FIG. 18.—A fireless cooker.FIG. 18.—A fireless cooker.
A very interesting experiment for the testing of the efficacy of non-conductors may be easily performed. Place hot water in a metal vessel, and note by means of a thermometer therapiditywith which the water cools; then place water of the same temperature in a second metal vessel similar to the first, but surrounded by asbestos or other non-conducting material, and note theslownesswith which the temperature falls.
Chemical Change, an Effect of Heat.This effect of heat has a vital influence on our lives, because the changes which take place when food is cooked are due to it. The doughy mass which goes into the oven, comes out a light spongy loaf; the small indigestible rice grain comes out the swollen, fluffy, digestible grain. Were it not for the chemical changes brought about by heat, many of our present foods would be useless to man. Hundreds of common materials like glass, rubber, iron, aluminum, etc., are manufactured by processes which involve chemical action caused by heat.
14. Temperature not a Measure of the Amount of Heat Present.If two similar basins containing unequal quantities of water are placed in the sunshine on a summer day, the smaller quantity of water will become quite warm in a short period of time, while the larger quantity will become only lukewarm. Both vessels receive the same amount of heat from the sun, but in one case the heat is utilized in heating to a high temperature a small quantity of water, while in the second case the heat is utilized in warming to a lower degree a larger quantity of water. Equal amounts of heat do not necessarily produce equivalent temperatures, and equal temperatures do not necessarily indicate equal amounts of heat. It takes more heat to raise a gallon of water to the boiling point than it does to raise a pint of water to the boiling point, but a thermometer would register the same temperature in the two cases. The temperature of boiling water is 100° C. whether there is a pint of it or a gallon. Temperature is independent of the quantity of matter present; but the amount of heat contained in a substance at any temperature is not independent of quantity, being greater in the larger quantity.
15. The Unit of Heat.It is necessary to have a unit of heat just as we have a unit of length, or a unit of mass, or a unit of time. One unit of heat is called acalorie, and is the amount of heat which will change the temperature of 1 gram of water 1° C. It is the amount of heat given out by 1 gram of water when its temperature falls 1° C., or the amount of heat absorbed by 1 gram of water when its temperature rises 1° C. If 400 grams of water are heated from 0° to 5° C.,the amount of heat which has entered the water is equivalent to 5 × 400 or 2000 calories; if 200 grams of water cool from 25° to 20° C., the heat given out by the water is equivalent to 5 × 200 or 1000 calories.
16. Some Substances Heat more readily than Others.If two equal quantities of water at the same temperature are exposed to the sun for the same length of time, their final temperatures will be the same. If, however, equal quantities of different substances are exposed, the temperatures resulting from the heating will not necessarily be the same. If a basin containing 1 lb. of mercury is put on the fire, side by side with a basin containing an equal quantity of water, the temperatures of the two substances will vary greatly at the end of a short time. The mercury will have a far higher temperature than the water, in spite of the fact that the amount of mercury is as great as the amount of water and that the heat received from the fire has been the same in each case. Mercury is not so difficult to heat as water; less heat being required to raise its temperature 1° than is required to raise the temperature of an equal quantity of water 1°. In fact, mercury is 30 times as easy to heat as water, and it requires only one thirtieth as much fire to heat a given quantity of mercury 1° as to heat the same quantity of water 1°.
17. Specific Heat.We know that different substances are differently affected by heat. Some substances, like water, change their temperature slowly when heated; others, like mercury, change their temperature very rapidly when heated. The number of calories needed by 1 gram of a substance in order that its temperature may be increased 1° C. is called thespecific heatof a substance; or, specific heat is the number of calories given out by 1 gram of a substance when its temperature falls 1° C. For experiments on the determination ofspecific heat, see Laboratory Manual.
Water has the highest specific heat of any known substance except hydrogen; that is, it requires more heat to raise the temperature of water a definite number of degrees than it does to raise the temperature of an equal amount of any other substance the same number of degrees. Practically this same thing can be stated in another way: Water in cooling gives out more heat than any other substance in cooling through the same number of degrees. For this reason water is used in foot warmers and in hot-water bags. If a copper lid were used as a foot warmer, it would give the feet only.095 as much heat as an equal weight of water; a lead weight only.031 as much heat as water. Flatirons are made of iron because of the relatively high specific heat of iron. The flatiron heats slowly and cools slowly, and, because of its high specific heat, not only supplies the laundress with considerable heat, but eliminates for her the frequent changing of the flatiron.
18. Water and Weather.About four times as much heat is required to heat a given quantity of water one degree as to heat an equal quantity of earth. In summer, when the rocks and the sand along the shore are burning hot, the ocean and lakes are pleasantly cool, although the amount of heat present in the water is as great as that present in the earth. In winter, long after the rocks and sand have given out their heat and have become cold, the water continues to give out the vast store of heat accumulated during the summer. This explains why lands situated on or near large bodies of water usually have less variation in temperature than inland regions. In the summer the water cools the region; in the winter, on the contrary, the water heats the region, and hence extremes of temperature are practically unknown.
