An undevout astronomer is mad;
An undevout astronomer is mad;
there being no necessary connexion between a devout state of mind and the observations and calculations of a practical astronomer. It is not until the man withdraws from his calculation, as a painter from his work, and thus realizes the great idea on which he has been engaged, that imagination and wonder are excited. There is, I admit, a possible danger here. If the arithmetical processes of science be too exclusively pursued, they may impair the imagination, and thus the study of Physics is open to the same objection as philological, theological, or political studies, when carried to excess. But even in this case, the injury done is to the investigator himself: it does not reach the mass of mankind. Indeed, the conceptions furnished by his cold unimaginative reckonings may furnish themes for the poet, and excite in the highest degree that sentiment of wonder which, notwithstanding all its foolish vagaries, table-turning included, I, for my part, should be sorry to see banished from the world.
I have thus far dwelt upon the study of Physics as an agent of intellectual culture; but like other things in Nature, this study subserves more than a single end. The colours of the clouds delight the eye, and, no doubt, accomplish moral purposes also, but the selfsame clouds hold within their fleeces the moisture by which our fields are rendered fruitful. The sunbeams excite our interest and invite our investigation; but they also extend their beneficent influences to our fruits and corn, and thus accomplish, not only intellectual ends, but minister, at the same time, to our material necessities. And so it is with scientific research.
While the love of science is a sufficient incentive to the pursuit of science, and the investigator, in the prosecution of his enquiries, is raised above all material considerations, the results of his labours may exercise a potent influence upon the physical condition of the community. This is the arrangement of Nature, and not that of the scientific investigator himself; for he usually pursues his object without regard to its practical applications.
And let him who is dazzled by such applications — who sees in the steam-engine and the electric telegraph the highest embodiment of human genius and the only legitimate object of scientific research, beware of prescribing conditions to the investigator. Let him beware of attempting to substitute for that simple love with which the votary of science pursues his task, the calculations of what he is pleased to call utility. The professed utilitarian is unfortunately, in most cases, the very last man to see the occult sources from which useful results are derived. He admires the flower, but is ignorant of the conditions of its growth. The scientific man must approach Nature in his own way; for if you invade his freedom by your so-called practical considerations, it may be at the expense of those qualities on which his success as a discoverer depends. Let the self-styled practical man look to those from the fecundity of whose thought be, and thousands like him, have sprung into existence. Were they inspired in their first enquiries by the calculations of utility? Not one of them. They were often forced to live low and lie hard, and to seek compensation for their penury in the delight which their favourite pursuits afforded them.
In the words of one well qualified to speak upon this subject, 'I say not merely look at the pittance of men like John Dalton, or the voluntary starvation of the late Graff; but compare what is considered as competency or affluence by your Faradays, Liebigs, and Herschels, with the expected results of a life of successful commercial enterprise: then compare the amount of mind put forth, the work done for society in either case, and you will be constrained to allow that the former belong to a class of workers who, properly speaking, are not paid, and cannot be paid for their work, as indeed it is of a sort to which no payment could stimulate.'
But while the scientific investigator, standing upon the frontiers of human knowledge, and aiming at the conquest of fresh soil from the surrounding region of the unknown, makes the discovery of truth his exclusive object for the time, he cannot but feel the deepest interest in the practical application of the truth discovered. There is something ennobling in the triumph of Mind over Matter. Apart even from its uses to society, there is something elevating in the idea of Man having tamed that wild force which flashes through the telegraphic wire, and made it the minister of his will. Our attainments in these directions appear to be commensurate with our needs. We had already subdued horse and mule, and obtained from them all the service which it was in their power to render: we must either stand still, or find more potent agents to execute our purposes. At this point the steam-engine appears. These are still new things; it is not long since we struck into the scientific methods which have produced these results. We cannot for an instant regard them as the final achievements of Science, but rather as an earnest of what she is yet to do. They mark our first great advances upon the dominion of Nature. Animal strength fails, but here are the forces which hold the world together, and the instincts and successes of Man assure him that these forces are his when he is wise enough to command them.
As an instrument of intellectual culture, the study of Physics is profitable to all: as bearing upon special functions, its value, though not so great, is still more tangible. Why, for example, should Members of Parliament be ignorant of the subjects concerning which they are called upon to legislate? In this land of practical physics, why should they be unable to form an independent opinion upon a physical question? Why should the member of a parliamentary committee be left at the mercy of interested disputants when a scientific question is discussed, until he deems the nap a blessing which rescues him from the bewilderments of the committee-room? The education which does not supply the want here referred to, fails in its duty to England. With regard to our working people, in the ordinary sense of the term working, the study of Physics would, I imagine, be profitable, not only as a means of intellectual culture, but also as a moral influence to woo them from pursuits which now degrade them. A man's reformation oftener depends upon the indirect, than upon the direct action of the will. The will must be exerted in the choice of employment which shall break the force of temptation by erecting a barrier against it. The drunkard, for example, is in a perilous condition if he content himself merely with saying, or swearing, that he will avoid strong drink. His thoughts, if not attracted by another force, will revert to the public-house, and to rescue him permanently from this, you must give him an equivalent.
By investing the objects of hourly intercourse with an interest which prompts reflection, new enjoyments would be opened to the working man, and every one of these would be a point of force to protect him against temptation. Besides this, our factories and our foundries present an extensive field of observation, and were those who work in them rendered capable, by previous culture, ofobservingwhat theysee, the results might be incalculable. Who can say what intellectual Samsons are at the present moment toiling with closed eyes in the mills and forges of Manchester and Birmingham? Grant these Samsons sight, and you multiply the chances of discovery, and with them the prospects of national advancement. In our multitudinous technical operations we are constantly playing with forces our ignorance of which is often the cause of our destruction. There are agencies at work in a locomotive of which the maker of it probably never dreamed, but which nevertheless may be sufficient to convert it into an engine of death. When we reflect on the intellectual condition of the people who work in our coal mines, those terrific explosions which occur from time to time need not astonish us. If these men possessed sufficient physical knowledge, from the operatives themselves would probably emanate a system by which these shocking accidents might be avoided. Possessed of the knowledge, their personal interests would furnish the necessary stimulus to its practical application, and thus two ends would be served at the same time the elevation of the men and the diminution of the calamity.
Before the present Course of Lectures was publicly announced, I had many misgivings as to the propriety of my taking a part in them, thinking that my place might be better filled by an older and more experienced man. To my experience, however, such as it was, I resolved to adhere, and I have therefore described things as they revealed themselves to my own eyes, and have been enacted in my own limited practice. There is one mind common to us all; and the true expression of this mind, even in small particulars, will attest itself by the response which it calls forth in the convictions of my hearers. I ask your permission to proceed a little further in this fashion, and to refer to a fact or two in addition to those already cited, which presented themselves to my notice during my brief career as a teacher in the college already alluded to. The facts, though extremely humble, and deviating in some slight degree from the strict subject of the present discourse, may yet serve to illustrate an educational principle.
