal fire by a man at each end, and, as soon as it begins to melt, the bag is twisted so as to strain the liquefied resin through its substance, and to make it drop upon smooth stems of the banyan tree (musa paradisa). In this way, the resin spreads into thin plates, and constitutes the substance known in commerce by the name ofshell-lac.The Pegu stick-lac, being very dark coloured, furnishes a shell-lac of a corresponding deep hue, and therefore of inferior value. The palest and finest shell-lac is brought from the northernCircar. It contains very little colouring matter. A stick-lac of an intermediate kind comes from the Mysore country, which yields a brilliant lac-dye and a good shell-lac.Lac-dyeis the watery infusion of the ground stick-lac, evaporated to dryness, and formed into cakes about two inches square and half an inch thick. Dr. John found it to consist of, colouring matter, 50; resin, 25; and solid matter, composed of alumina, plaster, chalk, and sand, 22.Dr. Macleod, of Madras, informs me that he prepared a very superior lac-dye from stick-lac, by digesting it in the cold in a slightly alkaline decoction of the dried leaves of theMemecylon tinctorium(perhaps theM. capitellatum, from which the natives of Malabar and Ceylon obtain a saffron-yellow dye). This solution being used along with a mordant consisting of a saturated solution of tin in muriatic acid, was found to dye woollen cloth of a very brilliant scarlet hue.The cakes oflac-dyeimported from India, stamped with peculiar marks to designate their different manufacturers, are now employed exclusively in England for dyeing scarlet cloth, and are found to yield an equally brilliant colour, and one less easily affected by perspiration than that produced by cochineal. When the lac-dye was first introduced, sulphuric acid was the solvent applied to the pulverized cakes, but as muriatic acid has been found to answer so much better, it has entirely supplanted it. A goodsolvent(No. 1.) for this dye-stuff may be prepared by dissolving 3 pounds of tin in 60 pounds of muriatic acid, of specific gravity 1·19. The propermordantfor the cloth is made by mixing 27 pounds of muriatic acid of sp. grav. 1·17, with 11â„2pounds of nitric acid of 1·19; putting this mixture into a salt-glazed stone bottle, and adding to it in small bits at a time, grain tin, till 4 pounds be dissolved. This solution (No. 2.) may be used within twelve hours after it is made, provided it has become cold and clear. For dyeing; three quarters of a pint of the solvent No. 1. is to be poured upon each pound of the pulverized lac-dye, and allowed to digest upon it for six hours. The cloth before being subjected to the dye bath, must be scoured in the mill with fullers’ earth. To dye 100 pounds of pelisse cloth, a tin boiler of 300 gallons capacity should be filled nearly brimful with water, and a fire kindled under it. Whenever the temperature rises to 150° Fahr., a handful of bran, and half a pint of the solution of tin (No. 2.) are to be introduced. The froth, which rises as it approaches ebullition, must be skimmed off; and when the liquor boils, 101â„2pounds of lac-dye, previously mixed with 7 pints of the solvent No. 1., and 31â„2pounds of solution of tin No. 2., must be poured in. An instant afterwards, 101â„2pounds of tartar, and 4 pounds of ground sumach, both tied up in a linen bag, are to be suspended in the boiling bath for five minutes. The fire being now withdrawn, 20 gallons of cold water, with 101â„2pints of solution of tin being poured into the bath, the cloth is to be immersed in it, moved about rapidly during ten minutes; the fire is to be then re-kindled, and the cloth winced more slowly through the bath, which must be made to boil as quickly as possible, and maintained at that pitch for an hour. The cloth is to be next washed in the river; and lastly with water only, in the fulling mill. The above proportions of the ingredients produce a brilliant scarlet tint, with