19. Sources of Heat.Most of the heat which we enjoy and use we owe to the sun. The wood which blazes on thehearth, the coal which glows in the furnace, and the oil which burns in the stove owe their existence to the sun.
Without the warmth of the sun seeds could not sprout and develop into the mighty trees which yield firewood. Even coal, which lies buried thousands of feet below the earth's surface, owes its existence in part to the sun. Coal is simply buried vegetation,—vegetation which sprouted and grew under the influence of the sun's warm rays. Ages ago trees and bushes grew "thick and fast," and the ground was always covered with a deep layer of decaying vegetable matter. In time some of this vast supply sank into the moist soil and became covered with mud. Then rock formed, and the rock pressed down upon the sunken vegetation. The constant pressure, the moisture in the ground, and heat affected the underground vegetable mass, and slowly changed it into coal.
The buried forest and thickets were not all changed into coal. Some were changed into oil and gas. Decaying animal matter was often mixed with the vegetable mass. When the mingled animal and vegetable matter sank into moist earth and came under the influence of pressure, it was slowly changed into oil and gas.
The heat of our bodies comes from the foods which we eat. Fruits, grain, etc., could not grow without the warmth and the light of the sun. The animals which supply our meats likewise depend upon the sun for light and warmth.
The sun, therefore, is the great source of heat; whether it is the heat which comes directly from the sun and warms the atmosphere, or the heat which comes from burning coal, wood, and oil.
20. Boiling.Heat absorbed in Boiling. If a kettle of water is placed above a flame, the temperature of the water gradually increases, and soon small bubbles form at the bottom of the kettle and begin to rise through the water. At first the bubbles do not get far in their ascent, but disappear before they reach the surface; later, as the water gets hotter and hotter, the bubbles become larger and more numerous, rise higher and higher, and finally reach the surface and pass from the water into the air; steam comes from the vessel, and the water is said toboil. The temperature at which a liquid boils is called the boiling point.
While the water is heating, the temperature steadily rises, but as soon as the water begins to boil the thermometer reading becomes stationary and does not change, no matter how hard the water boils and in spite of the fact that heat from the flame is constantly passing into the water.
If the flame is removed from the boiling water for but a second, the boiling ceases; if the flame is replaced, the boiling begins again immediately. Unless heat is constantly supplied, water at the boiling point cannot be transformed into steam.
The number of calories which must be supplied to 1 gram of water at the boiling point in order to change it into steam at the same temperature is called the heat of vaporization; it is the heat necessary to change 1 gram of water at the boiling point into steam ofthe same temperature.
21. The Amount of Heat Absorbed.The amount of heat which must be constantly supplied to water at the boiling point in order to change it into steam is far greater than we realize. If we put a beaker of ice water (water at 0° C.) over a steady flame, and note (1) the time which elapses before the water begins to boil, and (2) the time which elapses before the boiling water completely boils away, we shall see that it takes about 5-1/4 times as long to change water into steam as it does to change its temperature from 0° C. to 100° C. Since, with a steady flame, it takes 5-1/4 times as long to change water into steam as it does to change its temperature from 0° C. to the boiling point, we conclude that it takes 5-1/4 times as much heat to convert water at the boiling point into steam as it does to raise it from the temperature of ice water to that of boiling water.
The amount of heat necessary to raise the temperature of 1 gram of water 1° C. is equal to 1 calorie, and the amount necessary to raise the temperature 100° C. is equal to 100 calories; hence the amount of heat necessary to convert 1 gram of water at the boiling point into steam at that same temperature is equal to approximately 525 calories. Very careful experiments show the exact heat of vaporization to be 536.1 calories. (See Laboratory Manual.)
22. General Truths.Statements similar to the above hold for other liquids and for solutions. If milk is placed upon a stove, the temperature rises steadily until the boiling point is reached; further heating produces, not a change in temperature, but a change of the water of the milk into steam. As soon as the milk, or any other liquid food, comes to a boil, the gas flame should be lowered until only an occasional bubble forms, because so long as any bubbles form the temperature is that of the boiling point, and further heat merelyresults in waste of fuel.
We find by experiment that every liquid has its own specific boiling point; for example, alcohol boils at 78° C. and brine at 103° C. Both specific heat and the heat of vaporization vary with the liquid used.
23. Condensation.If one holds a cold lid in the steam of boiling water, drops of water gather on the lid; the steam is cooled by contact with the cold lid andcondensesinto water. Bottles of water brought from a cold cellar into a warm room become covered with a mist of fine drops of water, because the moisture in the air, chilled by contact with the cold bottles, immediately condenses into drops of water. Glasses filled with ice water show a similar mist.
In Section 21, we saw that 536 calories are required to change 1 gram of water into steam; if, now, the steam in turn condenses into water, it is natural to expect a release of the heat used in transforming water into steam. Experiment shows not only that vapor gives out heat during condensation, but that the amount of heat thus set free is exactly equal to the amount absorbed during vaporization. (See Laboratory Manual.)