One of the duties which fell to my share was the instruction of a class in mathematics, and I usually found that Euclid and the ancient geometry generally, when properly and sympathetically addressed to the understanding, formed a most attractive study for youth. But it was my habitual practice to withdraw the boys from the routine of the book, and to appeal to their self-power in the treatment of questions not comprehended in that routine. At first, the change from the beaten track usually excited aversion: the youth felt like a child amid strangers; but in no single instance did this feeling continue. When utterly disheartened, I have encouraged the boy by the anecdote of Newton, where he attributes the difference between him and other men, mainly to his own patience; or of Mirabeau, when be ordered his servant, who had stated something to be impossible, never again to use that blockhead of a word. Thus cheered, the boy has returned to his task with a smile, which perhaps had something of doubt in it, but which, nevertheless, evinced a resolution to try again. I have seen his eye brighten, and, at length, with a pleasure of which the ecstasy of Archimedes was but a simple expansion, heard him exclaim, 'I have it, sir.' The consciousness of self-power, thus awakened, was of immense value; and, animated by it, the progress of the class was astonishing. It was often my custom to give the boys the choice of pursuing their propositions in the book, or of trying their strength at others not to be found there. Never in a single instance was the book chosen. I was ever ready to assist when help was needful, but my offers of assistance were habitually declined. The boys had tasted the sweets of intellectual conquest and demanded victories of their own. Their diagrams were scratched on the walls, cut into the beams upon the playground, and numberless other illustrations were afforded of the living interest they took in the subject. For my own part, as far as experience in teaching goes, I was a mere fledgling — knowing nothing of the rules of pedagogics, as the Germans name it; but adhering to the spirit indicated at the commencement of this discourse, and endeavouring to make geometry a means rather than a branch of education. The experiment was successful, and some of the most delightful hours of my existence have been spent in marking the vigorous and cheerful expansion of mental power, when appealed to in the manner here described.
Our pleasure was enhanced when we applied our mathematical knowledge to the solution of physical problems. Many objects of hourly contact had thus a new interest and significance imparted to them. The swing, the see-saw, the tension of the giant-stride ropes, the fall and rebound of the football, the advantage of a small boy over a large one when turning short, particularly in slippy weather; all became subjects of investigation. A lady stands before a looking-glass, of her own height; it was required to know how much of the glass was really useful to her? We learned with pleasure the economic fact that she might dispense with the lower half and see her whole figure notwithstanding. It was also pleasant to prove by mathematics, and verify by experiment, that the angular velocity of a reflected beam is twice that of the mirror which reflects it. From the hum of a bee we were able to determine the number of times the insect flaps its wings in a second. Following up our researches upon the pendulum, we learned how Colonel Sabine had made it the means of determining the figure of the earth; and we were also startled by the inference which the pendulum enabled us to draw, that if the diurnal velocity of the earth were seventeen times its present amount, the centrifugal force at the equator would be precisely equal to the force of gravitation, so that an inhabitant of those regions would then have the same tendency to fall upwards as downwards. All these things were sources of wonder and delight to us: and when we remembered that we were gifted with the powers which had reached such results, and that the same great field was ours to work in, our hopes arose that at some future day we might possibly push the subject a little further, and add our own victories to the conquests already won.
I ought to apologise to you for dwelling so long upon this subject; but the days spent among these young philosophers made a deep impression on me. I learned among them something of myself and of human nature, and obtained some notion of a teacher's vocation. If there be one profession in England of paramount importance, I believe it to be that of the schoolmaster; and if there be a position where selfishness and incompetence do most serious mischief, by lowering the moral tone and exciting irreverence and cunning where reverence and noble truthfulness ought to be the feelings evoked, it is that of the principal of a school. When a man of enlarged heart and mind comes among boys, when he allows his spirit to stream through them, and observes the operation of his own character evidenced in the elevation of theirs, — it would be idle to talk of the position of such a man being honourable. It is a blessed position. The man is a blessing to himself and to all around him. Such men, I believe, are to be found in England, and it behoves those who busy themselves with the mechanics of education at the present day, to seek them out. For no matter what means of culture may be chosen, whether physical or philological, success must ever mainly depend upon the amount of life, love, and earnestness, which the teacher himself brings with him to his vocation.
Let me again, and finally, remind you that the claims of that science which finds in me to-day its unripened advocate, are those of the logic of Nature upon the reason of her child — that its disciplines, as an agent of culture, are based upon the natural relations subsisting between Man and the universe of which he forms a part. On the one side, we have the apparently lawless shifting of phenomena; on the other side, mind, which requires law for its equilibrium, and through its own indestructible instincts, as well as through the teachings of experience, knows that these phenomena are reducible to law. To chasten this apparent chaos is a problem which man has set before him. The world was built in order: and to us are trusted the will and power to discern its harmonies, and to make them the lessons of our lives. From the cradle to the grave we are surrounded with objects which provoke inquiry. Descending for a moment from this high plea to considerations which lie closer to us as a nation — as a land of gas and furnaces, of steam and electricity: as a land which science, practically applied, has made great in peace and mighty in war :— I ask you whether this 'land of old and just renown' has not a right to expect from her institutions a culture more in accordance with her present needs than that supplied by declension and conjugation? And if the tendency should be to lower the estimate of science, by regarding it exclusively as the instrument of material prosperity, let it be the high mission of our universities to furnish the proper counterpoise by pointing out its nobler uses — lifting the national mind to the contemplation of it as the last development of that 'increasing purpose' which runs through the ages and widens the thoughts of men.
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XII. ON CRYSTALLINE AND SLATY CLEAVAGE.
[Footnote:From a discourse delivered in the Royal Institution of Great Britain, June 6, 1856.]
WHEN the student of physical science has to investigate the character of any natural force, his first care must be to purify it from the mixture of other forces, and thus study its simple action. If, for example, he wishes to know how a mass of liquid would shape itself if at liberty to follow the bent of its own molecular forces, he must see that these forces have free and undisturbed exercise. We might perhaps refer him to the dewdrop for a solution of the question; but here we have to do, not only with the action of the molecules of the liquid upon each other, but also with the action of gravity upon the mass, which pulls the drop downwards and elongates it. If he would examine the problem in its purity, he must do as Plateau has done, detach the liquid mass from the action of gravity; he would then find the shape to be a perfect sphere. Natural processes come to us in a mixed manner, and to the uninstructed mind are a mass of unintelligible confusion. Suppose half-a-dozen of the best musical performers to be placed in the same room, each playing his own instrument to perfection, but no two playing the same tune; though each individual instrument might be a source of perfect music, still the mixture of all would produce mere noise.
Thus it is with the processes of nature, where mechanical and molecular laws intermingle and create apparent confusion. Their mixture constitutes what may be called thenoiseof natural laws, and it is the vocation of the man of science to resolve this noise into its components, and thus to detect the underlying music.