a slightly purple cast. If a more orange hue be wanted, white Florence argal may be used, instead of tartar, and some more sumach. Lac-dye may be substituted for cochineal in the orange-scarlets; but for the more delicate pink shades, it does notanswer so well, as the lustre is apt to be impaired by the large quantity of acid necessary to dissolve the colouring matter of the lac.Shell-lac, by Mr. Hatchett’s analysis, consists of resin, 90·5; colouring matter, 0·5; wax, 4·0; gluten, 2·8; loss, 1·8; in 100 parts.The resin may be obtained pure by treating shell-lac with cold alcohol, and filtering the solution in order to separate a yellow gray pulverulent matter. When the alcohol is again distilled off, a brown, translucent, hard, and brittle resin, of specific gravity 1·139, remains. It melts into a viscid mass with heat, and diffuses an aromatic odour. Anhydrous alcohol dissolves it in all proportions. According to John, it consists of two resins, one of which dissolves readily in alcohol, ether, the volatile and fat oils; while the other is little soluble in cold alcohol, and is insoluble in ether and the volatile oils. Unverdorben, however, has detected no less than four different resins, and some other substances in shell-lac. Shell-lac dissolves with ease in dilute muriatic and acetic acids; but not in concentrated sulphuric acid. The resin of shell-lac has a great tendency to combine with salifiable bases; as with caustic potash, which it deprives of its alkaline taste.This solution, which is of a dark red colour, dries into a brilliant, transparent, reddish brown mass; which may be re-dissolved in both water and alcohol. By passing chlorine in excess through the dark-coloured alkaline solution, the lac-resin is precipitated in a colourless state. When this precipitate is washed and dried, it forms, with alcohol, an excellent pale-yellow varnish, especially with the addition of a little turpentine and mastic.With the aid of heat, shell-lac dissolves readily in a solution of borax.The substances which Unverdorben found in shell-lac are the following:1. A resin, soluble in alcohol and ether;2. A resin, soluble in alcohol, insoluble in ether;3. A resinous body, little soluble in cold alcohol;4. A crystallizable resin;5. A resin, soluble in alcohol and ether, but insoluble in petroleum, and uncrystallizable.6. The unsaponified fat of thecoccusinsect, as well as oleic and margaric acids.7. Wax.8. Thelaccineof Dr. John.9. An extractive colouring matter.Statistical TableofLac-dyeandLac-lake, per favour of James Wilkinson, Esq., of Leadenhall-street.Import.Export.HomeConsump-tion.Prices.Stocks.lbs.lbs.lbs.s.d.s.d.Chests.1802253nonenone18031,735accot.burned180453118051,9871806none180725,35018085,731180940,6321810235,1541811378,3251812198,2501813289,6541814278,8995,071133,9351815598,5928,441137,9151816269,37327,412162,8941817384,90923,091234,7631818242,57232,079323,1691819179,51121,707207,0631820441,48649,519912,5141821641,75591,925322,8371822872,96729,578349,3511823534,22013,050414,7141824604,26953,843483,3391825541,44361,908385,7341826760,72968,603395,6091827756,31576,875448,270194011,5381828512,87454,999397,867133911,0851829475,63239,344433,851133611,9761830534,34178,099548,865093311,8341831913,562175,717597,568042612,5591832378,84369,842594,155042311,4201833326,89466,447426,460092411,4571834708,95989,229398,8320112411,9281835528,564203,840573,2880113010,4541836642,436200,975642,61510409,49218371,011,674133,959427,89010398,780The Stock includes 2,200 chests of Lac-lake.
LAC, LAC-DYE. (Laque, Fr.;Lack,Lackfarben, Germ.)Stick-lacis produced by the puncture of a peculiar female insect, calledcoccus laccaorficus, upon the branches of several plants; as theficus religiosa, theficus indica, therhamnus jujuba, thecroton lacciferum, and thebutea frondosa, which grow in Siam, Assam, Pegu, Bengal, and Malabar. The twig becomes thereby encrusted with a reddish mammelated resin, having a crystalline-looking fracture.
