CHAPTER IEARLY VIEWS OF ELECTRICITY

CHAPTER IEARLY VIEWS OF ELECTRICITY

I. GROWTH OF THE ATOMIC THEORY OF MATTER

There is an interesting and instructive parallelism between the histories of the atomic conception of matter and the atomic theory of electricity, for in both cases the ideas themselves go back to the very beginnings of the subject. In both cases too these ideas remained absolutely sterile until the development of precise quantitative methods of measurement touched them and gave them fecundity. It took two thousand years for this to happen in the case of the theory of matter and one hundred and fifty years for it to happen in the case of electricity; and no sooner had it happened in the case of both than the two domains hitherto thought of as distinct began to move together and to appear as perhaps but different aspects of one and the same phenomenon, thus recalling again Thales’ ancient belief in the essential unity of nature. How this attempt at union has come about can best be seen by a brief review of the histories of the two ideas.

The conception of a world made up of atoms which are in incessant motion was almost as clearly developed in the minds of the Greek philosophers of the School of Democritus (420 B.C.), Epicurus (370 B.C.), and Lucretius (Roman, 50 B.C.) as it is in the mind of the modern physicist, but the idea had its roots in one case in a mere speculative philosophy; in the other case, like most of ourtwentieth-century knowledge, it rests upon direct, exact, quantitative observations and measurement. Not that the human eye has ever seen or indeed can ever see an individual atom or molecule. This is forever impossible, and for the simple reason that the limitations on our ability to see small objects are imposed, not by the imperfections of our instruments, but by the nature of the eye itself, or by the nature of the light-wave to which the eye is sensitive. If we are to see molecules our biological friends must develop wholly new types of eyes, viz., eyes which are sensitive to waves one thousand times shorter than those to which our present optic nerves can respond.

But after all, the evidence of our eyes is about the least reliable kind of evidence which we have. We are continually seeing things which do not exist, even though our habits are unimpeachable. It is the relations which are seen by the mind’s eye to be the logical consequences of exact measurement which are for the most part dependable. So far as the atomic theory of matter is concerned, these relations have all been developed since 1800, so that both the modern atomic and the modern kinetic theories of matter, in spite of their great antiquity, are in a sense less than one hundred years old. Indeed, nearly all of our definite knowledge about molecules and atoms has come since 1851, when Joule[1]in England made the first absolute determination of a molecular magnitude, namely, the average speed with which gaseous molecules of a given kind are darting hither and thither at ordinary temperatures. This result was as surprising asmany others which have followed in the field of molecular physics, for it showed that this speed, in the case of the hydrogen molecule, has the stupendous value of about a mile a second. The second molecular magnitude to be found was the mean distance a molecule of a gas moves between collisions, technically called the mean free path of a molecule. This was computed first in 1860 by Clerk Maxwell.[2]It was also 1860 before anyone had succeeded in making any sort of an estimate of the number of molecules in a cubic centimeter of a gas. When we reflect that we can now count this number with probably greater precision than we can attain in determining the number of people living in New York, in spite of the fact that it has the huge value of 27.05 billion billion, one gains some idea of how great has been our progress in mastering some at least of the secrets of the molecular and atomic worlds. The wonder is that we got at it so late. Nothing is more surprising to the student brought up in the atmosphere of the scientific thought of the present than the fact that the relatively complex and intricate phenomena of light and electromagnetism had been built together into moderately consistent and satisfactory theories long before the much simpler phenomena of heat and molecular physics had begun to be correctly understood. And yet almost all the qualitative conceptions of the atomic and kinetic theories were developed thousands of years ago. Tyndall’s statement of the principles of Democritus, whom Bacon considered to be “a man of mightier metal than Plato or Aristotle, though their philosophy was noised andcelebrated in the schools amid the din and pomp of professors,” will show how complete an atomic philosophy had arisen 400 years B.C. “That it was entirely destroyed later was not so much due to the attacks upon it of the idealistic school, whose chief representatives were Plato and Aristotle, as to the attacks upon all civilization of Genseric, Attila, and the barbarians.” That the Aristotelian philosophy lasted throughout this period is explained by Bacon thus: “At a time when all human learning had suffered shipwreck these planks of Aristotelian and Platonic Philosophy, as being of a lighter and more inflated substance, were preserved and came down to us, while things more solid sank and almost passed into oblivion.”