The necessity of this detachment of one force from all other forces is nowhere more strikingly exhibited than in the phenomena of crystallisation. Here, for example, is a solution of common sulphate of soda or Glauber salt. Looking into it mentally, we see the molecules of that liquid, like disciplined squadrons under a governing eye, arranging themselves into battalions, gathering round distinct centres, and forming themselves into solid masses, which after a time assume the visible shape of the crystal now held in my hand. I may, like an ignorant meddler wishing to hasten matters, introduce confusion into this order. This may be done by plunging a glass rod into the vessel; the consequent action is not the pure expression of the crystalline forces; the molecules rush together with the confusion of an unorganised mob, and not with the steady accuracy of a disciplined host. In this mass of bismuth also we have an example of confused crystallisation; but in the crucible behind me a slower process is going on: here there is an architect at work 'who makes no chips, no din,' and who is now building the particles into crystals, similar in shape and structure to those beautiful masses which we see upon the table. By permitting alum to crystallise in this slow way, we obtain these perfect octahedrons; by allowing carbonate of lime to crystallise, nature produces these beautiful rhomboids; when silica crystallises, we have formed these hexagonal prisms capped at the ends by pyramids; by allowing saltpetre to crystallise we have these prismatic masses, and when carbon crystallises, we have the diamond. If we wish to obtain a perfect crystal we must allow the molecular forces free play; if the crystallising mass be permitted to rest upon a surface it will be flattened, and to prevent this a small crystal must be so suspended as to be surrounded on all sides by the liquid, or, if it rest upon the surface, it must be turned daily so as to present all its faces in succession to the working builder.
In building up crystals these little atomic bricks often arrange themselves into layers which are perfectly parallel to each other, and which can be separated by mechanical means; this is called the cleavage of the crystal. The crystal of sugar I hold in my hand has thus far escaped the solvent and abrading forces which sooner or later determine the fate of sugar-candy. I readily discover that it cleaves with peculiar facility in one direction. Again I lay my knife upon this piece of rocksalt, and with a blow cleave it in one direction. Laying the knife at right angles to its former position, the crystal cleaves again; and finally placing the knife at right angles to the two former positions, we find a third cleavage. Rocksalt cleaves in three directions, and the resulting solid is this perfect cube, which may be broken up into any number of smaller cubes. Iceland spar also cleaves in three directions, not at right angles, but oblique to each other, the resulting solid being a rhomboid. In each of these cases the mass cleaves with equal facility in all three directions. For the sake of completeness I may say that many crystals cleave with unequal facility in different directions: heavy spar presents an example of this kind of cleavage.
Turn we now to the consideration of some other phenomena to which the term cleavage may be applied. Beech, deal, and other woods cleave with facility along the fibre, and this cleavage is most perfect when the edge of the axe is laid across the rings which mark the growth of the tree. If you look at this bundle of hay severed from a rick, you will see a sort of cleavage in it also; the stalks lie in horizontal planes, and only a small force is required to separate them laterally. But we cannot regard the cleavage of the tree as the same in character as that of the hayrick. In the one case it is the molecules arranging themselves according to organic laws which produce a cleavable structure, in the other case the easy separation in one direction is due to the mechanical arrangement of the coarse sensible stalks of hay.
This sandstone rock was once a powder held in mechanical suspension by water. The powder was composed of two distinct parts, fine grains of sand and small plates of mica. Imagine a wide strand covered by a tide, or an estuary with water which holds such powder in suspension: how will it sink? The rounded grains of sand will reach the bottom first, because they encounter least resistance, the mica afterwards, and when the tide recedes we have the little plates shining like spangles upon the surface of the sand. Each successive tide brings its charge of mixed powder, deposits its duplex layer day after day, and finally masses of immense thickness are piled up, which by preserving the alternations of sand and mica tell the tale of their formation. Take the sand and mica, mix them together in water, and allow them to subside; they will arrange themselves in the manner indicated, and by repeating the process you can actually build up a mass which shall be the exact counterpart of that presented by nature. Now this structure cleaves with readiness along the planes in which the particles of mica are strewn. Specimens of such a rock sent to me from Halifax, and other masses from the quarries of Over Darwen in Lancashire, are here before you. With a hammer and chisel I can cleave them into flags; indeed these flags are employed for roofing purposes in the districts from which the specimens have come, and receive the name of 'slatestone.' But you will discern without a word from me, that this cleavage is not a crystalline cleavage any more than that of a hayrick is. It is molar, not molecular.
This, so far as I am aware of, has never been imagined, and it has been agreed among geologists not to call such splitting as this cleavage at all, but to restrict the term to a phenomenon of a totally different character.
Those who have visited the slate quarries of Cumberland and North Wales will have witnessed the phenomenon to which I refer. We have long drawn our supply of roofing-slates from such quarries; school-boys ciphered on these slates, they were used for tombstones in churchyards, and for billiard-tables in the metropolis; but not until a comparatively late period did men begin to enquire how their wonderful structure was produced. What is the agency which enables us to split Honister Crag, or the cliffs of Snowdon, into laminae from crown to base? This question is at the present moment one of the great difficulties of geologists, and occupies their attention perhaps more than any other. You may wonder at this. Looking into the quarry of Penrhyn, you may be disposed to offer the explanation I heard given two years ago. 'These planes of cleavage,' said a friend who stood beside me on the quarry's edge, 'are the planes of stratification which have been lifted by some convulsion into an almost vertical position.' But this was a mistake, and indeed here lies the grand difficulty of the problem. The planes of cleavage stand in most cases at a high angle to the bedding. Thanks to Sir Roderick Murchison, I am able to place the proof of this before you. Here is a specimen of slate in which both the planes of cleavage and of bedding are distinctly marked, one of them making a large angle with the other. This is common. The cleavage of slates then is not a question of stratification; what then is its cause?
In an able and elaborate essay published in 1835, Prof. Sedgwick proposed the theory that cleavage is due to the action of crystalline or polar forces subsequent to the consolidation of the rock. 'We may affirm,' he says, 'that no retreat of the parts, no contraction of dimensions in passing to a solid state, can explain such phenomena. They appear to me only resolvable on the supposition that crystalline or polar forces acted upon the whole mass simultaneously in one direction and with adequate force.' And again, in another place: 'Crystalline forces have re-arranged whole mountain masses, producing a beautiful crystalline cleavage, passing alike through all the strata.'[Footnote: Transactions of the Geological Society, ser. ii, vol. iii. p. 477.]