We learn that the heat of vaporization is the same whether it is considered as the heat absorbed by 1 gram of water in its change to steam, or as the heat given out by 1 gram of steam during its condensation into water.
24. Practical Application.We understand now the value of steam as a heating agent. Water is heated in a boiler in the cellar, and the steam passes through pipes which run to the various rooms; there the steam condenses into water in the radiators, each gram of steam setting free 536 calories of heat. When we consider the size of the radiators and the large number of grams of steam which they contain, and consider further that each gram in condensing sets free 536 calories, we understand the ease with which buildings are heated bysteam.
Most of us have at times profited by the heat of condensation. In cold weather, when there is a roaring fire in the range, the water frequently becomes so hot that it "steams" out of open faucets. If, at such times, the hot water is turned on in a small cold bathroom, and is allowed to run until the tub is well filled, vapor condenses on windows, mirrors, and walls, and the cold room becomes perceptibly warmer. The heat given out by the condensing steam passes into the surrounding air and warms the room.
There is, however, another reason for the rise in temperature. If a large pail of hot soup is placed in a larger pail of cold water, the soup will gradually cool and the cold water will gradually become warmer. A red-hot iron placed on a stand gradually cools, but warms the stand. A hot body loses heat so long as a cooler body is near it; the cold object is heated at the expense of the warmer object, and one loses heat and the other gains heat until the temperature of both is the same. Now the hot water in the tub gradually loses heat and the cold air of the room gradually gains heat by convection, but the amount given the room by convection is relatively small compared with the large amount set free by the condensing steam.
25. Distillation. If impure, muddy water is boiled, drops of water will collect on a cold plate held in the path of the steam, but the drops will be clear and pure. When impure water is boiled, the steam from it does not contain any of the impurities because these are left behind in the vessel. If all the water were allowed to boil away, a layer of mud or of other impurities would be found at the bottom of the vessel. Because of this fact, it is possible to purify water in a very simple way. Place over a fire a large kettle closed except for a spout which is long enough to reach across the stove and dip into a bottle. As the liquid boils, steam escapes throughthe spout, and on reaching the cold bottle condenses and drops into the bottle as pure water. The impurities remain behind in the kettle. Water freed from impurities in this way is calleddistilled water, and the process is calleddistillation(Fig. 19). By this method, the salt water of the ocean may be separated into pure drinking water and salt, and many of the large ocean liners distill from the briny deep all the drinking water used on their ocean voyages.
FIG. 19.—In order that the steam which passes through the coiled tube may be quickly cooled and condensed, cold water is made to circulate around the coil. The condensed steam escapes at w.FIG. 19.—In order that the steam which passes through the coiled tube may be quickly cooled and condensed, cold water is made to circulate around the coil. The condensed steam escapes atw.
Commercially, distillation is a very important process. Turpentine, for example, is made by distilling the sap of pine trees. Incisions are cut in the bark of the long-leaf pine trees, and these serve as channels for the escape of crude resin. This crude liquid is collected in barrels and taken to a distillery, where it is distilled into turpentine and rosin. The turpentine is the product which passes off as vapor, and the rosin is the mass left in the boiler after the distillation of the turpentine.
26. Evaporation.If a stopper is left off a cologne bottle, the contents of the bottle will slowly evaporate; if a dish of water is placed out of doors on a hot day, evaporation occurs very rapidly. The liquids which have disappeared from the bottle and the dish have passed into the surrounding air in the form of vapor. In Section 20, we saw that water could not pass into vapor without the addition of heat; now the heatnecessary for the evaporation of the cologne and water was taken from the air, leaving it slightly cooler. If wet hands are not dried with a towel, but are left to dry by evaporation, heat is taken from the hand in the process, leaving a sensation of coolness. Damp clothing should never be worn, because the moisture in it tends to evaporate at the expense of the bodily heat, and this undue loss of heat from the body produces chills. After a bath the body should be well rubbed, otherwise evaporation occurs at the expense of heat which the body cannot ordinarily afford to lose.
Evaporation is a slow process occurring at all times; it is hastened during the summer, because of the large amount of heat present in the atmosphere. Many large cities make use of the cooling effect of evaporation to lower the temperature of the air in summer; streets are sprinkled not only to lay the dust, but in order that the surrounding air may be cooled by the evaporation of the water.
Some thrifty housewives economize by utilizing the cooling effects of evaporation. Butter, cheese, and other foods sensitive to heat are placed in porous vessels wrapped in wet cloths. Rapid evaporation of the water from the wet cloths keeps the contents of the jars cool, and that without expense other than the muscular energy needed for wetting the cloths frequently.
