[1]See Newton's Optics, book iii.
[1]See Newton's Optics, book iii.
[2]The observations here alluded to never appeared.
[2]The observations here alluded to never appeared.
429.
We have hitherto had to do with colours which appear with vivacity, but which immediately vanish again when certain conditions cease. We have now to become acquainted with others, which it is true are still to be considered as transient, but which, under certain circumstances, become so fixed that, even after the conditions which first occasioned their appearance cease, they still remain, and thus constitutethe link between the physical and the chemical colours.
430.
They appear from various causes on the surface of a colourless body, originally, without communication, die or immersion (βαφή); and we now proceed to trace them, from their faintest indication to their most permanent state, through the different conditions of their appearance, which for easier survey we here at once summarily state.
431.
First condition.—The contact of two smooth surfaces of hard transparent bodies.
First case: if masses or plates of glass, or if lenses are pressed against each other.
Second case: if a crack takes place in a solid mass of glass, chrystal, or ice.
Third case: if lamellæ of transparent stones become separated.
Second condition.—If a surface of glass or a polished stone is breathed upon.
Third condition.—The combination of the two last; first, breathing on the glass, then placing another plate of glass upon it, thus exciting the colours by pressure; then removing the upper glass, upon which the colours begin to fade and vanish with the breath.
Fourth condition.—Bubbles of various liquids, soap, chocolate, beer, wine, fine glass bubbles.
Fifth condition.—Very fine pellicles and lamellæ, produced by the decomposition of minerals and metals. The pellicles of lime, the surface of stagnant water, especially if impregnated with iron, and again pellicles of oil on water, especially of varnish on aqua fortis.
Sixth condition.—If metals are heated; the operation of imparting tints to steel and other metals.
Seventh condition.—If the surface of glass is beginning to decompose.
432.
First condition, first case. If two convex glasses, or a convex and plane glass, or, best of all, a convex and concave glass come in contact, concentric coloured circles appear. The phenomenon exhibits itself immediately on the slightest pressure, and may then be gradually carried through various successive states. We will describe the complete appearance at once, as we shall then be better enabled to follow the different states through which it passes.
433.
The centre is colourless; where the glasses are, so to speak, united in one by the strongest pressure, a dark grey point appears with a silverwhite space round it: then follow, in decreasing distances, various insulated rings, all consisting of three colours, which are in immediate contact with each other. Each of these rings, of which perhaps three or four might be counted, is yellow on the inner side, blue on the outer, and red in the centre. Between two rings there appears a silver white interval. The rings which are farthest from the centre are always nearer together: they are composed of red and green without a perceptible white space between them.
434.
We will now observe the appearances in their gradual formation, beginning from the slightest pressure.
435.
On the slightest pressure the centre itself appears of a green colour. Then follow as far as the concentric circles extend, red and green rings. They are wide, accordingly, and no trace of a silver white space is to be seen between them. The green is produced by the blue of an imperfectly developed circle, mixing with the yellow of the first circle. All the remaining circles are, in this slight contact, broad; their yellow and blue edges mix together, thus producing a beautiful green. The red, however, ofeach circle, remains pure and untouched; hence the whole series is composed of these two colours.
436.
A somewhat stronger pressure separates the first circle by a slight interval from the imperfectly developed one: it is thus detached, and may be said to appear in a complete state. The centre is now a blue point; for the yellow of the first circle is now separated from this central point by a silver white space. From the centre of the blue a red appears, which is thus, in all cases, bounded on the outside by its blue edge. The second and third rings from the centre are quite detached. Where deviations from this order present themselves, the observer will be enabled to account for them, from what has been or remains to be stated.
437.
On a stronger pressure the centre becomes yellow; this yellow is surrounded by a red and blue edge: at last, the yellow also retires from the centre; the innermost circle is formed and is bounded with yellow. The whole centre itself now appears silver white, till at last, on the strongest pressure, the dark point appears, and the phenomenon, as described at first, is complete.
438.
The relative size of the concentric circles and their intervals depends on the form of the glasses which are pressed together.
439.
