The history of science, and more particularly the history of inventions, constantly confronts us with the problem presented by such writings as Friar Bacon’s. Rarely has it been given to one man to promote an entirely new theory or to devise an original instrument; it is more generally the case that, in the evolution of a single idea, there comes some stage which arrests our attention, and to which we assign the dignity of an “invention.†Furthermore, the obscurity that surrounds the early history of spectacles, the magic lantern, the telescope and the microscope, may find a partial solution in the spirit of the middle ages. The natural philosopher who was bold enough to present to a prince a pair of spectacles or a telescope would be in imminent danger of being regarded in the eyes of the church as a powerful and dangerous magician; and it is conceivable that the maker of such an instrument would jealously guard the secret of its actual construction, however much he might advertise its potentialities.3
§ 6. The awakening of Europe, which first manifested itself in Italy, England and France, was followed in the 16th century by a period of increasing intellectual activity. The need for experimental inquiry was realized, and a tendency to dispute the dogmatism of the church and to question the theories of the established schools of philosophy became apparent. In the science of optics, Italy led the van, the foremost pioneers being Franciscus Maurolycus (1494-1575) of Messina, and Giambattista della Porta (1538-1615) of Naples. A treatise by Maurolycus entitledPhotismi de Lumine et Umbra prospectivum radiorum incidentium facientes(1575), contains a discussion of the measurement of the intensity of light—an early essay in photometry; the formation of circular patches of light by small holes of any shape, with a correct explanation of the phenomenon; and the optical relations of the parts of the eye, maintaining that the crystalline humour acts as a lens which focuses images on the retina, explaining short- and long-sight (myopia and hyper-metropia), with the suggestion that the former may be corrected by concave, and the latter by convex, lenses. He observed the spherical aberration due to elements beyond the axis of a lens, and also the caustics of refraction (diacaustics) by a sphere (seen as the bright boundaries of the luminous patches formed by receiving the transmitted light on a screen), which he correctlyregarded as determined by the intersections of the refracted rays. His researches on refraction were less fruitful; he assumed the angles of incidence and refraction to be in the constant ratio of 8 to 5, and the rainbow, in which he recognized four colours, orange, green, blue and purple, to be formed by rays reflected in the drops along the sides of an octagon. Porta’s fame rests chiefly on hisMagia naturalis sive de miraculis rerum naturalium, of which four books were published in 1558, the complete work of twenty books appearing in 1589. It attained great popularity, perhaps by reason of its astonishing medley of subjects—pyrotechnics and perfumery, animal reproduction and hunting, alchemy and optics,—and it was several times reprinted, and translated into English (with the titleNatural Magick, 1658), German, French, Spanish, Hebrew and Arabic. The work contains an account of the camera obscura, with the invention of which the author has sometimes been credited; but, whoever the inventor, Porta was undoubtedly responsible for improving and popularizing that instrument, and also the magic lantern. In the same work practical applications of lenses are suggested, combinations comparable with telescopes are vaguely treated and spectacles are discussed. HisDe Refractione, optices parte(1593) contains an account of binocular vision, in which are found indications of the principle of the stereoscope.
§ 7. The empirical study of lenses led, in the opening decade of the 17th century, to the emergence of the telescope from its former obscurity. The first form, known as the Dutch or Galileo telescope, consisted of a convex and a concave lens, a combination which gave erect images; the later form, now known as the “Keplerian†or “astronomical†telescope (in contrast with the earlier or “terrestrial†telescope) consisted of two convex lenses, which gave inverted images. With the microscope, too, advances were made, and it seems probable that the compound type came into common use about this time. These single instruments were followed by the invention of binoculars,i.e.instruments which permitted simultaneous vision with both eyes. There is little doubt that the experimental realization of the telescope, opening up as it did such immense fields for astronomical research, stimulated the study of lenses and optical systems. The investigations of Maurolycus were insufficient to explain the theory of the telescope, and it was Kepler who first determined the principle of the Galilean telescope in hisDioptrice(1611), which also contains the first description of the astronomical or Keplerian telescope, and the demonstration that rays parallel to the axis of a plano-convex lens come to a focus at a point on the axis distant twice the radius of the curved surface of the lens, and, in the case of an equally convex lens, at an axial point distant only once the radius. He failed, however, to determine accurately the case for unequally convex lenses, a problem which was solved by Bonaventura Cavalieri, a pupil of Galileo.
Early in the 17th century great efforts were made to determine the law of refraction. Kepler, in hisProlegomena ad Vitellionem(1604), assiduously, but unsuccessfully, searched for the law, and can only be credited with twenty-seven empirical rules, really of the nature of approximations, which he employed in his theory of lenses. The true law—that the ratio of the sines of the angles of incidence and refraction is constant—was discovered in 1621 by Willebrord Snell (1591-1626); but was published for the first time after his death, and with no mention of his name, by Descartes. Whereas in Snell’s manuscript the law was stated in the form of the ratio of certain lines, trigonometrically interpretable as a ratio of cosecants, Descartes expressed the law in its modern trigonometrical form, viz. as the ratio of the sines. It may be observed that the modern form was independently obtained by James Gregory and published in hisOptica promota(1663). Armed with the law of refraction, Descartes determined the geometrical theory of the primary and secondary rainbows, but did not mention how far he was indebted to the explanation of the primary bow by Antonio de Dominis in 1611; and, similarly, in his additions to the knowledge of the telescope the influence of Galileo is not recorded.