The female lac insect is of the size of a louse; red, round, flat, with 12 abdominal circles, a bifurcated tail, antennæ, and 6 claws, half the length of the body. The male is twice the above size, and has 4 wings; there is one of them to 5000 females. In November or December the young brood makes its escape from the eggs, lying beneath the dead body of the mother; they crawl about a little way, and fasten themselves to the bark of the shrubs. About this period the branches often swarm to such a degree with this vermin, that they seem covered with a red dust; in this case, they are apt to dry up, by being exhausted of their juices. Many of these insects, however, become the prey of others, or are carried off by the feet of birds, to which they attach themselves, and are transplanted to other trees. They soon produce small nipple-like incrustations upon the twigs, their bodies being apparently glued, by means of a transparent liquor, which goes on increasing to the end of March, so as to form a cellular texture. At this time, the animal resembles a small oval bag, without life, of the size of cochineal. At the commencement, a beautiful red liquor only is perceived, afterwards eggs make their appearance; and in October or November, when the red liquor gets exhausted, 20 or 30 young ones bore a hole through the back of their mother, and come forth. The empty cells remain upon the branches. These are composed of the milky juice of the plant, which serves as nourishment to the insects, and which is afterwards transformed or elaborated into the red colouring matter that is found mixed with the resin, but in greater quantity in the bodies of the insects, in their eggs, and still more copiously in the red liquor secreted for feeding the young. After the brood escapes, the cells contain much less colouring matter. On this account, the branches should be broken off before this happens, and dried in the sun. In the East Indies this operation is performed twice in the year; the first time in March, the second in October. The twigs encrusted with the radiated cellular substance, constitute thestick-lacof commerce. It is of a red colour more or less deep, nearly transparent, and hard, with a brilliant conchoidal fracture. The stick-lac of Siam is the best; a piece of it presented to me by Mr. Rennie, of Fenchurch-street, having an incrustation fully one quarter of an inch thick all round the twig. The stick-lac of Assam ranks next; and, last, that of Bengal, in which the resinous coat is scanty, thin, and irregular. According to the analysis of Dr. John, stick-lac consists, in 120 parts, of
According to Franke, the constituents of stick-lac are, resin, 65·7; substance of the lac, 28·3; colouring matter, 0·6.
Seed-lac.—When the resinous concretion is taken off the twigs, coarsely pounded, and triturated with water in a mortar, the greater part of the colouring matter is dissolved, and the granular portion which remains being dried in the sun, constitutesseed-lac. It contains of course less colouring matter than the stick-lac, and is much less soluble. John found in 100 parts of it, resin, 66·7; wax, 1·7; matter of the lac, 16·7; bitter balsamic matter, 2·5; colouring matter, 3·9; dun yellow extract, 0·4; envelopes of insects, 2·1; laccic acid, 0·0; salts of potash and lime, 1·0; earths, 6·6; loss, 4·2.
In India theseed-lacis put into oblong bags of cotton cloth, which are held over a charcoal fire by a man at each end, and, as soon as it begins to melt, the bag is twisted so as to strain the liquefied resin through its substance, and to make it drop upon smooth stems of the banyan tree (musa paradisa). In this way, the resin spreads into thin plates, and constitutes the substance known in commerce by the name ofshell-lac.
The Pegu stick-lac, being very dark coloured, furnishes a shell-lac of a corresponding deep hue, and therefore of inferior value. The palest and finest shell-lac is brought from the northernCircar. It contains very little colouring matter. A stick-lac of an intermediate kind comes from the Mysore country, which yields a brilliant lac-dye and a good shell-lac.
Lac-dyeis the watery infusion of the ground stick-lac, evaporated to dryness, and formed into cakes about two inches square and half an inch thick. Dr. John found it to consist of, colouring matter, 50; resin, 25; and solid matter, composed of alumina, plaster, chalk, and sand, 22.
Dr. Macleod, of Madras, informs me that he prepared a very superior lac-dye from stick-lac, by digesting it in the cold in a slightly alkaline decoction of the dried leaves of theMemecylon tinctorium(perhaps theM. capitellatum, from which the natives of Malabar and Ceylon obtain a saffron-yellow dye). This solution being used along with a mordant consisting of a saturated solution of tin in muriatic acid, was found to dye woollen cloth of a very brilliant scarlet hue.