The utterance of such a man struck deep, as it ought to do, into the minds of geologists, and at the present day there are few who do not entertain this view either in whole or in part.[Footnote: In a letter to Sir Charles Lyell, dated from the Cape of Good Hope February 20, 1836, Sir John Herschel writes as follows:— 'If rocks have been so heated as to allow of a commencement of crystallisation, that is to say, if they have been heated to a point at which the particles can begin to move amongst themselves, or at least on their own axes, some general law must then determine the position in which these particles will rest on cooling. Probably that position will have some relation to the direction in which the heat escapes. Now when all or a majority of particles of the same nature have a general tendency to one position, that must of course determine a cleavage plane.']The boldness of the theory, indeed, has, in some cases, caused speculation to run riot, and we have books published on the action of polar forces and geologic magnetism, which rather astonish those who know something about the subject. According to this theory whole districts of North Wales and Cumberland, mountains included, are neither more nor less than the parts of a gigantic crystal. These masses of slate were originally fine mud, composed of the broken and abraded particles of older rocks. They contain silica, alumina, potash, soda, and mica mixed mechanically together. In the course of ages the mixture became consolidated, and the theory before us assumes that a process of crystallisation afterwards rearranged the particles and developed in it a single plane of cleavage. Though a bold, and I think inadmissible, stretch of analogies, this hypothesis has done good service. Right or wrong, a thoughtfully uttered theory has a dynamic power which operates against intellectual stagnation; and even by provoking opposition is eventually of service to the cause of truth. It would, however, have been remarkable if, among the ranks of geologists themselves, men were not found to seek an explanation of slate-cleavage involving a less hardy assumption.
The first step in an enquiry of this kind is to seek facts. This has been done, and the labours of Daniel Sharpe (the late President of the Geological Society, who, to the loss of science and the sorrow of all who knew him, has so suddenly been taken away from us), Mr. Henry Clifton Sorby, and others, have furnished us with a body of facts associated with slaty cleavage, and having a most important bearing upon the question.
Fossil shells are found in these slate-rocks. I have here several specimens of such shells in the actual rock, and occupying various positions in regard to the cleavage planes. They are squeezed, distorted, and crushed; in all cases the distortion leads to the inference that the rock which contains these shells has been subjected to enormous pressure in a direction at right angles to the planes of cleavage. The shells are all flattened and spread out in these planes. Compare this fossil trilobite of normal proportions with these others which have suffered distortion. Some have lain across, some along, and some oblique to the cleavage of the slate in which they are found; but in all cases the distortion is such as required for its production a compressing force acting at right angles to the planes of cleavage. As the trilobites lay in the mud, the jaws of a gigantic vice appear to have closed upon them and squeezed them into the shapes you see.
We sometimes find a thin layer of coarse gritty material, between two layers of finer rock, through which and across the gritty layer pass the planes of lamination. The coarse layer is found bent by the pressure into sinuosities like a contorted ribbon. Mr. Sorby has described a striking case of this kind. This crumpling can be experimentally imitated; the amount of compression might, moreover, be roughly estimated by supposing the contorted bed to be stretched out, its length measured and compared with the shorter distance into which it has been squeezed. We find in this way that the yielding of the mass has been considerable.
Let me now direct your attention to another proof of pressure; you see the varying colours which indicate the bedding on this mass of slate. The dark portion is gritty, being composed of comparatively coarse particles, which, owing to their size, shape and gravity, sink first and constitute the bottom of each layer. Gradually, from bottom to top the coarseness diminishes, and near the upper surface we have a layer of exceedingly fine grain. It is the fine mud thus consolidated from which are derived the German razor-stones, so much prized for the sharpening of surgical instruments.
When a bed is thin, the fine-grain slate is permitted to rest upon a slab of the coarse slate in contact with it; when the fine bed is thick, it is cut into slices which are cemented to pieces of ordinary slate, and thus rendered stronger. The mud thus deposited is, as might be expected, often rolled up into nodular masses, carried forward, and deposited among coarser material by the rivers from which the slate-mud has subsided. Here are such nodules enclosed in sandstone. Everybody, moreover, who has ciphered upon a school-slate must remember the whitish-green spots which sometimes dotted the surface of the slate, and over which the pencil usually slid as if the spots were greasy. Now these spots are composed of the finer mud, and they could not, on account of their fineness, bite the pencil like the surrounding gritty portions of the slate. Here is a beautiful example of these spots: you observe them, on the cleavage surface, in broad round patches. But turn the slate edgeways and the section of each nodule is seen to be a sharp oval with its longer axis parallel to the cleavage. This instructive fact has been adduced by Mr. Sorby. I have made excursions to the quarries of Wales and Cumberland, and to many of the slate yards of London, and found the fact general. Thus we elevate a common experience of our boyhood into evidence of the highest significance as regards a most important geological problem. From the magnetic deportment of these slates, I was led to infer that these spots contain a less amount of iron than the surrounding dark slate. An analysis was made for me by Mr. Hambly in the laboratory of Dr. Percy at the School of Mines with the following result :—
ANALYSIS OF SLATE.Dark Slate, two analyses.1. Percentage of iron5.852. Percentage of iron6.13Mean5.99Whitish Green Slate.1. Percentage of iron3.242. Percentage of iron3.12Mean3.18
ANALYSIS OF SLATE.Dark Slate, two analyses.1. Percentage of iron5.852. Percentage of iron6.13Mean5.99Whitish Green Slate.1. Percentage of iron3.242. Percentage of iron3.12Mean3.18
ANALYSIS OF SLATE.
Dark Slate, two analyses.
1. Percentage of iron
5.85
2. Percentage of iron
6.13
Mean
5.99
Whitish Green Slate.
1. Percentage of iron
3.24
2. Percentage of iron
3.12
Mean
3.18
According to these analyses the quantity of iron in the dark slate immediately adjacent to the greenish spot is nearly double the quantity contained in the spot itself. This is about the proportion which the magnetic experiments suggested.
Let me now remind you that the facts brought before you are typical — each is the representative of a class. We have seen shells crushed; the trilobites squeezed, beds contorted, nodules of greenish marl flattened; and all these sources of independent testimony point to one and the same conclusion, namely, that slate-rocks have been subjected to enormous pressure in a direction at right angles to the Planes of cleavage.
In reference to Mr. Sorby's contorted bed, I have said that by supposing it to be stretched out and its length measured, it would give us an idea of the amount of yielding of the mass above and below the bed. Such a measurement, however, would not give the exact amount of yielding. I hold in my hand a specimen of slate with its bedding marked upon it; the lower portions of each layer being composed of a comparatively coarse gritty material something like what you may suppose the contorted bed to be composed of. Now in crossing these gritty portions, the cleavage turns, as if tending to cross the bedding at another angle. When the pressure began to act, the intermediate bed, which is not entirely unyielding, suffered longitudinal pressure; as it bent, the pressure became gradually more transverse, and the direction of its cleavage is exactly such as you would infer from an action of this kind — it is neither quite across the bed, nor yet in the same direction as the cleavage of the slate above and below it, but intermediate between both. Supposing the cleavage to be at right angles to the pressure, this is the direction which it ought to take across these more unyielding strata.
Thus we have established the concurrence of the phenomena of cleavage and pressure — that they accompany each other; but the question still remains, Is the pressure sufficient to account for the cleavage? A single geologist, as far as I am aware, answers boldly in the affirmative. This geologist is Sorby, who has attacked the question in the true spirit of a physical investigator. Call to mind the cleavage of the flags of Halifax and Over Darwen, which is caused by the interposition of layers of mica between the gritty strata. Mr. Sorby finds plates of mica to be also a constituent of slate-rock. He asks himself, what will be the effect of pressure upon a mass containing such plates confusedly mixed up in it? It will be, he argues, and he argues rightly, to place the plates with their flat surfaces more or less perpendicular to the direction in which the pressure is exerted. He takes scales of the oxide of iron, mixes them with a fine powder, and on squeezing the mass finds that the tendency of the scales is to set themselves at right angles to the line of pressure. Along the planes of weakness produced by the scales the mass cleaves.