§ 8. In his metaphysical speculations on the system of nature, Descartes formulated a theory of light at variance with the generally accepted emission theory and showing some resemblance to the earlier views of Aristotle, and, in a smaller measure, to the modern undulatory theory. He imagined light to be a pressure transmitted by an infinitely elastic medium which pervades space, and colour to be due to rotatory motions of the particles of this medium. He attempted a mechanical explanation of the law of refraction, and came to the conclusion that light passed more readily through a more highly refractive medium. This view was combated by Pierre de Fermat (1601-1665), who, from the principle known as the “law of least time,†deduced the converse to be the case,i.e.that the velocity varied inversely with the refractive index. In brief, Fermat’s argument was as follows: Since nature performs her operations by the most direct routes or shortest paths, then the path of a ray of light between any two points must be such that the time occupied in the passage is a minimum. The rectilinear propagation and the law of reflection obviously agree with this principle, and it remained to be proved whether the law of refraction tallied.
Although Fermat’s premiss is useless, his inference is invaluable, and the most notable application of it was made in about 1824 by Sir William Rowan Hamilton, who merged it into his conception of the “characteristic function,†by the help of which all optical problems, whether on the corpuscular or on the undulator theory, are solved by one common process. Hamilton was in possession of the germs of this grand theory some years before 1824, but it was first communicated to the Royal Irish Academy in that year, and published in imperfect instalments some years later. The following is his own description of it. It is of interest as exhibiting the origin of Fermat’s deduction, its relation to contemporary and subsequent knowledge, and its connexion with other analytical principles. Moreover, it is important as showing Hamilton’s views on a very singular part of the more modern history of the science to which he contributed so much.
“Those who have meditated on the beauty and utility, in theoretical mechanics, of the general method of Lagrange, who have felt the power and dignity of that central dynamical theorem which he deduced, in theMécanique analytique..., must feel that mathematical optics can only then attain a coordinate rank with mathematical mechanics ..., when it shall possess an appropriate method, and become the unfolding of a central idea.... It appears that if a general method in deductive optics can be attained at all, it must flow from some law or principle, itself of the highest generality, and among the highest results of induction.... [This] must be the principle, or law, called usually the Law of Least Action; suggested by questionable views, but established on the widest induction, and embracing every known combination of media, and every straight, or bent, or curved line, ordinary or extraordinary, along which light (whatever light may be) extends its influence successively in space and time: namely, that this linear path of light, from one point to another, is always found to be such that, if it be compared with the other infinitely various lines by which in thought and in geometry the same two points might be connected, a certain integral or sum, called oftenAction, and depending by fixed rules on the length, and shape, and position of the path, and on the media which are traversed by it, is less than all the similar integrals for the other neighbouring lines, or, at least, possesses, with respect to them, a certainstationaryproperty. From this Law, then, which may, perhaps, be named theLaw of Stationary Action, it seems that we may most fitly and with best hope set out, in the synthetic or deductive process and in the search of a mathematical method.“Accordingly, from this known law of least or stationary action I deduced (long since) another connected and coextensive principle, which may be called by analogy theLaw of Varying Action, and which seems to offer naturally a method such as we are seeking; the one law being as it were the last step in the ascending scale of induction, respecting linear paths of light, while the other law may usefully be made the first in the descending and deductive way.“The former of these two laws was discovered in the following manner. The elementary principle of straight rays showed that light, under the most simple and usual circumstances, employs the direct, and therefore the shortest, course to pass from one point to another. Again, it was a very early discovery (attributed by Laplace to Ptolemy), that, in the case of a plane mirror, the bent line formed by the incident and reflected rays is shorter than any other bent line having the same extremities, and having its point of bending on the mirror. These facts were thought by some to be instances and results of the simplicity and economy of nature; and Fermat, whose researches on maxima and minima are claimed by the Continental mathematicians as the germ of the differential calculus, sought anxiously to trace some similar economy in themore complex case of refraction. He believed that by a metaphysical or cosmological necessity, arising from the simplicity of the universe, light always takes the course which it can traverse in the shortest time. To reconcile this metaphysical opinion with the law of refraction, discovered experimentally by Snellius, Fermat was led to suppose that the two lengths, orindices, which Snellius had measured on the incident ray prolonged and on the refracted ray, and had observed to have one common projection on a refracting plane, are inversely proportional to the two successive velocities of the light before and after refraction, and therefore that the velocity of light is diminished on entering those denser media in which it is observed to approach the perpendicular; for Fermat believed that the time of propagation of light along a line bent by refraction was represented by the sum of the two products, of the incident portion multiplied by the index of the first medium and of the refracted portion multiplied by the index of the second medium; because he found, by his mathematical method, that this sum was less, in the case of a plane refractor, than if light went by any other than its actual path from one given point to another, and because he perceived that the supposition of a velocity inversely as the index reconciled his mathematical discovery of the minimum of the foregoing sum with his cosmological principle of least time. Descartes attacked Fermat’s opinions respecting light, but Leibnitz zealously defended them; and Huygens was led, by reasonings of a very different kind, to adopt Fermat’s conclusions of a velocity inversely as the index, and of aminimum timeof propagation of light, in passing from one given point to another through an ordinary refracting plane. Newton, however, by his theory of emission and attraction, was led to conclude that the velocity of light wasdirectly, notinversely, as the index, and that it wasincreasedinstead of beingdiminishedon entering a denser medium; a result incompatible with the theorem of the shortest time in refraction. This theorem of shortest time was accordingly abandoned by many, and among the rest by Maupertuis, who, however, proposed in its stead, as a new cosmological principle, thatcelebrated law of least actionwhich has since acquired so high a rank in mathematical physics, by the improvements of Euler and Lagrange.â€
“Those who have meditated on the beauty and utility, in theoretical mechanics, of the general method of Lagrange, who have felt the power and dignity of that central dynamical theorem which he deduced, in theMécanique analytique..., must feel that mathematical optics can only then attain a coordinate rank with mathematical mechanics ..., when it shall possess an appropriate method, and become the unfolding of a central idea.... It appears that if a general method in deductive optics can be attained at all, it must flow from some law or principle, itself of the highest generality, and among the highest results of induction.... [This] must be the principle, or law, called usually the Law of Least Action; suggested by questionable views, but established on the widest induction, and embracing every known combination of media, and every straight, or bent, or curved line, ordinary or extraordinary, along which light (whatever light may be) extends its influence successively in space and time: namely, that this linear path of light, from one point to another, is always found to be such that, if it be compared with the other infinitely various lines by which in thought and in geometry the same two points might be connected, a certain integral or sum, called oftenAction, and depending by fixed rules on the length, and shape, and position of the path, and on the media which are traversed by it, is less than all the similar integrals for the other neighbouring lines, or, at least, possesses, with respect to them, a certainstationaryproperty. From this Law, then, which may, perhaps, be named theLaw of Stationary Action, it seems that we may most fitly and with best hope set out, in the synthetic or deductive process and in the search of a mathematical method.
