From an examination of Rowland’s tables of the solar spectrum, it appears that the fainter components of the multiplets invariably accompany the stronger ones, thus making the identifications certain.Only the stronger components are, however, powerful enough to appear in stellar spectra, with the dispersions ordinarily used.
The following multiplets, as analyzed by Russell[290]and Kiess,[291]are definitely present:,,,,,,,,,,.Doubtfully present are:,.
The maximum of these lines is difficult to determine; they are not well placed for measurement, many of the most important are seriously blended, and all are rather faint, even at maximum. They are first seen[292]at Class,and their maximum appears to be[293]ator.
The solar intensities of the lines of both neutral and ionized titanium fall off regularly with increasing excitation potential. The subject is discussed inChapter VII, as part of the evidence for the validity of the Saha theory.[294]
IONIZED TITANIUM
The lines of ionized titanium are about as strong in the solar spectrum as those of the neutral atom. Many of them appear, with the lines of the ionized iron atom, with abnormal strength in the spectra of the c-stars.[295]The following multiplets[296]are present in the solar spectrum:,,,,,,,,,,,,,,,,,,,,,.Doubtfully present are,,,.The lines which are especially enhanced in the c-stars are:,,,,,,,.
The lines of ionized titanium come to a maximum at about Class,but a significant maximum is difficult to determine, for the lines areextremely sensitive to absolute magnitude. Menzel,[297]usingCassiopeiae (classed by him as)for his typical star, found a maximum development of lines in that star. The present writer,[298]using the wider selection of stars enumerated in the appendix, obtainsas the maximum for Ti+. A glance at the measures[299]will indicate that the position of the maximum is in any case very uncertain, as the intensity does not change smoothly in going from class to class.
COMPOUNDS OF TITANIUM
The absorption bands of titanium oxide, TiO₂, are the characteristic flutings[300][301]of the stars of Class,and the strength of these bands has been proposed[302]as a criterion of class for the stars in which they are found. It is perhaps noteworthy that titanium, zirconium, and carbon, the only elements which give oxides in stellar spectra (hydrogen excepted) belong to the fourth group of the periodic system.
VANADIUM (23)
The vanadium lines are best identified by intensity from Rowland’s table. The following multiplets[303]are present in the solar spectrum:,,,,,,.Themultiplet is well seen in stellar spectra fromonwards, and increases in strength as cooler stars are approached.[304]Slipher[305]called attention to the strength inCeti of the vanadium group near 4400, presumably the two multiplets,,with excitation potential 0.28 volts.
IONIZED VANADIUM
Three multiplets, all far in the ultra-violet, are tabulated for ionized vanadium by Meggers, Kiess, and Walters,[306]and two of them are within the range of Rowland’s table. All the lines of these, theandmultiplets, have been satisfactorily identified with solar lines. The strength of the ultimate lines of ionized vanadium, which occur in the multiplet last named, is a little greater, in the solar spectrum, than that of the strongest lines of the neutral atom, at 4379, which are also ultimate lines.
The following tabulation contains, in the same form asTable XI, the data respecting the two multiplets which are identified in the solar spectrum.
CHROMIUM (24)
The lines of chromium were classified by Catalan,[307]and those which occur in the sun are comprised in the following multiplets:[308],,,,,,,,,,,.
The ultimate lines,at 4254, 4274, 4289 increase with advancing type.[309]The maximum for subordinate lines[310]is at.
IONIZED CHROMIUM
Of the six multiplets of ionized chromium tabulated by Meggers, Kiess, and Walters,[311]only two are within the measured range of the solar spectrum, but every line in these two multiplets accords satisfactorily in wave-length and intensity with a line in Rowland’s table. The ultimate lines are in the neighborhood of 2800, and are therefore unattainable. The lines, and the solar intensities, are contained in the appended table.
MANGANESE (25)
The lines of manganese are conspicuous in stellar spectra, and all the classified lines[312]within the range of Rowland’s table are found in the solar spectrum, namely the multiplets,,,,,,,,,.The ultimate linesare at 4030, and constitute a conspicuous group in the solar spectrum. They are well seen in the cooler stars, and are progressively strengthened with advancing type.[313]They first appear at.Themultiplet, at 4018, 4041, 4055, 4084, etc., has a maximum, according to Menzel,[314]at.
IONIZED MANGANESE
Meggers, Kiess, and Walters[315]give one multiplet of ionized manganese, and this is within the range of Rowland’s table. The multiplet was previously picked out by Catalan[316]as being analogous to the arc multiplet.All the lines can be satisfactorily identified with lines in the solar spectrum, as in the following table.