Democritus’ principles, as quoted by Tyndall, are as follows:

1. From nothing comes nothing. Nothing that exists can be destroyed. All changes are due to the combination and separation of molecules.2. Nothing happens by chance. Every occurrence has its cause from which it follows by necessity.3. The only existing things are the atoms and empty space; all else is mere opinion.4. The atoms are infinite in number and infinitely various in form; they strike together and the lateral motions and whirlings which thus arise are the beginnings of worlds.5. The varieties of all things depend upon the varieties of their atoms, in number, size, and aggregation.6. The soul consists of fine, smooth, round atoms like those of fire. These are the most mobile of all. They interpenetrate the whole body and in their motions the phenomena of life arise.

1. From nothing comes nothing. Nothing that exists can be destroyed. All changes are due to the combination and separation of molecules.

2. Nothing happens by chance. Every occurrence has its cause from which it follows by necessity.

3. The only existing things are the atoms and empty space; all else is mere opinion.

4. The atoms are infinite in number and infinitely various in form; they strike together and the lateral motions and whirlings which thus arise are the beginnings of worlds.

5. The varieties of all things depend upon the varieties of their atoms, in number, size, and aggregation.

6. The soul consists of fine, smooth, round atoms like those of fire. These are the most mobile of all. They interpenetrate the whole body and in their motions the phenomena of life arise.

These principles with a few modifications and omissions might almost pass muster today. The great advance which has been made in modern times is not so much in the conceptions themselves as in the kind offoundation upon which the conceptions rest. The principles enumerated above were simply the opinions of one man or of a school of men. There were scores of other rival opinions, and no one could say which was the better. Today there is absolutely no philosophy in the field other than the atomic philosophy, at least among physicists. Yet this statement could not have been made even as much as twenty years ago. For in spite of all the multiple relationships between combining powers of the elements, and in spite of all the other evidences of chemistry and nineteenth-century physics, a group of the foremost of modern thinkers, until quite recently, withheld their allegiance from these theories. The most distinguished of this group was the German chemist and philosopher, Wilhelm Ostwald. However, in the preface to the last edition of hisOutlines of Chemistryhe now makes the following clear and frank avowal of his present position. He says:

I am now convinced that we have recently become possessed of experimental evidence of the discrete or grained nature of matter for which the atomic hypothesis sought in vain for hundreds and thousands of years. The isolation and counting of gaseous ions on the one hand ... and on the other the agreement of the Brownian movements with the requirements of the kinetic hypothesis ... justify the most cautious scientist in now speaking of the experimental proof of the atomic theory of matter. The atomic hypothesis is thus raised to the position of a scientifically well-founded theory.

I am now convinced that we have recently become possessed of experimental evidence of the discrete or grained nature of matter for which the atomic hypothesis sought in vain for hundreds and thousands of years. The isolation and counting of gaseous ions on the one hand ... and on the other the agreement of the Brownian movements with the requirements of the kinetic hypothesis ... justify the most cautious scientist in now speaking of the experimental proof of the atomic theory of matter. The atomic hypothesis is thus raised to the position of a scientifically well-founded theory.