“Accordingly, from this known law of least or stationary action I deduced (long since) another connected and coextensive principle, which may be called by analogy theLaw of Varying Action, and which seems to offer naturally a method such as we are seeking; the one law being as it were the last step in the ascending scale of induction, respecting linear paths of light, while the other law may usefully be made the first in the descending and deductive way.
“The former of these two laws was discovered in the following manner. The elementary principle of straight rays showed that light, under the most simple and usual circumstances, employs the direct, and therefore the shortest, course to pass from one point to another. Again, it was a very early discovery (attributed by Laplace to Ptolemy), that, in the case of a plane mirror, the bent line formed by the incident and reflected rays is shorter than any other bent line having the same extremities, and having its point of bending on the mirror. These facts were thought by some to be instances and results of the simplicity and economy of nature; and Fermat, whose researches on maxima and minima are claimed by the Continental mathematicians as the germ of the differential calculus, sought anxiously to trace some similar economy in themore complex case of refraction. He believed that by a metaphysical or cosmological necessity, arising from the simplicity of the universe, light always takes the course which it can traverse in the shortest time. To reconcile this metaphysical opinion with the law of refraction, discovered experimentally by Snellius, Fermat was led to suppose that the two lengths, orindices, which Snellius had measured on the incident ray prolonged and on the refracted ray, and had observed to have one common projection on a refracting plane, are inversely proportional to the two successive velocities of the light before and after refraction, and therefore that the velocity of light is diminished on entering those denser media in which it is observed to approach the perpendicular; for Fermat believed that the time of propagation of light along a line bent by refraction was represented by the sum of the two products, of the incident portion multiplied by the index of the first medium and of the refracted portion multiplied by the index of the second medium; because he found, by his mathematical method, that this sum was less, in the case of a plane refractor, than if light went by any other than its actual path from one given point to another, and because he perceived that the supposition of a velocity inversely as the index reconciled his mathematical discovery of the minimum of the foregoing sum with his cosmological principle of least time. Descartes attacked Fermat’s opinions respecting light, but Leibnitz zealously defended them; and Huygens was led, by reasonings of a very different kind, to adopt Fermat’s conclusions of a velocity inversely as the index, and of aminimum timeof propagation of light, in passing from one given point to another through an ordinary refracting plane. Newton, however, by his theory of emission and attraction, was led to conclude that the velocity of light wasdirectly, notinversely, as the index, and that it wasincreasedinstead of beingdiminishedon entering a denser medium; a result incompatible with the theorem of the shortest time in refraction. This theorem of shortest time was accordingly abandoned by many, and among the rest by Maupertuis, who, however, proposed in its stead, as a new cosmological principle, thatcelebrated law of least actionwhich has since acquired so high a rank in mathematical physics, by the improvements of Euler and Lagrange.â€
§ 9. The second half of the 17th century witnessed developments in the practice and theory of optics which equal in importance the mathematical, chemical and astronomical acquisitions of the period. Original observations were made which led to the discovery, in an embryonic form, of new properties of light, and the development of mathematical analysis facilitated the quantitative and theoretical investigation of these properties. Indeed, mathematical and physical optics may justly be dated from this time. The phenomenon ofdiffraction, so named by Grimaldi, and by Newtoninflection, which may be described briefly as the spreading out, or deviation, from the strictly rectilinear path of light passing through a small aperture or beyond the edge of an opaque object, was discovered by the Italian Jesuit, Francis Maria Grimaldi (1619-1663), and published in hisPhysico-Mathesis de Lumine(1665); at about the same time Newton made his classical investigation of the spectrum or the band of colours formed when light is transmitted through a prism,4and studiedinterferencephenomena in the form of the colours of thin and thick plates, and in the form now termedNewton’s rings;double refraction, in the form of the dual images of a single object formed by a rhomb of Iceland spar, was discovered by Bartholinus in 1670; Huygens’s examination of the transmitted beams led to the discovery of an absence of symmetry now calledpolarization; and the finite velocity of light was deduced in 1676 by Ole Roemer from the comparison of the observed and computed times of the eclipses of the moons of Jupiter.