IRON (26)
The extensive occurrence of the arc lines of iron in the stellar spectrum is well known. The following multiplets[317]have been traced in the solar spectrum, and the corresponding lines are also to be traced in the spectra of the cooler stars:,,,,,,,,,,,,,,,.The iron lines have, in general,[318]a maximum at,but the only ultimate lines which are well shown in stellar spectra, thelines near 4480, increase with advancing type to the end of the sequence.[319]
The following lines are used as criteria of absolute magnitude by Harper and Young:[320]4202, 4250, 4272 (), 4072 (), 4482 ().
IONIZED IRON
The lines of ionized iron are strong in F stars of high luminosity, and are especially conspicuous in the stars which have the c-character. Menzel[321]places the maximum at,and the writer[322]finds it at.The following multiplets, as classified by Russell,[323]occur in the solar spectrum:,,,,,,,,,,,,,,,,,,,,.Doubtfully present are:,,.The ionized iron lines are strengthened, as are other enhanced lines, over sunspots, and many of the fainter components of multiplets are observed only in the spot spectrum.
COBALT (27)
The series relations for the arc spectrum of cobalt[324]have been published by Walters. Cobalt lines are frequent in the solar spectrum, but as the strongest of them lie near 3500, they cannot be traced in the spectra of stars. The following multiplets are certainly identified in the spectrum of the sun:,,,,,,,,,,and.The incompletely observed multipletis apparently absent from the solar spectrum.
NICKEL (28)
The series relations for nickel are as yet unpublished. The lines appear in great numbers in the solar spectrum, but they are not strong enough to be conspicuous in the spectra of the stars. The line 5476 appears to have a maximum at,indicating either that it is an enhanced line of nickel, or that it is blended with the enhanced line of some other element. The lines 5081, 4714 are strengthened in low temperature stars, and are probably due to neutral nickel. From the solar behavior of the lines of this element,[325]the ionization potential seems to be of the same order as that for cobalt, probably about 8 volts.
COPPER (29)
Copper is represented in the solar spectrum by the ultimate doublet 3273, 3247 (), which is strong. The pair 5700, 5782 ()is probably also present. The former lines are too far in the ultra-violet to have been studied in the stars, and the latter are too faint.
ZINC (30)
The principal singletis at 2138, and has therefore not been observed in stellar spectra. Thelines at 4722, 4810, are seen in the stellar sequence, where they appear at,and have a maximum[326]at.
Two unclassified lines of ionized zinc are mentioned in Fowler’s Report as lying at 5894, 6214. Neither of these lines can be traced in solar or stellar spectra.
GALLIUM (31)
The occurrence of gallium in stellar spectra is confined to the identification of two solar lines by Hartley and Ramage.[327]The lines in question are at 4033, 4172, and are the ultimate lines of the element (). They are too faint to be studied in the stars.
RUBIDIUM (37)
The ultimate lines of rubidium have been detected in the sunspot spectrum,[328]but they are not found in the spectra of the sun or stars.
STRONTIUM (38)
The element strontium is of great astrophysical importance, owing to the use of its enhanced lines in the estimation of absolute magnitudes. The neutral atom is represented in the sun and stars by the ultimate line ()4607, which is first clearly seen[329]at,and increases progressively in strength with advancing type. It varies with absolute magnitude, being weakened in stars of high luminosity later than.Estimates for the intensity of this line are difficult with small dispersions, as it is blended in cool stars.
IONIZED STRONTIUM
Ionized strontium is represented in stellar spectra by theand theseries. The former contains the important absolute magnitude lines 4215, 4077, which are first seen at about,and reach a maximum[330]near.They appear to have “abnormal” intensities in certain stars,[331]and in thestars are often the finest and sharpest lines in the spectrum. This behavior suggests a high-level origin, but “stationary Strontium,”although suggested by Plaskett[332]as likely to occur, has not yet been observed.
YTTRIUM (39)
Numerous lines of yttrium[333]are found in the solar spectrum. The lines of the ionized atom are somewhat stronger than the lines of the neutral atom. The lines of the neutral element which can be identified in the solar spectrum are contained in the following table.
The multipletsat 4174, etc., andat 4674, etc., and themultiplets, do not appear in the solar spectrum. None of the above lines is strong enough to be seen in the spectra of the stars.
IONIZED YTTRIUM
Four of the multiplets attributed to ionized yttrium[334]are satisfactorily identified in the solar spectrum. The wave-lengths and identifications are contained inTable XVI, p. 83. The arrangement is as inTable XI.