II. GROWTH OF ELECTRICAL THEORIES

The granular theory of electricity, while unlike the atomic and kinetic theories of matter in that it can boast no great antiquity in anyform, is like them in that the first man who speculated upon the nature of electricity at all conceived of it as having an atomic structure. Yet it is only within very recent years—thirty at the most—that the modern electron theory has been developed. There are no electrical theories of any kind which go back of Benjamin Franklin (1750). Aside from the discovery of the Greeks that rubbed amber had the power of attracting to itself light objects, there was no knowledge at all earlier than 1600 A.D., when Gilbert, Queen Elizabeth’s surgeon, and a scientist of great genius and insight, found that a glass rod and some twenty other bodies, when rubbed with silk, act like the rubbed amber of the Greeks, and he consequently decided to describe the phenomenon by saying that the glass rod had become electrified (amberized, electron being the Greek word for amber), or, as we now say, had acquired a charge of electricity. In 1733 Dufay, a French physicist, further found that sealing wax, when rubbed with cat’s fur, was also electrified, but that it differed from the electrified glass rod, in that it strongly attracted any electrified body which was repelled by the glass, while it repelled any electrified body which was attracted by the glass. He was thus led to recognize two kinds of electricity, which he termed “vitreous” and “resinous.” About 1747 Benjamin Franklin, also recognizing these two kinds of electrification, introduced the terms “positive” and “negative,” to distinguish them. Thus, he said, we will arbitrarily call any body positively electrified if it is repelled by a glass rod which has been rubbed with silk, and we will call any body negatively electrified if it is repelled by sealing wax which has been rubbed with cat’s fur.These aretoday our definitions of positive and negative electrical charges. Notice that in setting them up we propose no theory whatever of electrification, but content ourselves simply with describing the phenomena.

In the next place it was surmised by Franklin and indeed asserted by him in the very use of the terms “positive” and “negative,” although the accurate proof of the relation was not made until the time of Faraday’s ice-pail experiment in 1837, that when glass is positively electrified by rubbing it with silk, the silk itself takes up a negative charge of exactly the same amount as the positive charge received by the glass, and, in general, thatpositive and negative electrical charges always appear simultaneously and in exactly equal amounts.

So far, still no theory. But in order to have a rational explanation of the phenomena so far considered, particularly this last one, Franklin now made the assumption that something which he chose to call the electrical fluid or “electrical fire” exists in normal amount as a constituent of all matter in the neutral, or unelectrified state, and that more than the normal amount in any body is manifested as a positive electrical charge, and less than the normal amount as a negative charge. Aepinus, professor of physics at St. Petersburg and an admirer of Franklin’s theory, pointed out that, in order to account for the repulsion of two negatively electrified bodies, it was necessary to assume that matter, when divorced from Franklin’s electrical fluid, was self-repellent, i.e., that it possessed properties quite different from those which are found in ordinary unelectrified matter. In order, however, to leave matter, whose independent existence was thus threatened, endowed with its familiar old properties, and in order toget electrical phenomena into a class by themselves, other physicists of the day, led by Symmer, 1759, preferred to assume thatmatter in a neutral state shows no electrical properties because it contains as constituents equal amounts of two weightless fluids which they called positive and negative electricity, respectively. From this point of view a positively charged body is one in which there is more of the positive fluid than of the negative, and a negatively charged body is one in which the negative fluid is in excess.

Thus arose the so-called two-fluid theory—a theory which divorced again the notions of electricity and matter after Franklin had taken a step toward bringing them together. This theory, in spite of its intrinsic difficulties, dominated the development of electrical science for one hundred years and more. This was because, if one did not bother himself much with the underlying physical conception, the theory lent itself admirably to the description of electrical phenomena and also to mathematical formulation. Further, it was convenient for the purposes of classification. It made it possible to treat electrical phenomena in a category entirely by themselves, without raising any troublesome questions as to the relation, for example, between electrical and gravitational or cohesive forces. But in spite of these advantages it was obviously a makeshift. For the notion of two fluids which could exert powerful forces and yet which were absolutely without weight—the most fundamental of physical properties—and the further notion of two fluids which had no physical properties whatever, that is, which disappeared entirely when they were mixed in equal proportions—these notions were in a high degree non-physical. Indeed, Sir J. J. Thomsonremarked in his Silliman Lectures in 1903 that

the physicists and mathematicians who did most to develop the fluid theories confined their attention to questions which involved only the law of forces between electrified bodies and the simultaneous production of equal quantities of plus and minus electricity, and refined and idealized their conception of the fluids themselves until any reference to their physical properties was considered almost indelicate.

the physicists and mathematicians who did most to develop the fluid theories confined their attention to questions which involved only the law of forces between electrified bodies and the simultaneous production of equal quantities of plus and minus electricity, and refined and idealized their conception of the fluids themselves until any reference to their physical properties was considered almost indelicate.