These discoveries had a far-reaching influence upon the theoretical views which had been previously held: for instance, Newton’s recombination of the spectrum by means of a second (inverted) prism caused the rejection of the earlier view that the prism actually manufactured the colours, and led to the acceptance of the theory that the colours were physically present in the white light, the function of the prism being merely to separate the physical mixture; and Roemer’s discovery of the finite velocity of light introduced the necessity of considering the momentum of the particles which, on the accepted emission theory, composed the light. Of greater moment was the controversy concerning the emission or corpuscular theory championed by Newton and the undulatory theory presented by Huygens (see section II. of this article). In order to explain the colours of thin plates Newton was forced to abandon some of the original simplicity of his theory; and we may observe that by postulating certain motions for the Newtonian corpuscles all the phenomena of light can be explained, these motions aggregating to a transverse displacement, translated longitudinally, and the corpuscles, at the same time, becoming otiose and being replaced by a medium in which the vibration is transmitted. In this way the Newtonian theory may be merged into the undulatory theory. Newton’s results are collected in hisOpticks, the first edition of which appeared in 1704. Huygens published his theory in hisTraité de lumière(1690), where he explained reflection, refraction and double refraction, but did not elucidate the formation of shadows (which was readily explicable on the Newtonian hypothesis) or polarization; and it was this inability to explain polarization which led to Newton’s rejection of the wave theory. The authority of Newton and his masterly exposition of the corpuscular theory sustained that theory until the beginning of the 19th century, when it succumbed to the assiduous skill of Young and Fresnel.
§ 10. Simultaneously with this remarkable development of theoretical and experimental optics, notable progress was made in the construction of optical instruments. The increased demand for telescopes, occasioned by the interest in observational astronomy, led to improvements in the grinding of lenses (the primary aim being to obtain forms in which spherical aberration was a minimum), and also to the study of achromatism, the principles of which followed from Newton’s analysis andsynthesisof white light. Kepler’s supposition that lenses having the form of surfaces of revolution of the conic sections would bring rays to a focus without spherical aberration was investigated by Descartes, and the success of the latter’s demonstration led to the grinding of ellipsoidal and hyperboloidal lenses, but with disappointing results.5The grinding of spherical lenses was greatly improved by Huygens, who also attempted to reduce chromatic aberration in the refracting telescope by introducing a stop (i.e.by restricting the aperture of the rays); to the same experimenter are due compound eye-pieces, the invention of which had been previously suggested by Eustachio Divini. The so-called Huygenian eye-piece is composed of two plano-convex lenses with their plane faces towards the eye; the field-glass has a focal length three times that of the eye-glass, and the distance between them is twice the focal length of the eye-glass. Huygens observed that spherical aberration was diminished by making the deviations of the rays at the two lenses equal, and Ruggiero Giuseppe Boscovich subsequently pointed out that the combination was achromatic. The true development, however, of the achromatic refracting telescope, which followed from the introduction of compound object-glasses giving no dispersion, dates from about the middle of the 18th century.The difficulty of obtaining lens systems in which aberrations were minimized, and the theory of Newton that colour production invariably attended refraction, led to the manufacture of improved specula which permitted the introduction of reflecting telescopes. The idea of this type of instrument had apparently occurred to Marin Mersenne in about 1640, but the first reflector of note was described in 1663 by James Gregory in hisOptica promota; a second type was invented by Newton, and a third in 1672 by Cassegrain. Slight improvements were made in the microscope, although the achromatic type did not appear until about 1820, some sixty years after John Dollond had determined the principle of the achromatic telescope (seeAberration,Telescope,Microscope,Binocular Instrument).
§ 11. Passing over the discovery by Ehrenfried Walther Tschirnhausen (1651-1708) of the caustics produced by reflection (“catacausticsâ€) and his experiments with large reflectors and refractors (for the manufacture of which he established glass-works in Italy); James Bradley’s discovery in 1728 of the “aberration of light,†with the subsequent derivation of the velocity of light, the value agreeing fairly well with Roemer’s estimate; the foundation of scientific photometry by Pierre Bouguer in an essay published in 1729 and expanded in 1760 into hisTraité d’optique sur la graduation de la lumière; the publication of John Henry Lambert’s treatise on the same subject, entitledPhotometria, sive de Mensura et Gradibus Luminis, Colorum et Umbrae(1760); and the development of the telescope and other optical instruments, we arrive at the closing decades of the 18th century. During the forty years 1780 to 1820 the history of optics is especially marked by the names of Thomas Young and Augustin Fresnel, and in a lesser degree by Arago, Malus, Sir William Herschel, Fraunhofer, Wollaston, Biot and Brewster.
Although the corpuscular theory had been disputed by Benjamin Franklin, Leonhard Euler and others, the authority of Newton retained for it an almost general acceptance until the beginning of the 19th century, when Young and Fresnel instituted their destructive criticism. Basing his views on the earlier undulatory theories and diffraction phenomena of Grimaldi and Hooke, Young accepted the Huygenian theory, assuming, from a false analogy with sound waves, that the wave-disturbance was longitudinal, and ignoring the suggestion made by Hooke in 1672 that the direction of the vibration might be transverse,i.e.at right angles to the direction of the rays. As with Huygens, Young was unable to explain diffraction correctly, or polarization. But the assumption enabled him to establish the principle of interference,6one of the most fertile in the science of physical optics. The undulatory theory was also accepted by Fresnel who, perceiving the inadequacy of the researches of Huygens and Young, showed in 1818 by an analysis which, however, is not quite free from objection, that, by assuming that every element of a wave-surface could act as a source of secondary waves or wavelets, the diffraction bands were due to the interference of the secondary waves formed by each element of a primary wave falling upon the edge of an obstacle or aperture. One consequence of Fresnel’s theory was that the bands were independent of the nature of the diffracting edge—a fact confirmed by experiment and therefore invalidating Young’s theory that the bands were produced by the interference between the primary wave and the wave reflected from the edge of the obstacle. Another consequence, which was first mathematically deduced by Poisson and subsequently confirmed by experiment, is the paradoxical phenomenon that a small circular disk illuminated by a point source casts a shadow having a bright centre.