We remarked above, that the coloured centre is, in fact, an undeveloped circle. It is, however, often found, on the slightest pressure, that several undeveloped circles exist there, as it were, in the germ; these can be successively developed before the eye of the observer.
440.
The regularity of these rings is owing to the form of the convex glasses, and the diameter of the coloured appearance depends on the greater or lesser section of a circle on which a lens is polished. We easily conclude from this, that by pressing plane glasses together, irregular appearances only will be produced; the colours, in fact, undulate like watered silks, and spread from the point of pressure in all directions. Yet, the phenomenon as thus exhibited is much more splendid than in the former instance, and cannot fail to strike every spectator. If we make the experiment in this mode, we shall distinctly see, as in the other case, that, on a slight pressure, the green and red waves appear; on a stronger, stripes of blue, red, and yellow, become detached.At first, the outer sides of these stripes touch; on increased pressure they are separated by a silver white space.
441.
Before we proceed to a further description of this phenomenon, we may point out the most convenient mode of exhibiting it. Place a large convex glass on a table near the window; upon this glass lay a plate of well-polished mirror-glass, about the size of a playing-card, and the mere weight of the plate will press sufficiently to produce one or other of the phenomena above described. So, also, by the different weight of plates of glass, by other accidental circumstances, for instance, by slipping the plate on the side of the convex glass where the pressure cannot be so strong as in the centre, all the gradations above described can be produced in succession.
442.
In order to observe the phenomenon it is necessary to look obliquely on the surface where it appears. But, above all, it is to be remarked that by stooping still more, and looking at the appearance under a more acute angle, the circles not only grow larger but other circles are developed from the centre, of which no trace is to be discovered when we look perpendicularly, even through the strongest magnifiers.
443.
In order to exhibit the phenomenon in its greatest beauty, the utmost attention should be paid to the cleanness of the glasses. If the experiment is made with plate-glass adapted for mirrors, the glass should be handled with gloves. The inner surfaces, which must come in contact with the utmost nicety, may be most conveniently cleaned before the experiment, and the outer surfaces should be kept clean while the pressure is increased.
444.
From what has been said it will be seen that an exact contact of two smooth surfaces is necessary. Polished glasses are best adapted for the purpose. Plates of glass exhibit the most brilliant colours when they fit closely together, and for this reason the phenomenon will increase in beauty if exhibited under an air-pump, by exhausting the air.
445.
The appearance of the coloured rings may be produced in the greatest perfection by placing a convex and concave glass together which have been ground on similar segments of circles. I have never seen the effect more brilliant than with the object-glass of an achromatic telescope,in which the crown-glass and flint-glass were necessarily in the closest contact.
446.
A remarkable appearance takes place when dissimilar surfaces are pressed together; for example, a polished crystal and a plate of glass. The appearance does not at all exhibit itself in large flowing waves, as in the combination of glass with glass, but it is small and angular, and, as it were, disjointed: thus it appears that the surface of the polished crystal, which consists of infinitely small sections of lamellæ, does not come so uninterruptedly in contact with the glass as another glass-plate would.
447.
The appearance of colour vanishes on the strongest pressure, which so intimately unites the two surfaces that they appear to make but one substance. It is this which occasions the dark centre, because the pressed lens no longer reflects any light from this point, for the very same point, when seen against the light, is perfectly clear and transparent. On relaxing the pressure, the colours, in like manner, gradually diminish, and disappear entirely when the surfaces are separated.
448.
These same appearances occur in two similar cases. If entirely transparent masses become partially separated, the surfaces of their parts being still sufficiently in contact, we see the same circles and waves more or less. They may be produced in great beauty by plunging a hot mass of glass in water; the different fissures and cracks enabling us to observe the colours in various forms. Nature often exhibits the same phenomena in split rock crystals.
449.
This appearance, again, frequently displays itself in the mineral world in those kinds of stone which by nature have a tendency to exfoliate. These original lamellæ are, it is true, so intimately united, that stones of this kind appear altogether transparent and colourless, yet, the internal layers become separated, from various accidental causes, without altogether destroying the contact: thus the appearance, which is now familiar to us by the foregoing description, often occurs in nature, particularly in calcareous spars; the specularis, adularia, and other minerals of similar structure. Hence it shows an ignorance of the proximate causes of an appearance so often accidentally produced, to consider it so important in mineralogy, and to attach especial value to the specimens exhibiting it.