From the point of view of economy in hypothesis, Franklin’s one-fluid theory, as modified by Aepinus, was the better. Mathematically the two theories were identical. The differences may be summed up thus. The modified one-fluid theory required that matter, when divorced from the electrical fluid, have exactly the same properties which the two-fluid theory ascribed to negative electricity, barring only the property of fluidity. So that the most important distinction between the theories was that the two-fluid theory assumed the existence of three distinct entities, named positive electricity, negative electricity, and matter, while the one-fluid theory reduced these three entities to two, which Franklin called matter and electricity, but which might perhaps as well have been called positive electricity and negative electricity, unelectrified matter being reduced to a mere combination of these two.

Of course, the idea of a granular structure for electricity was foreign to the two-fluid theory, and since this dominated the development of electrical science, there was seldom any mention in connection with it of an electrical atom, even as a speculative entity. But with Franklin the case was different. His theory was essentially a material one, andhe unquestionably believed in the existence of an electrical particle or atom, for he says: “The electrical matter consists of particles extremely subtle, since it can permeate common matter, even the densest, with such freedom and ease as not to receive any appreciable resistance.” When Franklin wrote that, however, he could scarcely have dreamed that it would ever be possible to isolate and study by itself one of the ultimate particles of the electrical fluid. The atomic theory of electricity was to him what the atomic theory of matter was to Democritus, a pure speculation.

The first bit of experimental evidence which appeared in its favor came in 1833, when Faraday found that the passage of a given quantity of electricity through a solution containing a compound of hydrogen, for example, would always cause the appearance at the negative terminal of the same amount of hydrogen gas irrespective of the kind of hydrogen compound which had been dissolved, and irrespective also of the strength of the solution; that, further, the quantity of electricity required to cause the appearance of one gram of hydrogen would always deposit from a solution containing silver exactly 107.1 grams of silver. This meant, since the weight of the silver atom is exactly 107.1 times the weight of the hydrogen atom, that the hydrogen atom and the silver atom are associated in the solution with exactly the same quantity of electricity. When it was further found in this way that all atoms which are univalent in chemistry, that is, which combine with one atom of hydrogen, carry precisely the same quantity of electricity, and all atoms which are bivalent carry twice this amount, and, in general,that valency, in chemistry, is always exactly proportional to the quantity of electricity carried by the atom in question, it was obvious that the atomic theory of electricity had been given very strong support.

But striking and significant as were these discoveries, they did not serve at all to establish the atomic hypothesis of the nature of electricity. They were made at the very time when attention began to be directed strongly away from the conception of electricity as a substance of any kind, and it was no other than Faraday himself who, in spite of the brilliant discoveries just mentioned, started this second period in the development of electrical theory, a period lasting from 1840 to about 1900. In this period electrical phenomena are almost exclusively thought of in terms of stresses and strains in the medium which surrounds the electrified body. Up to this time a more or less definite something called a charge of electricity had been thought of as existing on a charged body and had been imagined to exert forces on other charged bodies at a distance from it in quite the same way in which the gravitational force of the earth acts on the moon or that of the sun on the earth. This notion of action at a distance was repugnant to Faraday, and he found in the case of electrical forces experimental reasons for discarding it which had not then, nor have they as yet, been found in the case of gravitational forces. These reasons are summed up in the statement that the electrical force between two charged bodies is found to depend on the nature of the intervening medium, while gravitational pulls are, so far as is known, independent of intervening bodies. Faraday, therefore, pictured to himself theintervening medium as transmitting electrical force in quite the same way in which an elastic deformation started at one end of a rod is transmitted by the rod. Further, since electrical forces act through a vacuum, Faraday had to assume that it is the ether which acts as the transmitter of these electrical stresses and strains. The properties of the ether were then conceived of as modified by the presence of matter in order to account for the fact that the same two charges attract each other with different forces according as the intervening medium is, for example, glass, or ebonite, or air, or merely ether. These views, conceived by Faraday and put into mathematical form by Maxwell, called attention away from the electrical phenomena in or on a conductor carrying electricity and focused it upon the stresses and strains taking place in the medium about the conductor. When in 1886 Heinrich Hertz in Bonn, Germany, proved by direct experiment that electrical forces are indeed transmitted in the form of electric waves, which travel through space with the speed of light exactly as the Faraday-Maxwell theory had predicted, the triumph of the ether-stress point of view was complete. Thereupon textbooks were written by enthusiastic, but none too cautious, physicists in which it was asserted that an electric charge is nothing more than a “state of strain in the ether,” and an electric current, instead of representing the passage of anything definite along the wire, corresponds merely to a continuous “slip” or “breakdown of a strain” in the medium within the wire. Sir Oliver Lodge’s early book,Modern Views of Electricity, was perhaps the most influential disseminator and expounder of this point of view.