§ 12. The undulatory theory reached its zenith when Fresnel explained the complex phenomena of polarization, by adopting the conception of Hooke that the vibrations were transverse, and not longitudinal.7Polarization by double refraction had been investigated by Huygens, and the researches of Wollaston and, more especially, of Young, gave such an impetus to the study that the Institute of France made double refraction the subject of a prize essay in 1812. E. L. Malus (1775-1812) discovered the phenomenon of polarization by reflection about 1808 and investigated metallic reflection; Arago discovered circular polarization in quartz in 1811, and, with Fresnel, made many experimental investigations, which aided the establishment of the Fresnel-Arago laws of the interference of polarized beams; Biot introduced a reflecting polariscope, investigated the colours of crystalline plates and made many careful researches on the rotation of the plane of polarization; Sir David Brewster made investigations over a wide range, and formulated the law connecting the angle of polarization with the refractive index of the reflecting medium. Fresnel’s theory was developed in a strikingly original manner by Sir William Rowan Hamilton, who interpreted from Fresnel’s analytical determination of the geometrical form of the wave-surface in biaxal crystals the existence of two hitherto unrecorded phenomena. At Hamilton’s instigation Humphrey Lloyd undertook the experimental search, and brought to light the phenomena of external and internal conical refraction.
The undulatory vibration postulated by Fresnel having been generally accepted as explaining most optical phenomena, it became necessary to determine the mechanical properties of the aether which transmits this motion. Fresnel, Neumann, Cauchy, MacCullagh, and, especially, Green and Stokes, developed the “elastic-solid theory.†By applying the theory of elasticity they endeavoured to determine the constants of a medium which could transmit waves of the nature of light. Many different allocations were suggested (of which one of the most recent is Lord Kelvin’s “contractile aether,†which, however, was afterwards discarded by its author), and the theory as left by Green and Stokes has merits other than purely historical. At a later date theories involving an action between the aether and material atoms were proposed, the first of any moment being J. Boussinesq’s (1867). C. Christiansen’s investigation of anomalous dispersion in 1870, and the failure of Cauchy’s formula (founded on the elastic-solid theory) to explain this phenomenon, led to the theories of W. Sellmeier (1872), H. von Helmholtz (1875), E. Ketteler (1878), E. Lommel (1878) and W. Voigt (1883). A third class of theory, to which the present-day theory belongs, followed from Clerk Maxwell’s analytical investigations in electromagnetics. Of the greatest exponents of this theory we may mention H. A. Lorentz, P. Drude and J. Larmor, while Lord Rayleigh has, with conspicuous brilliancy, explained several phenomena (e.g.the colour of the sky) on this hypothesis.
For a critical examination of these theories see section II. of this article; reference may also be made to theBritish Association Reports: “On Physical Optics,†by Humphrey Lloyd (1834), p. 35; “On Double Refraction,†by Sir G. G. Stokes (1862), p. 253; “On Optical Theories,†by R. T. Glazebrook (1885), p. 157.
For a critical examination of these theories see section II. of this article; reference may also be made to theBritish Association Reports: “On Physical Optics,†by Humphrey Lloyd (1834), p. 35; “On Double Refraction,†by Sir G. G. Stokes (1862), p. 253; “On Optical Theories,†by R. T. Glazebrook (1885), p. 157.
§ 13.Recent Developments.—The determination of the velocity of light (see section III. of this article) may be regarded as definitely settled, a result contributed to by A. H. L. Fizeau (1849), J. B. L. Foucault (1850, 1862), A. Cornu (1874), A. A. Michelson (1880), James Young and George Forbes (1882), Simon Newcomb (1880-1882) and Cornu (1900). The velocity in moving media was investigated theoretically by Fresnel; and Fizeau (1859), and Michelson and Morley (1886) showed experimentally that the velocity was increased in running water by an amount agreeing with Fresnel’s formula, which was based on the hypothesis of a stationary aether. The optics of moving media have also been investigated by Lord Rayleigh, and more especially by H. A. Lorentz, who also assumed a stationary aether. The relative motion of the earth and the aether has animportant connexion with the phenomenon of the aberration of light, and has been treated with masterly skill by Joseph Larmor and others (seeAether). The relation of the earth’s motion to the intensities of terrestrial sources of light was investigated theoretically by Fizeau, but no experimental inquiry was made until 1903, when Nordmeyer obtained negative results, which were confirmed by the theoretical investigations of A. A. Bucherer and H. A. Lorentz.