By tests of a different character from those applied by Mr. Sorby, it might be shown how true his conclusion is — that the effect of pressure on elongated particles, or plates, will be such as he describes it. But while the scales must be regarded as a true cause, I should not ascribe to them a large share in the production of the cleavage. I believe that even if the plates of mica were wholly absent, the cleavage of slate-rocks would be much the same as it is at present.
Here is a mass of pure white wax: it contains no mica particles, no scales of iron, or anything analogous to them. Here is the selfsame substance submitted to pressure. I would invite the attention of the eminent geologists now before me to the structure of this wax. No slate ever exhibited so clean a cleavage; it splits into laminae of surpassing tenuity, and proves at a single stroke that pressure is sufficient to produce cleavage, and that this cleavage is independent of intermixed plates or scales. I have purposely mixed this wax with elongated particles, and am unable to say at the present moment that the cleavage is sensibly affected by their presence — if anything, I should say they rather impair its fineness and clearness than promote it.
The finer the slate is the more perfect will be the resemblance of its cleavage to that of the wax. Compare the surface of the wax with the surface of this slate from Borrodale in Cumberland. You have precisely the same features in both: you see flakes clinging to the surfaces of each, which have been partially torn away in cleaving. Let any close observer compare these two effects, he will, I am persuaded, be led to the conclusion that they are the product of a common cause.[Footnote: I have usually softened the wax by warming it, kneaded it with the fingers, and pressed it between thick plates of glass previously wetted. At the ordinary summer temperature the pressed wax is soft, and tears rather than cleaves; on this account I cool my compressed specimens in a mixture of pounded ice and salt, and when thus cooled they split cleanly.]
But you will ask me how, according to my view, does pressure produce this remarkable result? This may be stated in a very few words.
There is no such thing in nature as a body of perfectly homogeneous structure. I break this clay which seems so uniform, and find that the fracture presents to my eyes innumerable surfaces along which it has given way, and it has yielded along those surfaces because in them the cohesion of the mass is less than elsewhere. I break this marble, and even this wax, and observe the same result; look at the mud at the bottom of a dried pond; look at some of the ungravelled walks in Kensington Gardens on drying after rain, — they are cracked and split, and other circumstances being equal, they crack and split where the cohesion is a minimum. Take then a mass of partially consolidated mud. Such a mass is divided and subdivided by interior surfaces along which the cohesion is comparatively small. Penetrate the mass in idea, and you will see it composed of numberless irregular polyhedra bounded by surfaces of weak cohesion. Imagine such a mass subjected to pressure, — it yields and spreads out in the direction of least resistance;[Footnote: It is scarcely necessary to say that if the mass were squeezed equally in all directions no laminated structure could be produced; it must have room to yield in a lateral direction. Mr. Warren De la Rue informs me that he once wished to obtain white-lead in a fine granular state, and to accomplish this he first compressed it. The mould was conical, and permitted the lead to spread out a little laterally. The lamination was as perfect as that of slate, and it quite defeated him in his effort to obtain a granular powder. ]the little polyhedra become converted into laminae, separated from each other by surfaces of weak cohesion, and the infallible result will be a tendency to cleave at right angles to the line of pressure.
Further, a mass of dried mud is full of cavities and fissures. If you break dried pipe-clay you see them in great numbers, and there are multitudes of them so small that you cannot see them. A flattening of these cavities must take place in squeezed mud, and this must to some extent facilitate the cleavage of the mass in the direction indicated.
Although the time at my disposal has not permitted me duly to develope these thoughts, yet for the last twelve months the subject has presented itself to me almost daily under one aspect or another. I have never eaten a biscuit during this period without remarking the cleavage developed by the rolling-pin. You have only to break a biscuit across, and to look at the fracture, to see the laminated structure. We have here the means of pushing the analogy further. I invite you to compare the structure of this slate, which was subjected to a high temperature during the conflagration of Mr. Scott Russell's premises, with that of a biscuit. Air or vapour within the slate has caused it to swell, and the mechanical structure it reveals is precisely that of a biscuit. During these enquiries I have received much instruction in the manufacture of puff-paste. Here is some such paste baked under my own superintendence. The cleavage of our hills is accidental cleavage, but this is cleavage with intention. The volition of the pastrycook has entered into its formation. It has been his aim to preserve a series of surfaces of structural weakness, along which the dough divides into layers. Puff-paste in preparation must not be handled too much; it ought, moreover, to be rolled on a cold slab, to prevent the butter from melting, and diffusing itself, thus rendering the paste more homogeneous and less liable to split. Puff-paste is, then, simply an exaggerated case of slaty cleavage.
The principle here enunciated is so simple as to be almost trivial; nevertheless, it embraces not only the cases mentioned, but, if time permitted, it might be shown you that the principle has a much wider range of application. When iron is taken from the puddling furnace it is more or less spongy, an aggregate in fact of small nodules: it is at a welding heat, and at this temperature is submitted to the process of rolling. Bright smooth bars are the result. But notwithstanding the high heat the nodules do not perfectly blend together. The process of rolling draws them into fibres. Here is a mass acted upon by dilute sulphuric acid, which exhibits in a striking manner this fibrous structure. The experiment was made by my friend Dr. Percy, without any reference to the question of cleavage.
Break a piece of ordinary iron and you have a granular fracture; heat the iron, you elongate these granules, and finally render the mass fibrous. Here are pieces of rails along which the wheels of locomotives have slid-den; the granules have yielded and become plates. They exfoliate or come off in leaves; all these effects belong, I believe, to the great class of phenomena of which slaty cleavage forms the most prominent example.[Footnote: For some further observations on this subject by Mr. Sorby and myself, see Philosophical Magazine for August, 1856.]
We have now reached the termination of our task. You have witnessed the phenomena of crystallisation, and have had placed before you the facts which are found associated with the cleavage of slate rocks. Such facts, as expressed by Helmholtz, are so many telescopes to our spiritual vision, by which we can see backward through the night of antiquity, and discern the forces which have been in operation upon the earth's surface
Ere the lion roared,Or the eagle soared.
Ere the lion roared,Or the eagle soared.
