APPENDICES
I. INDEX TO DEFINITIONS
AN attempt has been made to define specifically, at some point in the text, most of the technical terms that are associated with the theory of ionization. For convenience of reference, the most important of these terms are collected into the brief index which is given below. The references are to the pages on which the term is defined.
II. SERIES RELATIONS IN LINE SPECTRA
A SYNOPSIS of the normal series relations in line spectra has been published by Russell and Saunders (Ap. J., 61, 39, 1925). A transcription of the passages containing definitions of spectroscopic quantities that are mentioned in the present volume is given below:
“Every spectral line is now believed to be emitted (or absorbed) in connection with the transition of an atom (or molecule) between two definite (quantized) states, of different energy-content—the frequency of the radiation being exactly proportional to the change of energy. The wave-number of the line may therefore be expressed as the difference of twospectroscopic termswhich measure, in suitable units, the energies of the initial and final states. Combinations between these terms occur according to definite laws, which enable usto classify them into systems, each containing a number of series of terms, which are usually multiple—
“Any termmay be expressed in the formwhereis the Rydberg constant andan integer. For homologous components of successive terms of the same series,changes by unity, while the “residual”is sometimes practically constant (Rydberg’s formula), or, more often, is expressible in the form(Hicks’s formula), or(Ritz’s formula). In many cases this approximation fails for the smaller values of;and prediction becomes very uncertain, though a plot of the residuals usually gives a smooth curve....
“Theprinciples of selection, which determine what combinations among these numerous terms give rise to observable lines, are very simply expressed in terms of two sets of quantum numbers.
“Theazimuthal quantum number()is i for all terms of the s-series, 2 for those of the p-series, 3 for the d’s, 4 for the f’s, 5 for the g’s, 6 for the h’s, and so on.
“Combinations usually occur only between terms of adjacent series for which the values ofdiffer by a unit. A great many lines are, however, known for which the change ofis 0, and a few for which it is 2. In the simpler spectra, such lines are faint, except when produced under the influence of a strong magnetic field; but in the more complex spectra they are often numerous and strong.
“Theinner quantum number()differs from one component of a multiple term to another, and also in the various series and systems, according to the following scheme.
“Combinations occur only between terms for whichdiffers by 0 or ± 1. If, however,in both cases, no radiation occurs. Lines corresponding to a change ofare found in strong magnetic fields, and a very few in their absence.
“The combination of two multiple terms gives rise, therefore, to a group of lines (which may number as many as eighteen). Such groups have been calledmultipletsby Catalan. Their discovery has afforded the key to the many-lined spectra....
“In such a group, those lines for which the changes inand,in passing from one term to the other, are of the same sign, are the strongest, and those in which they are of opposite sign the weakest. These intensity relations are of great assistance in picking out the multiplets.
“Combinations between terms of different systems (consistent with the foregoing rules) often occur. Such lines are usually, though not always, faint....
“The serial numberof the term (which is equivalent to the total-quantum number) plays quite a subordinate rôle, being of importance only when series formulae have to be calculated. An extensive analysis of a spectrum is possible without it, though determination of the limits of the series, and the ionization potential, demands its introduction.”
THE line intensities quoted inChapter VIIIwere derived from the spectra of the stars enumerated below inTable XXXII. Successive columns contain the Draper class, the name of the star, the Boss number, the visual apparent magnitude, and the reduced proper motion H. The stars within each class are arranged in order of right ascension.
IV. INTENSITY CHANGES OF LINES WITH UNKNOWN SERIES RELATIONS
THE following tabulation shows the intensity changes of lines of unknown series relations that occur in the hotter stars. The arrangement follows that ofTable XIX. Notes on the maxima and blends are appended.
NOTES TO TABLE XXXIII
V. MATERIAL BEARING ON THE CLASSIFICATION OFSTARS, QUOTED IN CHAPTER XII
IN illustration of the problem of Class,observations of sixty-two stars are collected in the following table. Successive columns contain the H.D. number, the name of the star, the apparent magnitude, the reduced proper motion,and the spectral class. Then follow columns which indicate the presence ()or absence of metallic lines, the quality of the lines (sharp lines being represented by the letterand hazy lines by the letter), the presence of wings to the hydrogen lines, and the strength of the Sr+ line at 4077 and the Si+ lines at 4128, 4131.
The stars in each class are arranged in order of increasing strength of metallic lines, and it will be seen that this feature is correlated with the strength of the silicon and strontium lines, but not with the line quality or the hydrogen wings, nor with the reduced proper motion.