Experimental photometry has been greatly developed since the pioneer work of Bouguer and Lambert and the subsequent introduction of the photometers of Ritchie, Rumford, Bunsen and Wheatstone, followed by Swan’s in 1859, and O. R. Lummer and E. Brodhun’s instrument (essentially the same as Swan’s) in 1889. This expansion may largely be attributed to the increase in the number of artificial illuminants—especially the many types of filament- and arc-electric lights, and the incandescent gas light. Colour photometry has also been notably developed, especially since the enunciation of the “Purkinje phenomenon†in 1825. Sir William Abney has contributed much to this subject, and A. M. Meyer has designed a photometer in which advantage is taken of the phenomenon of contrast colours. “Flicker photometry†may be dated from O. N. Rood’s investigations in 1893, and the same principle has been applied by Haycraft and Whitman. These questions—colour and flicker photometry—have important affinities to colour perception and the persistence of vision (seeVision). The spectrophotometer, devised by De Witt Bristol Brace in 1899, which permits the comparison of similarly coloured portions of the spectra from two different sources, has done much valuable work in the determination of absorptive powers and extinction coefficients. Much attention has also been given to the preparation of a standard of intensity, and many different sources have been introduced (seePhotometry). Stellar photometry, which was first investigated instrumentally with success by Sir John Herschel, was greatly improved by the introduction of Zöllner’s photometer, E. C. Pickering’s meridian photometer and C. Pritchard’s wedge photometer. Other methods of research in this field are by photography—photographic photometry—and radiometric method (seePhotometry, Celestial).
The earlier methods for the experimental determination of refractive indices by measuring the deviation through a solid prism of the substance in question or, in the case of liquids, through a hollow prism containing the liquid, have been replaced in most accurate work by other methods. The method of total reflection, due originally to Wollaston, has been put into a very convenient form, applicable to both solids and liquids, in the Pulfrich refractometer (seeRefraction). Still more accurate methods, based on interference phenomena, have been devised. Jamin’s interference refractometer is one of the earlier forms of such apparatus; and Michelson’s interferometer is one of the best of later types (seeInterference). The variation of refractive index with density has been the subject of much experimental and theoretical inquiry. The empirical rule of Gladstone and Dale was often at variance with experiment, and the mathematical investigations of H. A. Lorentz of Leiden and L. Lorenz of Copenhagen on the electromagnetic theory led to a more consistent formula. The experimental work has been chiefly associated with the names of H. H. Landolt and J. W. Brühl, whose results, in addition to verifying the Lorenz-Lorentz formula, have established that this function of the refractive index and density is a colligative property of the molecule,i.e.it is calculable additively from the values of this function for the component atoms, allowance being made for the mode in which they are mutually combined (seeChemistry, Physical). The preparation of lenses, in which the refractive index decreases with the distance from the axis, by K. F. J. Exner, H. F. L. Matthiessen and Schott, and the curious results of refraction by non-homogeneous media, as realized by R. Wood may be mentioned (seeMirage).
The spectrum of white light produced by prismatic refraction has engaged many investigators. The infra-red or heat waves were discovered by Sir William Herschel, and experiments on the actinic effects of the different parts of the spectrum on silver salts by Scheele, Senebier, Ritter, Seebeck and others, proved the increased activity as one passed from the red to the violet and the ultra-violet. Wollaston also made many investigations in this field, noticing the dark lines—the “Fraunhofer linesâ€â€”which cross the solar spectrum, which were further discussed by Brewster and Fraunhofer, who thereby laid the foundations of modern spectroscopy. Mention may also be made of the investigations of Lord Rayleigh and Arthur Schuster on the resolving power of prisms (seeDiffraction), and also of the modern view of the function of the prism in analysing white light. The infra-red and ultra-violet rays are of especial interest since, although not affecting vision after the manner of ordinary light, they possess very remarkable properties. Theoretical investigation on the undulatory theory of the law of reflection shows that a surface, too rough to give any trace of regular reflection with ordinary light, may regularly reflect the long waves, a phenomenon experimentally realized by Lord Rayleigh. Long waves—the so-called “residual rays†or “Rest-strahlenâ€â€”have also been isolated by repeated reflections from quartz surfaces of the light from zirconia raised to incandescence by the oxyhydrogen flame (E. F. Nichols and H. Rubens); far longer waves were isolated by similar reflections from fluorite (56 µ) and sylvite (61 µ) surfaces in 1899 by Rubens and E. Aschkinass. The short waves—ultra-violet rays—have also been studied, the researches of E. F. Nichols on the transparency of quartz to these rays, which are especially present in the radiations of the mercury arc, having led to the introduction of lamps made of fused quartz, thus permitting the convenient study of these rays, which, it is to be noted, are absorbed by ordinary clear glass. Recent researches at the works of Schott and Genossen, Jena, however, have resulted in the production of a glass transparent to the ultra-violet.
Dispersion,i.e.that property of a substance which consists in having a different refractive index for rays of different wave-lengths, was first studied in the form known as “ordinary dispersion†in which the refrangibility of the ray increased with the wave-length. Cases had been observed by Fox Talbot, Le Roux, and especially by Christiansen (1870) and A. Kundt (1871-1872) where this normal rule did not hold; to such phenomena the name “anomalous dispersion†was given, but really there is nothing anomalous about it at all, ordinary dispersion being merely a particular case of the general phenomenon. The Cauchy formula, which was founded on the elastic-solid theory, did not agree with the experimental facts, and the germs of the modern theory, as was pointed out by Lord Rayleigh in 1900, were embodied in a question proposed by Clerk Maxwell for the Mathematical Tripos examination for 1869. The principle, which occurred simultaneously to W. Sellmeier (who is regarded as the founder of the modern theory) and had been employed about 1850 by Sir G. G. Stokes to explain absorption lines, involves an action between the aether and the molecules of the dispersing substance. The mathematical investigation is associated with the names of Sellmeier, Hermann Helmholtz, Eduard Ketteler, P. Drude, H. A. Lorentz and Lord Rayleigh, and the experimental side with many observers—F. Paschen, Rubens and others; absorbing media have been investigated by A. W. Pflüger, a great many aniline dyes by K. Stöckl, and sodium vapour by R. W. Wood. Mention may also be made of the beautiful experiments of Christiansen (1884) and Lord Rayleigh on the colours transmitted by white powders suspended in liquids of the same refractive index. If, for instance, benzol be gradually added to finely powdered quartz, a succession of beautiful colours—red, yellow, green and finally blue—is transmitted, or, under certain conditions, the colours may appear at once, causing the mixture to flash like a fiery opal. Absorption, too, has received much attention; the theory has been especially elaborated by M. Planck, and the experimental investigation has been prosecuted from the purely physical standpoint, and also from the standpoint of the physical chemist, with a view to correlating absorption with constitution.