27. Rain, Snow, Frost, Dew.The heat of the sun causes constant evaporation of the waters of oceans, rivers, streams, and marshes, and the water vapor set free by evaporation passes into the air, which becomes charged with vapor or is said to be humid. Constant, unceasing evaporation of our lakes, streams, and pools would mean a steady decrease in the supply of water available for daily use, if the escaped water were all retained by the atmosphere and lost to the earth. But although the escaped vapor mingles with the atmosphere,hovering near the earth's surface, or rising far above the level of the mountains, it does not remain there permanently. When this vapor meets a cold wind or is chilled in any way, condensation takes place, and a mass of tiny drops of water or of small particles of snow is formed. When these drops or particles become large enough, they fall to the earth as rain or snow, and in this way the earth is compensated for the great loss of moisture due to evaporation. Fog is formed when vapor condenses near the surface of the earth, and when the drops are so small that they do not fall but hover in the air, the fog is said "not to lift" or "not to clear."
If ice water is poured into a glass, a mist will form on the outside of the glass. This is because the water vapor in the air becomes chilled by contact with the glass and condenses. Often leaves and grass and sidewalks are so cold that the water vapor in the atmosphere condenses on them, and we say a heavy dew has formed. If the temperature of the air falls to the freezing point while the dew is forming, the vapor is frozen and frost is seen instead of dew.
The daily evaporation of moisture into the atmosphere keeps the atmosphere more or less full of water vapor; but the atmosphere can hold only a definite amount of vapor at a given temperature, and as soon as it contains the maximum amount for that temperature, further evaporation ceases. If clothes are hung out on a damp, murky day they do not dry, because the air contains all the moisture it can hold, and the moisture in the clothes has no chance to evaporate. When the air contains all the moisture it can hold, it is said to be saturated, and if a slight fall in temperature occurs when the air is saturated, condensation immediately begins in the form of rain, snow, or fog. If, however, the air is not saturated, a fall in temperature may occur without producing precipitation. The temperature at which air issaturated and condensation begins is called thedew point.
28. How Chills are Caused.The discomfort we feel in an overcrowded room is partly due to an excess of moisture in the air, resulting from the breathing and perspiration of many persons. The air soon becomes saturated with vapor and cannot take away the perspiration from our bodies, and our clothing becomes moist and our skin tender. When we leave the crowded "tea" or lecture and pass into the colder, drier, outside air, clothes and skin give up their load of moisture through sudden evaporation. But evaporation requires heat, and this heat is taken from our bodies, and a chill results.
Proper ventilation would eliminate much of the physical danger of social events; fresh, dry air should be constantly admitted to crowded rooms in order to replace the air saturated by the breath and perspiration of the occupants.
29. Weather Forecasts.When the air is near the saturation point, the weather is oppressive and is said to be very humid. For comfort and health, the air should be about two thirds saturated. The presence of some water vapor in the air is absolutely necessary to animal and plant life. In desert regions where vapor is scarce the air is so dry that throat trouble accompanied by disagreeable tickling is prevalent; fallen leaves become so dry that they crumble to dust; plants lose their freshness and beauty.
The likelihood of rain or frost is often determined by temperature and humidity. If the air is near saturation and the temperature is falling, it is safe to predict bad weather, because the fall of temperature will probably cause rapid condensation, and hence rain. If, however, the air is not near the saturation point, a fall in temperature will not necessarily produce bad weather.
The measurement of humidity is of far wider importancethan the mere forecasting of local weather conditions. The close relation between humidity and health has led many institutions, such as hospitals, schools, and factories, to regulate the humidity of the atmosphere as carefully as they do the temperature. Too great humidity is enervating, and not conducive to either mental or physical exertion; on the other hand, too dry air is equally harmful. In summer the humidity conditions cannot be well regulated, but in winter, when houses are artificially heated, the humidity of a room can be increased by placing pans of water near the registers or on radiators.
30. Heat Needed to Melt Substances.If a spoon is placed in a vessel of hot water for a few seconds and then removed, it will be warmer than before it was placed in the hot water. If a lump of melting ice is placed in the vessel of hot water and then removed, the ice will not be warmer than before, but there will be less of it. The heat of the water has been used in melting the ice, not in changing its temperature.
If, on a bitter cold day, a pail of snow is brought into a warm room and a thermometer is placed in the snow, the temperature rises gradually until 32° F. is reached, when it becomes stationary, and the snow begins to melt. If the pail is put on the fire, the temperature still remains 32°F., but the snow melts more rapidly. As soon as all the snow is completely melted, however, the temperature begins to rise and rises steadily until the water boils, when it again becomes stationary and remains so during the passage of water into vapor.
We see that heat must be supplied to ice at 0° C. or 32° F. in order to change it into water, and further, that the temperature of the mixture does not rise so long as any ice is present, no matter how much heat is supplied. The amount of heat necessary to melt 1 gram ofice is easily calculated. (See Laboratory Manual.)
Heat must be supplied to ice to melt it. On the other hand, water, in freezing, loses heat, and the amount of heat lost by freezing water is exactly equal to the amount of heat absorbed by melting ice.
The number of units of heat required to melt a unit mass of ice is called theheat of fusionof water.