Now what had actually been proved was not that electricity is a state of strain, but that when any electrical charge appears upon a body the medium about the body does indeed become the seat of new forces which are transmitted through the medium, like any elastic forces, with a definite speed. Hence it is entirely proper to say that the medium about a charged body is in a state of strain. But it is one thing to say that the electrical charge on the bodyproducesa state of strain in the surrounding medium, and quite another thing to say that the electrical charge isnothing buta state of strain in the surrounding medium, just as it is one thing to say that when a man stands on a bridge he produces a mechanical strain in the timbers of the bridge, and another thing to say that the man is nothing more than a mechanical strain in the bridge. The practical difference between the two points of view is that in the one case you look for other attributes of the man besides the ability to produce a strain in the bridge, and in the other case you do not look for other attributes. So the strain theory, although not irreconcilable with the atomic hypothesis, was actually antagonistic to it, because it led men to think of the strain as distributed continuously about the surface of the charged body, rather than as radiating from definite spots or centers peppered over the surface of the body. Between 1833 and 1900, then, the physicist was in this peculiar position: when he was thinking of the passage of electricity through a solution, he for the most part, following Faraday, pictured to himself definite specks or atoms of electricity as traveling through the solution, each atom of matter carrying an exact multiple, which might be anywhere between one and eight, of a definite elementary electrical atom, while, when he wasthinking of the passage of a current through a metallic conductor, he gave up altogether the atomic hypothesis, and attempted to picture the phenomenon to himself as a continuous “slip” or “breakdown of a strain” in the material of the wire. In other words, he recognized two types of electrical conduction which were wholly distinct in kind—electrolytic conduction and metallic conduction; and since more of the problems of the physicist dealt with metallic than with electrolytic conduction, the atomic conception, as a general hypothesis, was almost, though not quite, unheard of. Of course it would be unjust to the thinkers of this period to say that they failed to recognize and appreciate this gulf between current views as to the nature of electrolytic and metallic conduction, and simply ignored the difficulty. This they did not do, but they had all sorts of opinions as to the causes. Maxwell himself in his text onElectricity and Magnetism, published in 1873, recognizes, in the chapter on “Electrolysis,”[3]the significance of Faraday’s laws, and even goes so far as to say that “for convenience in description we may call this constant molecular charge (revealed by Faraday’s experiments) one molecule of electricity.” Nevertheless, a little farther on he repudiates the idea that this term can have any physical significance by saying that “it is extremely improbable that when we come to understand the true nature of electrolysis we shall retain in any form the theory of molecular charges, for then we shall have obtained a secure basis on which to form a true theory of electric currents and so become independent of these provisional hypotheses.”

And as a matter of fact, Faraday’s experiments had not shown at all that electrical charges on metallic conductors consist of specks of electricity, even though they had shown that the charges on ions in solutions have definite values which are always the same for univalent ions. It was entirely logical to assume, as Maxwell did, that an ion took into solution a definite quantity of electricity because of some property which it had of always charging up to the same amount from a charged plate. There was no reason for assuming the chargeon the electrodeto be made up of some exact number of electrical atoms.