Interference phenomena have been assiduously studied. Theexperiments of Young, Fresnel, Lloyd, Fizeau and Foucault, of Fresnel and Arago on the measurement of refractive indices by the shift of the interference bands, of H. F. Talbot on the “Talbot bands†(which he insufficiently explained on the principle of interference, it being shown by Sir G. B. Airy that diffraction phenomena supervene), of Baden-Powell on the “Powell bands,†of David Brewster on “Brewster’s bands,†have been developed, together with many other phenomena—Newton’s rings, the colours of thin, thick and mixed plates, &c.—in a striking manner, one of the most important results being the construction of interferometers applicable to the determination of refractive indices and wave-lengths, with which the names of Jamin, Michelson, Fabry and Perot, and of Lummer and E. Gehrcke are chiefly associated. The mathematical investigations of Fresnel may be regarded as being completed by the analysis chiefly due to Airy, Stokes and Lord Rayleigh. Mention may be made of Sir G. G. Stokes’ attribution of the colours of iridescent crystals to periodic twinning; this view has been confirmed by Lord Rayleigh (Phil. Mag., 1888) who, from the purity of the reflected light, concluded that the laminae were equidistant by the order of a wave-length. Prior to 1891 only interference between waves proceeding in the same direction had been studied. In that year Otto H. Wiener obtained, on a film 1/20th of a wave-length in thickness, photographic impressions of the stationary waves formed by the interference of waves proceeding in opposite directions, and in 1892 Drude and Nernst employed a fluorescent film to record the same phenomenon. This principle is applied in the Lippmann colour photography, which was suggested by W. Zenker, realized by Gabriel Lippmann, and further investigated by R. G. Neuhauss, O. H. Wiener, H. Lehmann and others.
Great progress has been made in the study of diffraction, and “this department of optics is precisely the one in which the wave theory has secured its greatest triumphs†(Lord Rayleigh). The mathematical investigations of Fresnel and Poisson were placed on a dynamical basis by Sir G. G. Stokes; and the results gained more ready interpretation by the introduction of “Babinet’s principle†in 1837, and Cornu’s graphic methods in 1874. The theory also gained by the researches of Fraunhofer, Airy, Schwerd, E. Lommel and others. The theory of the concave grating, which resulted from H. A. Rowland’s classical methods of ruling lines of the necessary nature and number on curved surfaces, was worked out by Rowland, E. Mascart, C. Runge and others. The resolving power and the intensity of the spectra have been treated by Lord Rayleigh and Arthur Schuster, and more recently (1905), the distribution of light has been treated by A. B. Porter. The theory of diffraction is of great importance in designing optical instruments, the theory of which has been more especially treated by Ernst Abbe (whose theory of microscopic vision dates from about 1870) by the scientific staff at the Zeiss works, Jena, by Rayleigh and others. The theory of coronae (as diffraction phenomena) was originally due to Young, who, from the principle involved, devised theeriometerfor measuring the diameters of very small objects; and Sir G. G. Stokes subsequently explained the appearances presented by minute opaque particles borne on a transparent plate. The polarization of the light diffracted at a slit was noted in 1861 by Fizeau, whose researches were extended in 1892 by H. Du Bois, and, for the case of gratings, by Du Bois and Rubens in 1904. The diffraction of light by small particles was studied in the form of very fine chemical precipitates by John Tyndall, who noticed the polarization of the beautiful cerulean blue which was transmitted. This subject—one form of which is presented in the blue colour of the sky—has been most auspiciously treated by Lord Rayleigh on both the elastic-solid and electromagnetic theories. Mention may be made of R. W. Wood’s experiments on thin metal films which, under certain conditions, originate colour phenomena inexplicable by interference and diffraction. These colours have been assigned to the principle of optical resonance, and have been treated by Kossonogov (Phys. Zeit., 1903). J. C. Maxwell Garnett (Phil. Trans. vol. 203) has shown that the colours of coloured glasses are due to ultra-microscopic particles, which have been directly studied by H. Siedentopf and R. Zsigmondy under limiting oblique illumination.