31. Climate.Water, in freezing, loses heat, even though its temperature remains at 0° C. Because water loses heat when it freezes, the presence of large streams of water greatly influences the climate of a region. In winter the heat from the freezing water keeps the temperature of the surrounding higher than it would naturally be, and consequently the cold weather is less severe. In summer water evaporates, heat is taken from the air, and consequently the warm weather is less intense.
32. Molding of Glass and Forging of Iron.The fire which is hot enough to melt a lump of ice may not be hot enough to melt an iron poker; on the other hand, it may be sufficiently hot to melt a tin spoon. Different substances melt, or liquefy, at different temperatures; for example, ice melts at 0° C., and tin at 233° C., while iron requires the relatively high temperature of 1200° C. Most substances have a definite melting or freezing point which never changes so long as the surrounding conditions remain the same.
But while most substances have a definite melting point, some substances do not. If a glass rod is held in a Bunsen burner, it will gradually grow softer and softer, and finally a drop of molten glass will fall from the end of the rod into the fire. The glass did not suddenly become a liquid at a definite temperature; instead it softened gradually, and then melted. While glass is in the soft, yielding, pliable state, it is molded into dishes, bottles, and other useful objects, such as lamp shades, globes, etc. (Fig. 20). If glass melted at a definitetemperature, it could not be molded in this way. Iron acts in a similar manner, and because of this property the blacksmith can shape his horseshoes, and the workman can make his engines and other articles of daily service to man.
FIG. 20.—Molten glass being rolled into a form suitable for window panes.FIG. 20.—Molten glass being rolled into a form suitable for window panes.
33. Strange Behavior of Water.One has but to remember that bottles of water burst when they freeze, and that ice floats on water like wood, to know that water expands on freezing or on solidifying. A quantity of water which occupies 100 cubic feet of space will, on becoming ice, need 109 cubic feet of space. On a cold winter night the water sometimes freezes in the water pipes, and the pipes burst. Water is very peculiar in expanding on solidification, because most substances contract on solidifying; gelatin and jelly, for example, contract so much that they shrink from the sides of the dish which contains them.
If water contracted in freezing, ice would be heavier thanwater and would sink in ponds and lakes as fast as it formed, and our streams and ponds would become masses of solid ice, killing all animal and plant life. But the ice is lighter than water and floats on top, and animals in the water beneath are as free to live and swim as they were in the warm sunny days of summer. The most severe winter cannot freeze a deep lake solid, and in the coldest weather a hole made in the ice will show water beneath the surface. Our ice boats cut and break the ice of the river, and through the water beneath our boats daily ply their way to and fro, independent of winter and its blighting blasts.
While most of us are familiar with the bursting of water pipes on a cold night, few of us realize the influence which freezing water exerts on the character of the land around us.
Water sinks into the ground and, on the approach of winter, freezes, expanding about one tenth of its volume; the expanding ice pushes the earth aside, the force in some cases being sufficient to dislodge even huge rocks. In the early days in New England it was said by the farmers that "rocks grew," because fields cleared of stones in the fall became rock covered with the approach of spring; the rocks and stones hidden underground and unseen in the fall were forced to the surface by the winter's expansion. We have all seen fence posts and bricks pushed out of place because of the heaving of the soil beneath them. Often householders must relay their pavements and walks because of the damage done by freezing water.
FIG. 21.—The destruction caused by freezing water.FIG. 21.—The destruction caused by freezing water.
The most conspicuous effect of the expansive power of freezing water is seen in rocky or mountainous regions (Fig. 21). Water easily finds entrance into the cracks and crevices of the rocks, where it lodges until frozen; then it expands and acts like a wedge, widening cracks, chiseling off edges, and even breaking rocks asunder. In regions where frequentfrosts occur, the destructive action of water works constant changes in the appearance of the land; small cracks and crevices are enlarged, massive rocks are pried up out of position, huge slabs are split off, and particles large and small are forced from the parent rock. The greater part of the debris and rubbish brought down from the mountain slopes by the spring rains owes its origin to the fact that water expands when it freezes.
34. Heat Necessary to Dissolve a Substance.It requires heat to dissolve any substance, just as it requires heat to change ice to water. If a handful of common salt is placed in a small cup of water and stirred with a thermometer, the temperature of the mixture falls several degrees. This is just what one would expect, because the heat needed to liquefy the salt must come from somewhere, and naturally it comes from the water, thereby lowering the temperature of the water. We know very well that potatoes cease boiling if a pinch of salt is put in the water; this is because the temperature of the water has been lowered by the amount of heat necessary to dissolve the salt.
Let some snow or chopped ice be placed in a vessel and mixed with one third its weight of coarse salt; if then a small tube of cold water is placed in this mixture, the water in the test tube will soon freeze solid. As soon as the snow and saltare mixed they melt. The heat necessary for this comes in part from the air and in part from the water in the test tube, and the water in the tube becomes in consequence cold enough to freeze. But the salt mixture does not freeze because its freezing point is far below that of pure water. The use of salt and ice in ice-cream freezers is a practical application of this principle. The heat necessary for melting the mixture of salt and ice is taken from the cream which thus becomes cold enough to freeze.