450.
We have yet to speak of the very remarkable inversion of this appearance, as related by men of science. If, namely, instead of looking at the colours by a reflected light, we examine them by a transmitted light, the opposite colours are said to appear, and in a mode corresponding with that which we have before described as physiological; the colours evoking each other. Instead of blue, we should thus see red-yellow; instead of red, green, &c., andvice versâ. We reserve experiments in detail, the rather as we have ourselves still some doubts on this point.
451.
If we were now called upon to give some general explanation of these epoptical colours, as they appear under the first condition, and to show their connexion with the previously detailed physical phenomena, we might proceed to do so as follows:—
452.
The glasses employed for the experiments are to be regarded as the utmost possible practical approach to transparence. By the intimate contact, however, occasioned by the pressure applied to them, their surfaces, we are persuaded, immediately become in a very slight degree dimmed. Within this semi-transparencethe colours immediately appear, and every circle comprehends the whole scale; for when the two opposites, yellow and blue, are united by their red extremities, pure red appears: the green, on the other hand, as in prismatic experiments, when yellow and blue touch.
453.
We have already repeatedly found that where colour exists at all, the whole scale is soon called into existence; a similar principle may be said to lurk in the nature of every physical phenomenon; it already follows, from the idea of polar opposition, from which an elementary unity or completeness results.
454.
The fact that a colour exhibited by transmitted light is different from that displayed by reflected light, reminds us of those dioptrical colours of the first class which we found were produced precisely in the same way through semi-opacity. That here, too, a diminution of transparency exists there can scarcely be a doubt; for the adhesion of the perfectly smooth plates of glass (an adhesion so strong that they remain hanging to each other) produces a degree of union which deprives each of the two surfaces, in some degree, of its smoothness and transparence. The fullest proof may, however,be found in the fact that in the centre, where the lens is most strongly pressed on the other glass, and where a perfect union is accomplished, a complete transparence takes place, in which we no longer perceive any colour. All this may be hereafter confirmed in a recapitulation of the whole.
455.
Second condition.—If after breathing on a plate of glass, the breath is merely wiped away with the finger, and if we then again immediately breathe on the glass, we see very vivid colours gliding through each other; these, as the moisture evaporates, change their place, and at last vanish altogether. If this operation is repeated, the colours are more vivid and beautiful, and remain longer than they did the first time.
456.
Quickly as this appearance passes, and confused as it appears to be, I have yet remarked the following effects:—At first all the principal colours appear with their combinations; on breathing more strongly, the appearance may be perceived in some order. In this succession it may be remarked, that when the breath in evaporating becomes contracted from all sidestowards the centre, the blue colour vanishes last.
457.
The phenomenon appears most readily between the minute lines, which the action of passing the fingers leaves on the clear surface; a somewhat rough state of the surface of the glass is otherwise requisite. On some glass the appearance may be produced by merely breathing; in other cases the wiping with the fingers is necessary: I have even met with polished mirror-glasses, one side of which immediately showed the colours vividly; the other not. To judge from some remaining pieces, the former was originally the front of the glass, the latter the side which was covered with quicksilver.
458.
These experiments may be best made in cold weather, because the glass may be more quickly and distinctly breathed upon, and the breath evaporates more suddenly. In severe frost the phenomenon may be observed on a large scale while travelling in a carriage; the glasses being well cleaned, and all closed. The breath of the persons within is very gently diffused over the glass, and immediately produces the most vivid play of colours. How far they may present a regular succession I have not been able to remark;but they appear particularly vivid when they have a dark object as a background. This alternation of colours does not, however, last long; for as soon as the breath gathers in drops, or freezes to points of ice, the appearance is at once at an end.
459.