Polarization phenomena may, with great justification, be regarded as the most engrossing subject of optical research during the 19th century; the assiduity with which it was cultivated in the opening decades of that century received a great stimulus when James Nicol devised in 1828 the famous “Nicol prism,†which greatly facilitated the determination of the plane of vibration of polarized light, and the facts that light is polarized by reflection, repeated refractions, double refraction and by diffraction also contributed to the interest which the subject excited. The rotation of the plane of polarization by quartz was discovered in 1811 by Arago; if white light be used the colours change as the Nicol rotates—a phenomenon termed by Biot “rotatory dispersion.†Fresnel regarded rotatory polarization as compounded from right- and left-handed (dextro- and laevo-) circular polarizations; and Fresnel, Cornu, Dove and Cotton effected their experimental separation. Legrand des Cloizeaux discovered the enormously enhanced rotatory polarization of cinnabar, a property also possessed—but in a lesser degree—by the sulphates of strychnine and ethylene diamine. The rotatory power of certain liquids was discovered by Biot in 1815; and at a later date it was found that many solutions behaved similarly. A. Schuster distinguishes substances with regard to their action on polarized light as follows: substances which act in the isotropic state are termedphotogyric; if the rotation be associated with crystal structure,crystallogyric; if the rotation be due to a magnetic field,magnetogyric; for cases not hitherto included the termallogyricis employed, while optically inactive substances are calledisogyric. The theory of photogyric and crystallogyric rotation has been worked out on the elastic-solid (MacCullagh and others) and on the electromagnetic hypotheses (P. Drude, Cotton, &c.). Allogyrism is due to a symmetry of the molecule, and is a subject of the greatest importance in modern (and, more especially, organic) chemistry (seeStereoisomerism).
The optical properties of metals have been the subject of much experimental and theoretical inquiry. The explanations of MacCullagh and Cauchy were followed by those of Beer, Eisenlohr, Lundquist, Ketteler and others; the refractive indices were determined both directly (by Kundt) and indirectly by means of Brewster’s law; and the reflecting powers from λ = 251 µµ to λ = 1500 µµ were determined in 1900-1902 by Rubens and Hagen. The correlation of the optical and electrical constants of many metals has been especially studied by P. Drude (1900) and by Rubens and Hagen (1903).
The transformations of luminous radiations have also been studied. John Tyndall discovered calorescence. Fluorescence was treated by John Herschel in 1845, and by David Brewster in 1846, the theory being due to Sir G. G. Stokes (1852). More recent studies have been made by Lommel, E. L. Nichols and Merritt (Phys. Rev., 1904), and by Millikan who discovered polarized fluorescence in 1895. Our knowledge of phosphorescence was greatly improved by Becquerel, and Sir James Dewar obtained interesting results in the course of his low temperature researches (seeLiquid Gases). In the theoretical and experimental study of radiation enormous progress has been recorded. The pressure of radiation, the necessity of which was demonstrated by Clerk Maxwell on the electromagnetic theory, and, in a simpler manner, by Joseph Larmor in his articleRadiationin these volumes, has been experimentally determined by E. F. Nichols and Hull, and the tangential component by J. H. Poynting. With the theoretical and practical investigation the names of Balfour Stewart, Kirchhoff, Stefan, Bartoli, Boltzmann, W. Wien and Larmor are chiefly associated. Magneto-optics, too, has been greatly developed since Faraday’s discovery of the rotation of the plane of polarization by the magnetic field. The rotation for many substances was measured by Sir William H. Perkin, who attempted a correlation between rotation and composition. Brace effected the analysis of the beam into its two circularly polarizedcomponents, and in 1904 Mills measured their velocities. The Kerr effect, discovered in 1877, and the Zeeman effect (1896) widened the field of research, which, from its intimate connexion with the nature of light and electromagnetics, has resulted in discoveries of the greatest importance.
§ 14.Optical Instruments.—Important developments have been made in the construction and applications of optical instruments. To these three factors have contributed. The mathematician has quantitatively analysed the phenomena observed by the physicist, and has inductively shown what results are to be expected from certain optical systems. A consequence of this was the detailed study, and also the preparation, of glasses of diverse properties; to this the chemist largely contributed, and the manufacture of the so-calledoptical glass(seeGlass) is possibly the most scientific department of glass manufacture. The mathematical investigations of lenses owe much to Gauss, Helmholtz and others, but far more to Abbe, who introduced the method of studying the aberrations separately, and applied his results with conspicuous skill to the construction of optical systems. The development of Abbe’s methods constitutes the main subject of research of the present-day optician, and has brought about the production of telescopes, microscopes, photographic lenses and other optical apparatus to an unprecedented pitch of excellence. Great improvements have been effected in the stereoscope. Binocular instruments with enhanced stereoscopic vision, an effect achieved by increasing the distance between the object glasses, have been introduced. In the study of diffraction phenomena, which led to the technical preparation of gratings, the early attempts of Fraunhofer, Nobert and Lewis Morris Rutherfurd, were followed by H. A. Rowland’s ruling of plane and concave gratings which revolutionized spectroscopic research, and, in 1898, by Michelson’s invention of the echelon grating. Of great importance are interferometers, which permit extremely accurate determinations of refractive indices and wave-lengths, and Michelson, from his classical evaluation of the standard metre in terms of the wave-lengths of certain of the cadmium rays, has suggested the adoption of the wave-length of one such ray as a standard with which national standards of length should be compared. Polarization phenomena, and particularly the rotation of the plane of polarization by such substances as sugar solutions, have led to the invention and improvements of polarimeters. The polarized light employed in such instruments is invariably obtained by transmission through a fixed Nicol prism—the polarizer—and the deviation is measured by the rotation of a second Nicol—the analyser. The early forms, which were termed “light and shade†polarimeters, have been generally replaced by “half-shade†instruments. Mention may also be made of the microscopic examination of objects in polarized light, the importance of which as a method of crystallographic and petrological research was suggested by Nicol, developed by Sorby and greatly expanded by Zirkel, Rosenbusch and others.