35. Why Things Burn.The heat of our bodies comes from the food we eat; the heat for cooking and for warming our houses comes from coal. The production of heat through the burning of coal, or oil, or gas, or wood, is called combustion. Combustion cannot occur without the presence of a substance called oxygen, which exists rather abundantly in the air; that is, one fifth of our atmosphere consists of this substance which we call oxygen. We throw open our windows to allow fresh air to enter, and we take walks in order to breathe the pure air into our lungs. What we need for the energy and warmth of our bodies is the oxygen in the air. Whether we burn gas or wood or coal, the heat which is produced comes from the power which these various substances possess to combine with oxygen. We open the draft of a stove that it may "draw well": that it may secure oxygen for burning. We throw a blanket over burning material to smother the fire: to keep oxygen away from it. Burning, or oxidation, is combining with oxygen, and the more oxygen you add to a fire, the hotter the fire will burn, and the faster. The effect of oxygen on combustion may be clearly seen by thrusting a smoldering splinter into a jar containing oxygen; the smoldering splinter will instantly flare and blaze, while if it is removed from the jar, it loses its flame and againburns quietly. Oxygen for this experiment can be produced in the following way.
FIG. 22.—Preparing oxygen from potassium chlorate and manganese dioxide.FIG. 22.—Preparing oxygen from potassium chlorate and manganese dioxide.
36. How to Prepare Oxygen.Mix a small quantity of potassium chlorate with an equal amount of manganese dioxide and place the mixture in a strong test tube. Close the mouth of the tube with a one-hole rubber stopper in which is fitted a long, narrow tube, and clamp the test tube to an iron support, as shown in Figure 22. Fill the trough with water until the shelf is just covered and allow the end of the delivery tube to rest just beneath the hole in the shelf. Fill a medium-sized bottle with water, cover it with a glass plate, invert the bottle in the trough, and then remove the glass plate. Heat the test tube very gently, and when gas bubbles out of the tube, slip the bottle over the opening in the shelf, so that the tube runs into the bottle. The gas will force out the water and will finally fill the bottle. When all the water has been forced out, slip the glass plate under the mouth of the bottle and remove the bottle from the trough. The gas in the bottle is oxygen.
Everywhere in a large city or in a small village, smoke is seen, indicating the presence of fire; hence there must exist a large supply of oxygen to keep all the fires alive. The supplyof oxygen needed for the fires of the world comes largely from the atmosphere.
37. Matches. The burning material is ordinarily set on fire by matches, thin strips of wood tipped with sulphur or phosphorus, or both. Phosphorus can unite with oxygen at a fairly low temperature, and if phosphorus is rubbed against a rough surface, the friction produced will raise the temperature of the phosphorus to a point where it can combine with oxygen. The burning phosphorus kindles the wood of the match, and from the burning match the fire is kindled. If you want to convince yourself that friction produces heat, rub a cent vigorously against your coat and note that the cent becomes warm. Matches have been in use less than a hundred years. Primitive man kindled his camp fire by rubbing pieces of dry wood together until they took fire, and this method is said to be used among some isolated distant tribes at the present time. A later and easier way was to strike flint and steel together and to catch the spark thus produced on tinder or dry fungus. Within the memory of some persons now living, the tinder box was a valuable asset to the home, particularly in the pioneer regions of the West.
38. Safety Matches. Ordinary phosphorus, while excellent as a fire-producing material, is dangerously poisonous, and those to whom the dipping of wooden strips into phosphorus is a daily occupation suffer with a terrible disease which usually attacks the teeth and bones of the jaw. The teeth rot and fall out, abscesses form, and bones and flesh begin to decay; the only way to prevent the spread of the disease is to remove the affected bone, and in some instances it has been necessary to remove the entire jaw. Then, too, matches made of yellow or white phosphorus ignite easily, and, when rubbed against any rough surface, are apt to takefire. Many destructive fires have been started by the accidental friction of such matches against rough surfaces.
For these reasons the introduction of the so-called safety match was an important event. When common phosphorus, in the dangerous and easily ignited form, is heated in a closed vessel to about 250° C., it gradually changes to a harmless red mass. The red phosphorus is not only harmless, but it is difficult to ignite, and, in order to be ignited by friction, must be rubbed on a surface rich in oxygen. The head of a safety match is coated with a mixture of glue and oxygen-containing compounds; the surface on which the match is to be rubbed is coated with a mixture of red phosphorus and glue, to which finely powdered glass is sometimes added in order to increase the friction. Unless the head of the match is rubbed on the prepared phosphorus coating, ignition does not occur, and accidental fires are avoided.