The cakes oflac-dyeimported from India, stamped with peculiar marks to designate their different manufacturers, are now employed exclusively in England for dyeing scarlet cloth, and are found to yield an equally brilliant colour, and one less easily affected by perspiration than that produced by cochineal. When the lac-dye was first introduced, sulphuric acid was the solvent applied to the pulverized cakes, but as muriatic acid has been found to answer so much better, it has entirely supplanted it. A goodsolvent(No. 1.) for this dye-stuff may be prepared by dissolving 3 pounds of tin in 60 pounds of muriatic acid, of specific gravity 1·19. The propermordantfor the cloth is made by mixing 27 pounds of muriatic acid of sp. grav. 1·17, with 11â„2pounds of nitric acid of 1·19; putting this mixture into a salt-glazed stone bottle, and adding to it in small bits at a time, grain tin, till 4 pounds be dissolved. This solution (No. 2.) may be used within twelve hours after it is made, provided it has become cold and clear. For dyeing; three quarters of a pint of the solvent No. 1. is to be poured upon each pound of the pulverized lac-dye, and allowed to digest upon it for six hours. The cloth before being subjected to the dye bath, must be scoured in the mill with fullers’ earth. To dye 100 pounds of pelisse cloth, a tin boiler of 300 gallons capacity should be filled nearly brimful with water, and a fire kindled under it. Whenever the temperature rises to 150° Fahr., a handful of bran, and half a pint of the solution of tin (No. 2.) are to be introduced. The froth, which rises as it approaches ebullition, must be skimmed off; and when the liquor boils, 101â„2pounds of lac-dye, previously mixed with 7 pints of the solvent No. 1., and 31â„2pounds of solution of tin No. 2., must be poured in. An instant afterwards, 101â„2pounds of tartar, and 4 pounds of ground sumach, both tied up in a linen bag, are to be suspended in the boiling bath for five minutes. The fire being now withdrawn, 20 gallons of cold water, with 101â„2pints of solution of tin being poured into the bath, the cloth is to be immersed in it, moved about rapidly during ten minutes; the fire is to be then re-kindled, and the cloth winced more slowly through the bath, which must be made to boil as quickly as possible, and maintained at that pitch for an hour. The cloth is to be next washed in the river; and lastly with water only, in the fulling mill. The above proportions of the ingredients produce a brilliant scarlet tint, with a slightly purple cast. If a more orange hue be wanted, white Florence argal may be used, instead of tartar, and some more sumach. Lac-dye may be substituted for cochineal in the orange-scarlets; but for the more delicate pink shades, it does notanswer so well, as the lustre is apt to be impaired by the large quantity of acid necessary to dissolve the colouring matter of the lac.
Shell-lac, by Mr. Hatchett’s analysis, consists of resin, 90·5; colouring matter, 0·5; wax, 4·0; gluten, 2·8; loss, 1·8; in 100 parts.
The resin may be obtained pure by treating shell-lac with cold alcohol, and filtering the solution in order to separate a yellow gray pulverulent matter. When the alcohol is again distilled off, a brown, translucent, hard, and brittle resin, of specific gravity 1·139, remains. It melts into a viscid mass with heat, and diffuses an aromatic odour. Anhydrous alcohol dissolves it in all proportions. According to John, it consists of two resins, one of which dissolves readily in alcohol, ether, the volatile and fat oils; while the other is little soluble in cold alcohol, and is insoluble in ether and the volatile oils. Unverdorben, however, has detected no less than four different resins, and some other substances in shell-lac. Shell-lac dissolves with ease in dilute muriatic and acetic acids; but not in concentrated sulphuric acid. The resin of shell-lac has a great tendency to combine with salifiable bases; as with caustic potash, which it deprives of its alkaline taste.
This solution, which is of a dark red colour, dries into a brilliant, transparent, reddish brown mass; which may be re-dissolved in both water and alcohol. By passing chlorine in excess through the dark-coloured alkaline solution, the lac-resin is precipitated in a colourless state. When this precipitate is washed and dried, it forms, with alcohol, an excellent pale-yellow varnish, especially with the addition of a little turpentine and mastic.
With the aid of heat, shell-lac dissolves readily in a solution of borax.
The substances which Unverdorben found in shell-lac are the following:
1. A resin, soluble in alcohol and ether;
2. A resin, soluble in alcohol, insoluble in ether;
3. A resinous body, little soluble in cold alcohol;
4. A crystallizable resin;
5. A resin, soluble in alcohol and ether, but insoluble in petroleum, and uncrystallizable.
6. The unsaponified fat of thecoccusinsect, as well as oleic and margaric acids.
7. Wax.
8. Thelaccineof Dr. John.
9. An extractive colouring matter.
Statistical TableofLac-dyeandLac-lake, per favour of James Wilkinson, Esq., of Leadenhall-street.