On the other hand, Wilhelm Weber, in papers written in 1871,[4]built up his whole theory of electromagnetism on a basis which was practically identical with the modified Franklin theory and explained all the electrical phenomena exhibited by conductors, including thermo-electric and Peltier effects, on the assumption of two types of electrical constituents of atoms, one of which was very much more mobile than the other. Thus the hypothetical molecular current, which Ampere had imagined fifty years earlier to be continually flowing inside of molecules and thereby rendering these molecules little electromagnets, Weber definitely pictures to himself as the rotation of light, positive charges about heavy negative ones. His words are:

The relation of the two particles as regards their motions is determined by the ratio of their massesand,on the assumption that inandare included the masses of the ponderable atoms which are attached to the electrical atoms. Letbe the positive electrical particle. Let the negative be exactly equal and opposite and therefore denoted by(instead of).But let a ponderable atom be attracted to the latter so that its mass is thereby so greatly increased as to make the mass of the positive particle vanishingly small in comparison. The particlemay then be thought of as at rest and the particleas in motion about the particle.The two unlike particles in the condition described constitute then an Amperian molecular current.

The relation of the two particles as regards their motions is determined by the ratio of their massesand,on the assumption that inandare included the masses of the ponderable atoms which are attached to the electrical atoms. Letbe the positive electrical particle. Let the negative be exactly equal and opposite and therefore denoted by(instead of).But let a ponderable atom be attracted to the latter so that its mass is thereby so greatly increased as to make the mass of the positive particle vanishingly small in comparison. The particlemay then be thought of as at rest and the particleas in motion about the particle.The two unlike particles in the condition described constitute then an Amperian molecular current.

It is practically this identical point of view which has been elaborated and generalized by Lorentz and others within the past three decades in the development of the modern electron theory, with this single difference, that we now have experimental proof that it is the negative particle whose mass or inertia is negligible in comparison with that of the positive instead of the reverse. Weber even went so far as to explain thermo-electric and Peltier effects by differences in the kinetic energies in different conductors of the electrical particles.[5]Nevertheless his explanations are here widely at variance with our modern conceptions of heat.

Again, in a paper read before the British Association at Belfast in 1874, G. Johnstone Stoney not only stated clearly the atomic theory of electricity, but actually went so far as to estimate the value of the elementary electrical charge, and he obtained a value which was about as reliable as any which had been found until within quite recent years. He got, as will be more fully explained in the next chapter,,and he got this result from the amount of electricity necessary to separate from a solution one gram of hydrogen, combined with kinetic theory estimates as to the number of atoms of hydrogen in two grams, i.e., in one gram moleculeof that element. This paper was entitled, “On the Physical Units of Nature,” and though read in 1874 it was not published in full until 1881.[6]After showing that all physical measurements may be expressed in terms of three fundamental units, he asserts that it would be possible to replace our present purely arbitrary units (the centimeter, the gram, and the second) by three natural units, namely, the velocity of light, the coefficient of gravitation, and the elementary electrical charge. With respect to the last he says:

Finally nature presents us with a single definite quantity of electricity which is independent of the particular bodies acted on. To make this clear, I shall express Faraday’s law in the following terms, which, as I shall show, will give it precision, viz.:For each chemical bond which is ruptured within an electrolyte a certain quantity of electricity traverses the electrolyte which is the same in all cases. This definite quantity of electricity I shall call.If we make this our unit of electricity, we shall probably have made a very important step in our study of molecular phenomena.Hence we have very good reason to suppose that in,and,we have three of a series of systematic units that in an eminent sense are the units of nature, and stand in an intimate relation with the work which goes on in her mighty laboratory.

Finally nature presents us with a single definite quantity of electricity which is independent of the particular bodies acted on. To make this clear, I shall express Faraday’s law in the following terms, which, as I shall show, will give it precision, viz.:For each chemical bond which is ruptured within an electrolyte a certain quantity of electricity traverses the electrolyte which is the same in all cases. This definite quantity of electricity I shall call.If we make this our unit of electricity, we shall probably have made a very important step in our study of molecular phenomena.

Hence we have very good reason to suppose that in,and,we have three of a series of systematic units that in an eminent sense are the units of nature, and stand in an intimate relation with the work which goes on in her mighty laboratory.