Various kinds of safety matches have been manufactured in the last few years, but they are somewhat more expensive than the ordinary form, and hence manufacturers are reluctant to substitute them for the cheaper matches. Some foreign countries, such as Switzerland, prohibit the sale of the dangerous type, and it is hoped that the United States will soon follow the lead of these countries in demanding the sale of safety matches only.
39. Some Unfamiliar Forms of Burning.While most of us think of burning as a process in which flames and smoke occur, there are in reality many modes of burning accompanied by neither flame nor smoke. Iron, for example, burns when it rusts, because it slowly combines with the oxygen of the air and is transformed into new substances. When the air is dry, iron does not unite with oxygen, but when moisture is present in the air, the iron unites with the oxygen and turns into iron rust. The burning is slow andunaccompanied by the fire and smoke so familiar to us, but the process is none the less burning, or combination with oxygen. Burning which is not accompanied by any of the appearances of ordinary burning is known as oxidation.
The tendency of iron to rust lessens its efficiency and value, and many devices have been introduced to prevent rusting. A coating of paint or varnish is sometimes applied to iron in order to prevent contact with air. The galvanizing of iron is another attempt to secure the same result; in this process iron is dipped into molten zinc, thereby acquiring a coating of zinc, and forming what is known as galvanized iron. Zinc does not combine with oxygen under ordinary circumstances, and hence galvanized iron is immune from rust.
Decay is a process of oxidation; the tree which rots slowly away is undergoing oxidation, and the result of the slow burning is the decomposed matter which we see and the invisible gases which pass into the atmosphere. The log which blazes on our hearth gives out sufficient heat to warm us; the log which decays in the forest gives out an equivalent amount of heat, but the heat is evolved so slowly that we are not conscious of it. Burning accompanied by a blaze and intense heat is a rapid process; burning unaccompanied by fire and appreciable heat is a slow, gradual process, requiring days, weeks, and even long years for its completion.
Another form of oxidation occurs daily in the human body. In Section 35 we saw that the human body is an engine whose fuel is food; the burning of that food in the body furnishes the heat necessary for bodily warmth and the energy required for thought and action. Oxygen is essential to burning, and the food fires within the body are kept alive by the oxygen taken into the body at every breath by the lungs.We see now one reason for an abundance of fresh air in daily life.
40. How to Breathe. Air, which is essential to life and health, should enter the body through the nose andnot through the mouth. The peculiar nature and arrangement of the membranes of the nose enable the nostrils to clean, and warm, and moisten the air which passes through them to the lungs. Floating around in the atmosphere are dust particles which ought not to get into the lungs. The nose is provided with small hairs and a moist inner membrane which serve as filters in removing solid particles from the air, and in thus purifying it before its entrance into the lungs.
In the immediate neighborhood of three Philadelphia high schools, having an approximate enrollment of over 8000 pupils, is a huge manufacturing plant which day and night pours forth grimy smoke and soot into the atmosphere which must supply oxygen to this vast group of young lives. If the vital importance of nose breathing is impressed upon these young people, the harmful effect of the foul air may be greatly lessened, the smoke particles and germs being held back by the nose filters and never reaching the lungs. If, however, this principle of hygiene is not brought to their attention, the dangerous habit of breathing through the open, or at least partially open, mouth will continue, and objectionable matter will pass through the mouth and find a lodging place in the lungs.
There is another very important reason why nose breathing is preferable to mouth breathing. The temperature of the human body is approximately 98° F., and the air which enters the lungs should not be far below this temperature. If air reaches the lungs through the nose, its journey is relatively long and slow, and there is opportunity for it to be warmed before it reaches the lungs. If, on the other hand, air passes to the lungs by way of the mouth, the warmingprocess is brief and insufficient, and the lungs suffer in consequence. Naturally, the gravest danger is in winter.
41. Cause of Mouth Breathing.Some people find it difficult to breathe through the nostrils on account of growths, called adenoids, in the nose. If you have a tendency toward mouth breathing, let a physician examine your nose and throat.
FIG. 23.—Intelligent expression is often lacking in children with adenoid growths.FIG. 23.—Intelligent expression is often lacking in children with adenoid growths.
Adenoids not only obstruct breathing and weaken the whole system through lack of adequate air, but they also press upon the blood vessels and nerves of the head and interfere with normal brain development. Moreover, they interfere in many cases with the hearing, and in general hinder activity and growth. The removal of adenoids is simple, and carries with it only temporary pain and no danger. Some physicians claim that the growths disappear in later years, but even if that is true, the physical and mental development of earlier years is lost, and the person is backward in the struggle for life and achievement.
42. How to Build a Fire.Substances differ greatly as to the ease with which they may be made to burn or, in technical terms, with which they may be made to unite with oxygen. For this reason, we put light materials, like shavings, chips, and paper, on the grate, twisting the latter and arranging it so that air (oxygen in the air) can reach a largesurface; upon this we place small sticks of wood, piling them across each other so as to allow entrance for the oxygen; and finally upon this we place our hard wood or coal.