Third condition.—The two foregoing experiments of the pressure and breathing may be united; namely, by breathing on a plate of glass, and immediately after pressing the other upon it. The colours then appear as in the case of two glasses unbreathed upon, with this difference, that the moisture occasions here and there an interruption of the undulations. On pushing one glass away from the other the moisture appears iridescent as it evaporates.
460.
It might, however, be asserted that this combined experiment exhibits no more than each single experiment; for it appears the colours excited by pressure disappear in proportion as the glasses are less in contact, and the moisture then evaporates with its own colours.
461.
Fourth condition.—Iridescent appearances are observable in almost all bubbles; soap-bubblesare the most commonly known, and the effect in question is thus exhibited in the easiest mode; but it may be observed in wine, beer, in pure spirit, and again, especially, in the froth of chocolate.
462.
As in the above cases we required an infinitely narrow space between two surfaces which are in contact, so we can consider the pellicle of the soap-bubble as an infinitely thin lamina between two elastic bodies; for the appearance in fact takes place between the air within, which distends the bubble, and the atmospheric air.
463.
The bubble when first produced is colourless; then coloured stripes, like those in marble paper, begin to appear: these at length spread over the whole surface, or rather are driven round it as it is distended.
464.
In a single bubble, suffered to hang from the straw or tube, the appearance of colour is difficult to observe, for the quick rotation prevents any accurate observation, and all the colours seem to mix together; yet we can perceive that the colours begin at the orifice of the tube. The solution itself may, however, be blown into carefully,so that only one bubble shall appear. This remains white (colourless) if not much agitated; but if the solution is not too watery, circles appear round the perpendicular axis of the bubble; these being near each other, are commonly composed alternately of green and red. Lastly, several bubbles may be produced together by the same means; in this case the colours appear on the sides where two bubbles have pressed each other flat.
465.
The bubbles of chocolate-froth may perhaps be even more conveniently observed than those of soap; though smaller, they remain longer. In these, owing to the heat, an impulse, a movement, is produced and sustained, which appears necessary to the development and succession of the appearances.
466.
If the bubble is small, or shut in between others, coloured lines chase each other over the surface, resembling marbled paper; all the colours of the scale are seen to pass through each other; the pure, the augmented, the combined, all distinctly clear and beautiful. In small bubbles the appearance lasts for a considerable time.
467.
If the bubble is larger, or if it becomes by degrees detached, owing to the bursting of others near, we perceive that this impulsion and attraction of the colours has, as it were, an end in view; for on the highest point of the bubble we see a small circle appear, which is yellow in the centre; the other remaining coloured lines move constantly round this with a vermicular action.
468.
In a short time the circle enlarges and sinks downwards on all sides; in the centre the yellow remains; below and on the outside it becomes red, and soon blue; below this again appears a new circle of the same series of colours: if they approximate sufficiently, a green is produced by the union of the border-colours.
469.
When I could count three such leading circles, the centre was colourless, and this space became by degrees larger as the circles sank lower, till at last the bubble burst.
470.
Fifth condition.—Very delicate pellicles may be formed in various ways: on these films we discover a very lively play of colours, either in the usual order, or more confusedly passing through each other. The water in which limehas been slaked soon skims over with a coloured pellicle: the same happens on the surface of stagnant water, especially if impregnated with iron. The lamellæ of the fine tartar which adheres to bottles, especially in red French wine, exhibit the most brilliant colours, on being exposed to the light, if carefully detached. Drops of oil on water, brandy, and other fluids, produce also similar circles and brilliant effects: but the most beautiful experiment that can be made is the following:—Let aqua fortis, not too strong, be poured into a flat saucer, and then with a brush drop on it some of the varnish used by engravers to cover certain portions during the process of biting their plates. After quick commotion there presently appears a film which spreads itself out in circles, and immediately produces the most vivid appearances of colour.
471.
Sixth condition.—When metals are heated, colours rapidly succeeding each other appear on the surface: these colours can, however, be arrested at will.
472.
If a piece of polished steel is heated, it will, at a certain degree of warmth, be overspread with yellow. If taken suddenly away from the fire, this yellow remains.
473.