From evidence of the most independent and trustworthy character, we come to the conclusion that these slaty masses have been subjected to enormous pressure, and by the sure method of experiment we have shown — and this is the only really new point which has been brought before you — how the pressure is sufficient to produce the cleavage. Expanding our field of view, we find the self-same law, whose footsteps we trace amid the crags of Wales and Cumberland, extending into the domain of the pastrycook and ironfounder; nay, a wheel cannot roll over the half-dried mud of our streets without revealing to us more or less of the features of this law. Let me say, in conclusion, that the spirit in which this problem has been attacked by geologists, indicates the dawning of a new day for their science. The great intellects who have laboured at geology, and who have raised it to its present pitch of grandeur, were compelled to deal with the subject in mass; they had no time to look after details. But the desire for more exact knowledge is increasing; facts are flowing in which, while they leave untouched the intrinsic wonders of geology, are gradually supplanting by solid truths the uncertain speculations which beset the subject in its infancy. Geologists now aim to imitate, as far as possible, the conditions of nature, and to produce her results; they are approaching more and more to the domain of physics, and I trust the day will soon come when we shall interlace our friendly arms across the common boundary of our sciences, and pursue our respective tasks in a spirit of mutual helpfulness, encouragement and goodwill.
[I would now lay more stress on the lateral yielding, referred to in the footnote concerning Mr. Warren De la Rue's attempt to produce finely granular white-lead, accompanied as it is by tangential sliding, than I was prepared to do when this lecture was given. This sliding is, I think, the principal cause of the planes of weakness, both in pressed wax and slate rock. J. T. 1871.]
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XIII. ON PARAMAGNETIC AND DIAMAGNETIC FORCES.
[Footnote:Abstract of a discourse delivered in the Royal Institution, February 1, 1856.]
THE notion of an attractive force, which draws bodies towards the centre of the earth, was entertained by Anaxagoras and his pupils, by Democritus, Pythagoras, and Epicurus; and the conjectures of these ancients were renewed by Galileo, Huyghens, and others, who stated that bodies attract each other as a magnet attracts iron. Kepler applied the notion to bodies beyond the surface of the earth, and affirmed the extension of this force to the most distant stars. Thus it would appear, that in the attraction of iron by a magnet originated the conception of the force of gravitation. Nevertheless, if we look closely at the matter, it will be seen that the magnetic force possesses characters strikingly distinct from those of the force which holds the universe together. The theory of gravitation is, that every particle of matter attracts every other particle; in magnetism also we have attraction, but we have always, at the same time, repulsion, the final effect being due to the difference of these two forces. A body may be intensely acted on by a magnet, and still no motion of translation will follow, if the repulsion be equal to the attraction. Previous to magnetization, a dipping needle, when its centre of gravity is supported, stands accurately level; but, after magnetization, one end of it, in our latitude, is pulled towards the north pole of the earth. The needle, however, being suspended from the arm of a fine balance, its weight is found unaltered by its magnetization. In like manner, when the needle is permitted to float upon a liquid, and thus to follow the attraction of the north magnetic pole of the earth, there is no motion of the mass towards that pole. The reason is known to be, that although the marked end of the needle is attracted by the north pole, the unmarked end is repelled by an equal force, the two equal and opposite forces neutralizing each other.
When the pole of an ordinary magnet is brought to act upon the swimming needle, the latter is attracted, — the reason being that the attracted end of the needle being nearer to the pole of the magnet than the repelled end, the force of attraction is the more powerful of the two. In the case of the earth, its pole is so distant that the length of the needle is practically zero. In like manner, when a piece of iron is presented to a magnet, the nearer parts are attracted, while the more distant parts are repelled; and because the attracted portions are nearer to the magnet than the repelled ones, we have a balance in favour of attraction. Here then is the special characteristic of the magnetic force, which distinguishes it from that of gravitation. The latter is a simple unpolar force, while the former is duplex or polar. Were gravitation like magnetism, a stone would no more fall to the ground than a piece of iron towards the north magnetic pole: and thus, however rich in consequences the supposition of Kepler and others may have been, it is clear that a force like that of magnetism would not be able to transact the business of the universe.
The object of this discourse is to enquire whether the force of diamagnetism, which manifests itself as a repulsion of certain bodies by the poles of a magnet, is to be ranged as a polar force, beside that of magnetism; or as an unpolar force, beside that of gravitation. When a cylinder of soft iron is placed within a wire helix, and surrounded by an electric current, the antithesis of its two ends, or, in other words, its polar excitation, is at once manifested by its action upon a magnetic needle; and it may be asked why a cylinder of bismuth may not be substituted for the cylinder of iron, and its state similarly examined. The reason is, that the excitement of the bismuth is so feeble, that it would be quite masked by that of the helix in which it is enclosed; and the problem that now meets us is, so to excite a diamagnetic body that the pure action of the body upon a magnetic needle may be observed, unmixed with the action of the body used to excite the diamagnetic.
Image81.gifHow this has been effected may be illustrated in the following manner:—
When through an upright helix of covered copper wire, a voltaic current is sent, the top of the helix attracts, while its bottom repels, the same pole of a magnetic needle; its central point, on the contrary, is neutral, and exhibits neither attraction nor repulsion. Such a helix is caused to stand between the two poles N's' of an astatic system.[Footnote: The reversal of the poles of the two magnets, which were of the same strength, completely annulled the action of the earth as a magnet.]The two magnets S N' and S'N are united by a rigid cross piece at their centres, and are suspended from the point a, so that both magnets swing in the same horizontal plane. It is so arranged that the poles N' s' are opposite to the central or neutral point of the helix, so that when a current is sent through the latter, the magnets, as before explained, are unaffected. Here then we have an excited helix which itself has no action upon the magnets, and we are thus enabled to examine the action of a body placed within the helix and excited by it, undisturbed by the influence of the latter. The helix being 12 inches high, a cylinder of soft iron 6 inches long, suspended from a string and passing over a pulley, can be raised or lowered within the helix. When it is so far sunk that its lower end rests upon the table, the upper end finds itself between the poles N´S´of the astatic system. The iron cylinder is thus converted into a strong magnet, attracting one of the poles, and repelling the other, and consequently deflecting the entire astatic system. When the cylinder is raised so that the upper end is at the level of the top of the helix, its lower end comes between the poles N´S´; and a deflection opposed in direction to the former one is the immediate consequence. To render these deflections more easily visible, a mirror m is attached to the system of magnets; a beam of light thrown upon the mirror being reflected and projected as a bright disk against the wall. The distance of this image from the mirror being considerable, and its angular motion double that of the latter, a very slight motion of the magnet is sufficient to produce a displacement of the image through several yards.
This then is the principle of the beautiful apparatus[Footnote: Devised by Prof. W. Weber, and constructed by M. Leyser, of Leipzig.]by which the investigation was conducted. It is manifest that if a second helix be placed between the poles SN with a cylinder within it, the action upon the astatic magnet may be exalted. This was the arrangement made use of in the actual enquiry. Thus to intensify the feeble action, which it is here our object to seek, we have in the first place neutralized the action of the earth upon the magnets, by placing them astatically. Secondly, by making use of two cylinders, and permitting them to act simultaneously on the four poles of the magnets, we have rendered the deflecting force four times what it would be, if only a single pole were used. Finally, the whole apparatus was enclosed in a suitable case which protected the magnets from air-currents, and the deflections were read off through a glass plate in the case, by means of a telescope and scale placed at a considerable distance from the instrument.