Take one more illustration from prominent writers of this period. In his Faraday lecture delivered at the Royal Institution in 1881, Helmholtz spoke as follows:

Now the most startling result of Faraday’s law is perhaps this, if we accept the hypothesis that the elementary substances are composed of atoms, we cannot avoid concluding that electricity also, positive as well as negative, is divided into definite elementary portions which behave like atoms of electricity.[7]

Now the most startling result of Faraday’s law is perhaps this, if we accept the hypothesis that the elementary substances are composed of atoms, we cannot avoid concluding that electricity also, positive as well as negative, is divided into definite elementary portions which behave like atoms of electricity.[7]

This looks like a very direct and unequivocal statement of the atomic theory of electricity, and yet in the same lecture Helmholtz apparently thinks of metallic conduction as something quite different from electrolytic when he says:

All these facts show that electrolytic conduction is not at all limited to solutions of acids or salts. It will, however, be rather a difficult problem to find out how far the electrolytic conduction is extended, and I am not yet prepared to give a positive answer.

All these facts show that electrolytic conduction is not at all limited to solutions of acids or salts. It will, however, be rather a difficult problem to find out how far the electrolytic conduction is extended, and I am not yet prepared to give a positive answer.

The context shows that he thought of extending the idea of electrolytic conduction to a great many insulators. But there is no indication that he thought of extending it to metallic conductors and imagining these electrical atoms as existing as discrete individual things on charged metals or as traveling along a wire carrying an electrical current. Nevertheless, the statement quoted above is one of the most unequivocal which can be found anywhere up to about 1899 as to the atomic nature of electricity.

The foregoing quotations are sufficient to show that the atomic theory of electricity, like the atomic theory of matter, is not at all new so far as the conception alone is concerned. In both cases there were individuals who held almost exactly the modern point of view. In both cases, too, the chief new developments have consisted in the appearance of new and exact experimental data which has silenced criticism and compelled the abandonment of other points of view which up to about 1900 flourished along with, and even more vigorously than, the atomic conception. Even in 1897 Lord Kelvin, with a full knowledge of all the new work which was appearing on X-rays and cathode rays, could seriously raise the question whether electricity might not be a“continuous homogeneous liquid.” He does it in these words:

Varley’s fundamental discovery of the cathode rays, splendidly confirmed and extended by Crookes, seems to me to necessitate the conclusion that resinous electricity, not vitreous, isThe Electric Fluid, if we are to have a one-fluid theory of electricity. Mathematical reasons prove that if resinous electricity is a continuous homogeneous liquid it must, in order to produce the phenomena of contact electricity, which you have seen this evening, be endowed with a cohesional quality. It is just conceivable, though it does not at present seem to me very probable, that this idea may deserve careful consideration. I leave it, however, for the present and prefer to consider an atomic theory of electricity foreseen as worthy of thought by Faraday and Clerk-Maxwell, very definitely proposed by Helmholtz in his last lecture to the Royal Institution, and largely accepted by present-day workers and teachers. Indeed Faraday’s laws of electrolysis seem to necessitate something atomic in electricity....[8]

Varley’s fundamental discovery of the cathode rays, splendidly confirmed and extended by Crookes, seems to me to necessitate the conclusion that resinous electricity, not vitreous, isThe Electric Fluid, if we are to have a one-fluid theory of electricity. Mathematical reasons prove that if resinous electricity is a continuous homogeneous liquid it must, in order to produce the phenomena of contact electricity, which you have seen this evening, be endowed with a cohesional quality. It is just conceivable, though it does not at present seem to me very probable, that this idea may deserve careful consideration. I leave it, however, for the present and prefer to consider an atomic theory of electricity foreseen as worthy of thought by Faraday and Clerk-Maxwell, very definitely proposed by Helmholtz in his last lecture to the Royal Institution, and largely accepted by present-day workers and teachers. Indeed Faraday’s laws of electrolysis seem to necessitate something atomic in electricity....[8]

What was the new experimental work which already in 1897 was working this change in viewpoint? Much of it was at first little if at all more convincing than that which had been available since Faraday’s time. Nevertheless it set physicists to wondering whether stresses and strains in the ether had not been a bit overworked, and whether in spite of their undoubted existence electricity itself might not after all be something more definite, more material, than the all-conquering Maxwell theory had assumed it to be.

The result of the past twenty-five years has been to bring us back very close to where Franklin was in 1750, with the single difference that our modern electron theory rests upon a mass of very direct and convincing evidence, which it is the purpose of the next chapters to present.


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