As the steel becomes hotter, the yellow appears darker, intenser, and presently passes into red. This is difficult to arrest, for it hastens very quickly to bright blue.
474.
This beautiful blue is to be arrested if the steel is suddenly taken out of the heat and buried in ashes. The blue steel works are produced in this way. If, again, the steel is held longer over the fire, it soon becomes a light blue, and so it remains.
475.
These colours pass like a breath over the plate of steel; each seems to fly before the other, but, in reality, each successive hue is constantly developed from the preceding one.
476.
If we hold a penknife in the flame of a light, a coloured stripe will appear across the blade. The portion of the stripe which was nearest to the flame is light blue; this melts into blue-red; the red is in the centre; then follow yellow-red and yellow.
477.
This phenomenon is deducible from the precedingones; for the portion of the blade next the handle is less heated than the end which is in the flame, and thus all the colours which in other cases exhibited themselves in succession, must here appear at once, and may thus be permanently preserved.
478.
Robert Boyle gives this succession of colours as follows:—"A florido flavo ad flavum saturum et rubescentem (quem artifices sanguineum vocant) inde ad languidum, postea ad saturiorem cyaneum." This would be quite correct if the words "languidus" and "saturior" were to change places. How far the observation is correct, that the different colours have a relation to the degree of temper which the metal afterwards acquires, we leave to others to decide. The colours are here only indications of the different degrees of heat.—Note R.
479.
When lead is calcined, the surface is first greyish. This greyish powder, with greater heat, becomes yellow, and then orange. Silver, too, exhibits colours when heated; the fracture of silver in the process of refining belongs to the same class of examples. When metallic glasses melt, colours in like manner appear on the surface.
480.
Seventh condition.—When the surface of glass becomes decomposed. The accidental opacity (blindwerden) of glass has been already noticed: the term (blindwerden) is employed to denote that the surface of the glass is so affected as to appear dim to us.
481.
White glass becomes "blind" soonest; cast, and afterwards polished glass is also liable to be so affected; the bluish less, the green least.
482.
Of the two sides of a plate of glass one is called the mirror side; it is that which in the oven lies uppermost, on which one may observe roundish elevations: it is smoother than the other, which is undermost in the oven, and on which scratches may be sometimes observed. On this account the mirror side is placed facing the interior of rooms, because it is less affected by the moisture adhering to it from within, than the other would be, and the glass is thus less liable to become "blind."
483.
This half-opacity or dimness of the glass assumes by degrees an appearance of colour which may become very vivid, and in whichperhaps a certain succession, or otherwise regular order, might be discovered.
484.
Having thus traced the physical colours from their simplest effects to the present instances, where these fleeting appearances are found to be fixed in bodies, we are, in fact, arrived at the point where the chemical colours begin; nay, we have in some sort already passed those limits; a circumstance which may excite a favourable prejudice for the consistency of our statement. By way of conclusion to this part of our inquiry, we subjoin a general observation, which may not be without its bearing on the common connecting principle of the phenomena that have been adduced.
485.
The colouring of steel and the appearances analogous to it, might perhaps be easily deduced from the doctrine of the semi-opaque mediums. Polished steel reflects light powerfully: we may consider the colour produced by the heat as a slight degree of dimness: hence a bright yellow must immediately appear; this, as the dimness increases, must still appear deeper, more condensed, and redder, and at last pure and ruby-red. The colour has now reached the extreme point of depth, and if we suppose the same degreeof semi-opacity still to continue, the dimness would now spread itself over a dark ground, first producing a violet, then a dark-blue, and at last a light-blue, and thus complete the series of the appearances.
We will not assert that this mode of explanation will suffice in all cases; our object is rather to point out the road by which the all-comprehensive formula, the very key of the enigma, may be at last discovered.—Note S.
486.
We give this denomination to colours which we can produce, and more or less fix, in certain bodies; which we can render more intense, which we can again take away and communicate to other bodies, and to which, therefore, we ascribe a certain permanency: duration is their prevailing characteristic.
487.
In this view the chemical colours were formerly distinguished with various epithets; they were calledcolores proprii, corporei, materiales, veri, permanentes, fixi.
488.