The coal and the large sticks cannot be kindled with a match, but the paper and shavings can, and these in burning will heat the large sticks until they take fire and in turn kindle the coal.
43. Spontaneous Combustion.We often hear of fires "starting themselves," and sometimes the statement is true. If a pile of oily rags is allowed to stand for a time, the oily matter will begin to combine slowly with oxygen and as a result will give off heat. The heat thus given off is at first insufficient to kindle a fire; but as the heat is retained and accumulated, the temperature rises, and finally the kindling point is reached and the whole mass bursts into flames. For safety's sake, all oily cloths should be burned or kept in metal vessels.
44. The Treatment of Burns.In spite of great caution, burns from fires, steam, or hot water do sometimes occur, and it is well to know how to relieve the suffering caused by them and how to treat the injury in order to insure rapid healing.
Burns are dangerous because they destroy skin and thus open up an entrance into the body for disease germs, and in addition because they lay bare nerve tissue which thereby becomes irritated and causes a shock to the entire system.
In mild burns, where the skin is not broken but is merely reddened, an application of moist baking soda brings immediate relief. If this substance is not available, flour paste, lard, sweet oil, or vaseline may be used.
In more severe burns, where blisters are formed, the blisters should be punctured with a sharp, sterilized needle and allowed to dischargetheir watery contents before the above remedies are applied.
In burns severe enough to destroy the skin, disinfection of the open wound with weak carbolic acid or hydrogen peroxide is very necessary. After this has been done, a soft cloth soaked in a solution of linseed oil and limewater should be applied and the whole bandaged. In such a case, it is important not to use cotton batting, since this sticks to the rough surface and causes pain when removed.
45. Carbon Dioxide.A Product of Burning.When any fuel, such as coal, gas, oil, or wood, burns, it sends forth gases into the surrounding atmosphere. These gases, like air, are invisible, and were unknown to us for a long time. The chief gas formed by a burning substance is called carbon dioxide (CO2) because it is composed of one part of carbon and two parts of oxygen. This gas has the distinction of being the most widely distributed gaseous compound of the entire world; it is found in the ocean depths and on the mountain heights, in brilliantly lighted rooms, and most abundantly in manufacturing towns where factory chimneys constantly pour forth hot gases and smoke.
Wood and coal, and in fact all animal and vegetable matter, contain carbon, and when these substances burn or decay, the carbon in them unites with oxygen and forms carbon dioxide.
The food which we eat is either animal or vegetable, and it is made ready for bodily use by a slow process of burning within the body; carbon dioxide accompanies this bodily burning of food just as it accompanies the fires with which we are more familiar. The carbon dioxide thus produced within the body escapes into the atmosphere with the breath.
We see that the source of carbon dioxide is practically inexhaustible, coming as it does from every stove, furnace, and candle, and further with every breath of a living organism.
46. Danger of Carbon Dioxide.When carbon dioxideoccurs in large quantities, it is dangerous to health, because it interferes with normal breathing, lessening the escape of waste matter through the breath and preventing the access to the lungs of the oxygen necessary for life. Carbon dioxide is not poisonous, but it cuts off the supply of oxygen, just as water cuts it off from a drowning man.
Since every man, woman, and child constantly breathes forth carbon dioxide, the danger in overcrowded rooms is great, and proper ventilation is of vital importance.
47. Ventilation.In estimating the quantity of air necessary to keep a room well aired, we must take into account the number of lights (electric lights do not count) to be used, and the number of people to occupy the room. The average house should provide at theminimum600 cubic feet of space for each person, and in addition, arrangements for allowing at least 300 cubic feet of fresh air per person to enter every hour.
In houses which have not a ventilating system, the air should be kept fresh by intelligent action in the opening of doors and windows; and since relatively few houses are equipped with a satisfactory system, the following suggestions relative to intelligent ventilation are offered.
1. Avoid drafts in ventilation.
2. Ventilate on the sheltered side of the house. If the wind is blowing from the north, open south windows.
48. What Becomes of the Carbon Dioxide.When we reflect that carbon dioxide is constantly being supplied to the atmosphere and that it is injurious to health, the question naturally arises as to how the air remains free enough of the gas to support life. This is largely because carbon dioxide is an essential food of plants. Through their leaves plants absorb it from the atmosphere, and by a wonderful process break it up into its component parts, oxygen and carbon. They reject the oxygen, which passes back to the air, but theyretain the carbon, which becomes a part of the plant structure. Plants thus serve to keep the atmosphere free from an excess of carbon dioxide and, in addition, furnish oxygen to the atmosphere.
49. How to Obtain Carbon Dioxide. There are several ways in which carbon dioxide can be produced commercially, but for laboratory use the simplest is to mix in a test tube powdered marble, or chalk, and hydrochloric acid, and to collect the effervescing gas as shown in Figure 24. The substance which remains in the test tube after the gas has passed off is a solution of a salt and water. From a mixture of hydrochloric acid (HCl) and marble are obtained a salt, water, and carbon dioxide, the desired gas.