A pair of bismuth cylinders was first examined. Sending a current through the helices, and observing that the magnets swung perfectly free, it was first arranged that the bismuth cylinders within the helices had their central or neutral points opposite to the poles of the magnets. All being at rest the number on the scale marked by the cross wire of the telescope was 572. The cylinders were then moved, one up the other down, so that two of their ends were brought to bear simultaneously upon the magnetic poles: the magnet moved promptly, and after some oscillations[Footnote: To lessen these a copper damper was made use of.]came to rest at the number 612; thus moving from a smaller to a larger number. The other two ends of the bars were next brought to bear upon the magnet: a prompt deflection was the consequence, and the final position of equilibrium was 526; the movement being from a larger to a smaller number. We thus observe a manifest polar action of the bismuth cylinders upon the magnet; one pair of ends deflecting it in one direction, and the other pair deflecting it in the opposite direction.
Substituting for the cylinders of bismuth thin cylinders of iron, of magnetic slate, of sulphate of iron, carbonate of iron, protochloride of iron, red ferrocyanide of potassium, and other magnetic bodies, it was found that when the position of the magnetic cylinders was the same as that of the cylinders of bismuth, the deflection produced by the former was always opposed in direction to that produced by the latter; and hence the disposition of the force in the diamagnetic body must have been precisely antithetical to its disposition in the magnetic ones.
But it will be urged, and indeed has been urged against this inference, that the deflection produced by the bismuth cylinders may be due to induced currents excited in the metal by its motion within the helices. In reply to this objection, it may be stated, in the first place, that the deflection is permanent, and cannot therefore be due to induced currents, which are only of momentary duration. It has also been urged that such experiments ought to be made with other metals, and with better conductors than bismuth; for if due to currents of induction, the better the conductor the more exalted will be the effect. This requirement was complied with.
Cylinders of antimony were substituted for those of bismuth. This metal is a better conductor of electricity, but less strongly diamagnetic than bismuth. If therefore the action referred to be due to induced currents we ought to have it greater in the case of antimony than with bismuth; but if it springs from a true diamagnetic polarity, the action of the bismuth ought to exceed that of the antimony. Experiment proves this to be the case. Hence the deflection produced by these metals is due to their diamagnetic, and not to their conductive capacity. Copper cylinders were next examined: here we have a metal which conducts electricity fifty times better than bismuth, but its diamagnetic power is nearly null; if the effects be due to induced currents we ought to have them here in an enormously exaggerated degree, but no sensible deflection was produced by the two cylinders of copper.
It has also been proposed by the opponents of diamagnetic polarity to coat fragments of bismuth with some insulating substance, so as to render the formation of induced currents impossible, and to test the question with cylinders of these fragments. This requirement was also fulfilled. It is only necessary to reduce the bismuth to powder and expose it for a short time to the air to cause the particles to become so far oxidised as to render them perfectly insulating. The insulating power of the powder was exhibited experimentally; nevertheless, this powder, enclosed in glass tubes, exhibited an action scarcely less powerful than that of the massive bismuth cylinders.
But the most rigid proof, a proof admitted to be conclusive by those who have denied the antithesis of magnetism and diamagnetism, remains to be stated. Prisms of the same heavy glass as that with which the diamagnetic force was discovered, were substituted for the metallic cylinders, and their action upon the magnet was proved to be precisely the same in kind as that of the cylinders of bismuth. The enquiry was also extended to other insulators: to phosphorus, sulphur, nitre, calcareous spar, statuary marble, with the same invariable result: each of these substances was proved to be polar, the disposition of the force being the same as that of bismuth and the reverse of that of iron. When a bar of iron is set erect, its lower end is known to be a north pole, and its upper end a south pole, in virtue of the earth's induction. A marble statue, on the contrary, has its feet a south pole, and its head a north pole, and there is no doubt that the same remark applies to its living archetype; each man walking over the earth's surface is a true diamagnet, with its poles the reverse of those of a mass of magnetic matter of the same shape and position.
An experiment of practical value, as affording a ready estimate of the different conductive powers of two metals for electricity, was exhibited in the lecture, for the purpose of proving experimentally some of the statements made in reference to this subject. A cube of bismuth was suspended by a twisted string between the two poles of an electro-magnet. The cube was attached by a short copper wire to a little square pyramid, the base of which was horizontal, and its sides formed of four small triangular pieces of looking-glass. A beam of light was suffered to fall upon this reflector, and as the reflector followed the motion of the cube the images cast from its sides followed each other in succession, each describing a circle about thirty feet in diameter. As the velocity of rotation augmented, these images blended into a continuous ring of light. At a particular instant the electro-magnet was excited, currents were evolved in the rotating cube, and the strength of these currents, which increases with the conductivity of the cube for electricity, was practically estimated by the time required to bring the cube and its associated mirrors to a state of rest. With bismuth this time amounted to a score of seconds or more: a cube of copper, on the contrary, was struck almost instantly motionless when the circuit was established.
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XIV. PHYSICAL BASIS OF SOLAR CHEMISTRY.
[Footnote:From a discourse delivered at the Royal Institution of Great Britain, June 7, 1861.]
OMITTING all preface, attention was first drawn to an experimental arrangement intended to prove that gaseous bodies radiate heat in different degrees. Near a double screen of polished tin was placed an ordinary ring gas-burner, and on this was placed a hot copper ball, from which a column of heated air ascended. Behind the screen, but so situated that no ray from the ball could reach the instrument, was an excellent Thermo-electric pile, connected by wires with a very delicate galvanometer. The pile was known to be an instrument whereby heat is applied to the generation of electric currents; the strength of the current being an accurate measure of the quantity of the heat. As long as both faces of the pile are at the same temperature, no current is produced; but the slightest difference in the temperature of the two faces at once declares itself by the production of a current, which, when carried through the galvanometer, indicates by the deflection. of the needle both its strength and its direction.
The two faces of the pile were in the first instance brought to the same temperature; the equilibrium being shown by the needle of the galvanometer standing at zero. The rays emitted by the current of hot air already referred to were permitted to fall upon one of the faces of the pile; and an extremely slight movement of the needle showed that the radiation from the hot air, though sensible, was extremely feeble. Connected with the ring-burner was a holder containing oxygen gas; and by turning a cock, a stream of this gas was permitted to issue from the burner, strike the copper ball, and ascend in a heated column in front of the pile. The result was, that oxygen showed itself, as a radiator of heat, to be quite as feeble as atmospheric air.
A second holder containing olefiant gas was then connected with the ring-burner. Oxygen and air had already flowed over the ball and cooled it in some degree. Hence the olefiant gas laboured under a disadvantage. But on permitting the gas to rise from the ball, it casts an amount of heat against the adjacent face of the pile sufficient to impel the needle of the galvanometer almost to 90°. This experiment proved the vast difference between two equally invisible gases with regard to their power of emitting radiant heat.