In the preceding chapter we observed how the fluctuating and transient nature of the physical colours becomes gradually fixed, thus forming the natural transition to our present subject.
489.
Colour becomes fixed in bodies more or less permanently; superficially, or thoroughly.
490.
All bodies are susceptible of colour; it caneither be excited, rendered intense, and gradually fixed in them, or at least communicated to them.
491.
In the examination of coloured appearances we had occasion everywhere to take notice of a principle of contrast: so again, in approaching the precincts of chemistry, we find a chemical contrast of a remarkable nature. We speak here, with reference to our present purpose, only of that which is comprehended under the general names of acid and alkali.
492.
We characterised the chromatic contrast, in conformity with all other physical contrasts as amoreandless; ascribing theplusto the yellow side, theminusto the blue; and we now find that these two divisions correspond with the chemical contrasts. The yellow and yellow-red affect the acids, the blue and blue-red the alkalis; thus the phenomena of chemical colours, although still necessarily mixed up withother considerations, admit of being traced with sufficient simplicity.
493.
The principal phenomena in chemical colours are produced by the oxydation of metals, and it will be seen how important this consideration is at the outset. Other facts which come into the account, and which are worthy of attention, will be examined under separate heads; in doing this we, however, expressly state that we only propose to offer some preparatory suggestions to the chemist in a very general way, without entering into the nicer chemical problems and questions, or presuming to decide on them. Our object is only to give a sketch of the mode in which, according to our conviction, the chemical theory of colours may be connected with general physics.
494.
In treating of the dioptrical colours of the first class (155) we have already in some degree anticipated this subject. Transparent substancesmay be said to be in the highest class of inorganic matter. With these, colourless semi-transparence is closely connected, and white may be considered the last opaque degree of this.
495.
Pure water crystallised to snow appears white, for the transparence of the separate parts makes no transparent whole. Various crystallised salts, when deprived to a certain extent of moisture, appear as a white powder. The accidentally opaque state of a pure transparent substance might be called white; thus pounded glass appears as a white powder. The cessation of a combining power, and the exhibition of the atomic quality of the substance might at the same time be taken into the account.
496.
The known undecomposed earths are, in their pure state, all white. They pass to a state of transparence by natural crystallization. Silex becomes rock-crystal; argile, mica; magnesia, talc; calcareous earth and barytes appear transparent in various spars.—Note T.
497.
As in the colouring of mineral bodies themetallic oxydes will often invite our attention, we observe, in conclusion, that metals, when slightly oxydated, at first appear white, as lead is converted to white lead by vegetable acid.
498.
Black is not exhibited in so elementary a state as white. We meet with it in the vegetable kingdom in semi-combustion; and charcoal, a substance especially worthy of attention on other accounts, exhibits a black colour. Again, if woods—for example, boards, owing to the action of light, air, and moisture, are deprived in part of their combustibility, there appears first the grey then the black colour. So again, we can convert even portions of animal substance to charcoal by semi-combustion.
499.
In the same manner we often find that a sub-oxydation takes place in metals when the black colour is to be produced. Various metals, particularly iron, become black by slight oxydation,by vinegar, by mild acid fermentations; for example, a decoction of rice, &c.
500.
Again, it may be inferred that a de-oxydation may produce black. This occurs in the preparation of ink, which becomes yellow by the solution of iron in strong sulphuric acid, but when partly de-oxydised by the infusion of gall-nuts, appears black.
501.
In the division of physical colours, where semi-transparent mediums were considered, we saw colours antecedently to white and black. In the present case we assume a white and black already produced and fixed; and the question is, how colour can be excited in them?
502.
Here, too, we can say, white that becomes darkened or dimmed inclines to yellow; black, as it becomes lighter, inclines to blue.—Note U.
503.
Yellow appears on the active (plus) side, immediately in the light, the bright, the white. All white surfaces easily assume a yellow tinge; paper, linen, wool, silk, wax: transparent fluids again, which have a tendency to combustion, easily become yellow; in other words they easily pass into a very slight state of semi-transparence.
504.
So again the excitement on the passive side, the tendency to obscure, dark, black, is immediately accompanied with blue, or rather with a reddish-blue. Iron dissolved in sulphuric acid, and much diluted with water, if held to the light in a glass, exhibits a beautiful violet colour as soon as a few drops only of the infusion of gall-nuts are added. This colour presents the peculiar hues of the dark topaz, theorphninonof a burnt-red, as the ancients expressed it.
505.
Whether any colour can be excited in the pure earths by the chemical operations of nature and art, without the admixture of metallic oxydes, is an important question, generally, indeed, answered in the negative. It is perhaps connected with the question—to what extentchanges may be produced in the earths through oxydation?
506.
Undoubtedly the negation of the above question is confirmed by the circumstance that wherever mineral colours are found, some trace of metal, especially of iron, shows itself; we are thus naturally led to consider how easily iron becomes oxydised, how easily the oxyde of iron assumes different colours, how infinitely divisible it is, and how quickly it communicates its colour. It were to be wished, notwithstanding, that new experiments could be made in regard to the above point, so as either to confirm or remove any doubt.
507.
However this may be, the susceptibility of the earths with regard to colours already existing is very great; aluminous earth is thus particularly distinguished.
508.
In proceeding to consider the metals, which in the inorganic world have the almost exclusive prerogative of appearing coloured, we find that, in their pure, independent, natural state, they are already distinguished from thepure earths by a tendency to some one colour or other.
509.
While silver approximates most to pure white,—nay, really represents pure white, heightened by metallic splendour,—steel, tin, lead, and so forth, incline towards pale blue-grey; gold, on the other hand, deepens to pure yellow, copper approaches a red hue, which, under certain circumstances, increases almost to bright red, but which again returns to a yellow golden colour when combined with zinc.
510.
But if metals in their pure state have so specific a determination towards this or that exhibition of colour, they are, through the effect of oxydation, in some degree reduced to a common character; for the elementary colours now come forth in their purity, and although this or that metal appears to have a particular tendency to this or that colour, we find some that can go through the whole circle of hues, others, that are capable of exhibiting more than one colour; tin, however, is distinguished by its comparative inaptitude to become coloured. We propose to give a table hereafter, showing how far the different metals can be more or less made to exhibit the different colours.
511.
When the clean, smooth surface of a pure metal, on being heated, becomes overspread with a mantling colour, which passes through a series of appearances as the heat increases, this, we are persuaded, indicates the aptitude of the metal to pass through the whole range of colours. We find this phenomenon most beautifully exhibited in polished steel; but silver, copper, brass, lead, and tin, easily present similar appearances. A superficial oxydation is probably here taking place, as may be inferred from the effects of the operation when continued, especially in the more easily oxydizable metals.
512.
The same conclusion may be drawn from the fact that iron is more easily oxydizable by acid liquids when it is red hot, for in this case the two effects concur with each other. We observe, again, that steel, accordingly as it is hardened in different stages of its colorification, may exhibit a difference of elasticity: this is quite natural, for the various appearances of colour indicate various degrees of heat.[1]
513.
If we look beyond this superficial mantling,this pellicle of colour, we observe that as metals are oxydized throughout their masses, white or black appears with the first degree of heat, as may be seen in white lead, iron, and quicksilver.
514.
If we examine further, and look for the actual exhibition of colour, we find it most frequently on theplusside. The mantling, so often mentioned, of smooth metallic surfaces begins with yellow. Iron passes presently into yellow ochre, lead from white lead to massicot, quicksilver from æthiops to yellow turbith. The solutions of gold and platinum in acids are yellow.
515.
The exhibitions on theminusside are less frequent. Copper slightly oxydized appears blue. In the preparation of Prussian-blue, alkalis are employed.
516.
Generally, however, these appearances of colour are of so mutable a nature that chemists look upon them as deceptive tests, at least in the nicer gradations. For ourselves, as we can only treat of these matters in a general way, we merely observe that the appearances of colour in metals may be classed according to theirorigin, manifold appearance, and cessation, as various results of oxydation, hyper-oxydation, ab-oxydation, and de-oxydation.[2]