The converse experiment was now performed. The thermo-electric pile was removed and placed between two cubes filled with water kept in a state of constant ebullition; and it was so arranged that the quantities of heat falling from the cubes on the opposite faces of the pile were exactly equal, thus neutralising each other. The needle of the galvanometer being at zero, a sheet of oxygen gas was caused to issue from a slit between one of the cubes and the adjacent face of the pile. If this sheet of gas possessed any sensible power of intercepting the thermal rays from the cube, one face of the pile being deprived of the heat thus intercepted, a difference of temperature between its two faces would instantly set in, and the result would be declared by the galvanometer. The quantity absorbed by the oxygen under those circumstances was too feeble to affect the galvanometer; the gas, in fact, proved perfectly transparent to the rays of heat. It had but a feeble power of radiation: it had an equally feeble power of absorption.
The pile remaining in its position, a sheet of olefiant gas was caused to issue from the same slit as that through which the oxygen had passed. No one present could see the gas; it was quite invisible, the light went through it as freely as through oxygen or air; but its effect upon the thermal rays emanating from the cube was what might be expected from a sheet of metal. A quantity so large was cut off, that the needle of the galvanometer, promptly quitting the zero line, moved with energy to its stops. Thus the olefiant gas, so light and clear and pervious to luminous rays, was proved to be a most potent destroyer of the rays emanating from an obscure source. The reciprocity of action established in the case of oxygen comes out here; the good radiator is found by this experiment to be the good absorber.
This result, now exhibited before a public audience for the first time, was typical of what had been obtained with gases generally. Going through the entire list of gases and vapours in this way, we find radiation and absorption to be as rigidly associated as positive and negative in electricity, or as north and south polarity in magnetism. So that if we make the number which expresses the absorptive power the numerator of a fraction, and that which expresses its radiative power the denominator, the result would be, that on account of the numerator and denominator varying in the same, proportion, the value of that fraction would always remain the same, whatever might be the gas or vapour experimented with.
But why should this reciprocity exist? What is the meaning of absorption? what is the meaning of radiation? When you cast a stone into still water, rings of waves surround the place where it falls; motion is radiated on all sides from the centre of disturbance. When a hammer strikes a bell, the latter vibrates; and sound, which is nothing more than an undulatory motion of the air, is radiated in all directions. Modern philosophy reduces light and heat to the same mechanical category. A luminous body is one with its atoms in a state of vibration; a hot body is one with its atoms also vibrating, but at a rate which is incompetent to excite the sense of vision; and, as a sounding body has the air around it, through which it propagates its vibrations, so also the luminous or heated body has a medium, called aether, which accepts its motions and carries them forward with inconceivable velocity. Radiation, then, as regards both light and heat, is the transference of motion from the vibrating body to the aether in which it swings: and, as in the case of sound, the motion imparted to the air is soon transferred to surrounding objects, against which the aerial undulations strike, the sound being, in technical language,absorbed; so also with regard to light and heat, absorption consists in the transference of motion from the agitated aether to the molecules of the absorbing body.
The simple atoms are found to be bad radiators; the compound atoms good ones: and the higher the degree of complexity in the atomic grouping, the more potent, as a general rule, is the radiation and absorption. Let us get definite ideas here, however gross, and purify them afterwards by the process of abstraction. Imagine our simple atoms swinging like single spheres in the aether; they cannot create the swell which a group of them united to form a system can produce. An oar runs freely edgeways through the water, and imparts far less of its motion to the water than when its broad flat side is brought to bear upon it. In our present language the oar, broad side vertical, is a good radiator; broad side horizontal, it is a bad radiator. Conversely the waves of water, impinging upon the flat face of the oar-blade, will impart a greater amount of motion to it than when impinging upon the edge. In the position in which the oar radiates well, it also absorbs well. Simple atoms glide through the aether without much resistance; compound ones encounter resistance, and hence yield up more speedily their motion to the aether.Mixoxygen and nitrogen mechanically, they absorb and radiate a certain amount of heat. Cause these gases tocombinechemically and form nitrous oxide, both the absorption and radiation are thereby augmented hundreds of times!
In this way we look with the telescope of the intellect into atomic systems, and obtain a conception of processes which the eye of sense can never reach. But gases and vapours possess a power of choice as to the rays which they absorb. They single out certain groups of rays for destruction, and allow other groups to pass unharmed. This is best illustrated by a famous experiment of Sir David Brewster's, modified to suit present requirements. Into a glass cylinder, with its ends stopped by discs of plate-glass, a small quantity of nitrous acid gas is introduced; the presence of the gas being indicated by its rich brown colour. The beam from an electric lamp being sent through two prisms of bisulphide of carbon, a spectrum seven feet long and eighteen inches wide is cast upon the screen. Introducing the cylinder containing the nitrous acid into the path of the beam as it issues from the lamp, the splendid and continuous spectrum becomes instantly furrowed by numerous dark bands, the rays answering to which are intercepted by the nitric gas, while the light which falls upon the intervening spaces is permitted to pass with comparative impunity.
Here also the principle of reciprocity, as regards radiation and absorption, holds good; and could we, without otherwise altering its physical character, render that nitrous gas luminous, we should find that the very rays which it absorbs are precisely those which it would emit. When atmospheric air and other gases are brought to a state of intense incandescence by the passage of an electric spark, the spectra which we obtain from them consist of a series of bright bands. But such spectra are produced with the greatest brilliancy when, instead of ordinary gases, we make use of metals heated so highly as to volatilise them. This is easily done by the voltaic current. A capsule of carbon filled with mercury, which formed the positive electrode of the electric lamp, has a carbon point brought down upon it. On separating the one from the other, a brilliant arc containing the mercury in a volatilised condition passes between them. The spectrum of this arc is not continuous like that of the solid carbon points, but consists of a series of vivid bands, each corresponding in colour to that particular portion of the spectrum to which its rays belong. Copper gives its system of bands; zinc gives its system; and brass, which is an alloy of copper and zinc, gives a spectrum made up of the bands belonging to both metals.
Not only, however, when metals are united like zinc and copper to form an alloy, is it possible to obtain the bands which belong to them. No matter how we may disguise the metal — allowing it to unite with oxygen to form an oxide, and this again with an acid to form a salt; if the heat applied be sufficiently intense, the bands belonging to the metal reveal themselves with perfect definition. Into holes drilled in a cylinder of retort carbon, pure culinary salt is introduced. When the carbon is made the positive electrode of the lamp, the resultant spectrum shows the brilliant yellow lines of the metal sodium. Similar experiments made with the chlorides of strontium, calcium, lithium,[Footnote: The vividness of the colours of the lithium spectrum is extraordinary; the spectrum, moreover, contained a blue band of indescribable splendour. It was thought by many, during the discourse, that I had mistaken strontium for lithium, as this blue band had never before been seen. I have obtained it many times since; and my friend Dr. Miller, having kindly analysed the substance made use of, pronounces it pure chloride of lithium. — J. T.]and other metals, give the bands due to the respective metals. When different salts are mixed together, and rammed into holes in the carbon; a spectrum is obtained which contains the bands of them all.