Fig. 185.Fig. 185.
Assume that a source of alternating currentSbe connected, as in Fig. 185, with one of its terminals to earth (conveniently to the water mains) and with the other to a body of large surfaceP. When the electric oscillation is set up there will be a movement of electricity in and out ofP, and alternating currents will pass through the earth, converging to, or diverging from, the pointCwhere the ground connection is made. In this manner neighboring points on the earth's surface within a certain radius will be disturbed. But the disturbance will diminish with the distance, and the distance at which the effect will still be perceptible will depend on the quantity of electricity set in motion. Since the bodyPis insulated, in order to displace a considerable quantity, the potential of the source must be excessive, since there would be limitations as to the surface ofP. The conditions might be adjusted so that the generator or sourceSwill set up the same electrical movement as though its circuit were closed. Thus it is certainly practicable to impress an electric vibration at least of a certain low period upon the earth by means of proper machinery. At what distance such a vibration might be made perceptible can only be conjectured. I have on another occasion considered the question how the earth might behave to electric disturbances. There is no doubt that, since in such an experiment the electrical density at the surface could be but extremely small considering the size of the earth, the air would not act as a very disturbing factor, and there would be not much energy lost through the action of the air, which would be the case if the density were great. Theoretically, then, it could not require a great amount of energy to produce a disturbance perceptible at great distance, or even all over the surface of the globe. Now, it is quite certain that at any point within a certain radius of the sourceSa properly adjusted self-induction and capacity device can be set in action by resonance. But not only can this be done, but another sourceS1, Fig. 185, similar toS, or any number of such sources, can be set to work in synchronism with the latter, and the vibration thus intensified and spread over a large area, or a flow of electricity produced to or from the sourceS1if the same be of opposite phase to the sourceS. I think that beyond doubt it is possible to operate electrical devices in a city through the ground or pipe system by resonance from an electrical oscillator located at a central point. But the practical solution of this problem would be of incomparably smaller benefit to man than the realization of the scheme of transmitting intelligence, or perhaps power, to any distance through the earth or environing medium. If this is at all possible, distance does not mean anything. Proper apparatus must first be produced by means of which the problem can be attacked and I have devoted much thought to this subject. I am firmly convinced that it can be done and hope that we shall live to see it done.
Returning now to the light effects which it has been the chief object to investigate, it is thought proper to divide these effects into four classes: 1. Incandescence of a solid. 2. Phosphorescence. 3. Incandescence or phosphorescence of a rarefied gas; and 4. Luminosity produced in a gas at ordinary pressure. The first question is: How are these luminous effects produced? In order to answer this question as satisfactorily as I am able to do in the light of accepted views and with the experience acquired, and to add some interest to this demonstration, I shall dwell here upon a feature which I consider of great importance, inasmuch as it promises, besides, to throw a better light upon the nature of most of the phenomena produced by high-frequency electric currents. I have on other occasions pointed out the great importance of the presence of the rarefied gas, or atomic medium in general, around the conductor through which alternate currents of high frequency are passed, as regards the heating of the conductor by the currents. My experiments, described some time ago, have shown that, the higher the frequency and potential difference of the currents, the more important becomes the rarefied gas in which the conductor is immersed, as a factor of the heating. The potential difference, however, is, as I then pointed out, a more important element than the frequency. When both of these are sufficiently high, the heating may be almost entirely due to the presence of the rarefied gas. The experiments to follow will show the importance of the rarefied gas, or, generally, of gas at ordinary or other pressure as regards the incandescence or other luminous effects produced by currents of this kind.
I take two ordinary 50-volt 16c. p.lamps which are in every respect alike, with the exception, that one has been opened at the top and the air has filled the bulb, while the other is at the ordinary degree of exhaustion of commercial lamps. When I attach the lamp which is exhausted to the terminal of the secondary of the coil, which I have already used, as in experiments illustrated in Fig. 179afor instance, and turn on the current, the filament, as you have before seen, comes to high incandescence. When I attach the second lamp, which is filled with air, instead of the former, the filament still glows, but much less brightly. This experiment illustrates only in part the truth of the statements before made. The importance of the filament's being immersed in rarefied gas is plainly noticeable but not to such a degree as might be desirable. The reason is that the secondary of this coil is wound for low tension, having only 150 turns, and the potential difference at the terminals of the lamp is therefore small. Were I to take another coil with many more turns in the secondary, the effect would be increased, since it depends partially on the potential difference, as before remarked. But since the effect likewise depends on the frequency, it maybe properly stated that it depends on the time rate of the variation of the potential difference. The greater this variation, the more important becomes the gas as an element of heating. I can produce a much greater rate of variation in another way, which, besides, has the advantage of doing away with the objections, which might be made in the experiment just shown, even if both the lamps were connected in series or multiple arc to the coil, namely, that in consequence of the reactions existing between the primary and secondary coil the conclusions are rendered uncertain. This result I secure by charging, from an ordinary transformer which is fed from the alternating current supply station, a battery of condensers, and discharging the latter directly through a circuit of small self-induction, as before illustrated in Figs. 183a, 183b, and 183c.
Fig. 186a, 186b, 186c.Fig.186a.Fig.186b.Fig.186c.
In Figs. 186a, 186band 186c, the heavy copper barsB B1, areconnected to the opposite coatings of a battery of condensers, or generally in such way, that the high frequency or sudden discharges are made to traverse them. I connect first an ordinary 50-volt incandescent lamp to the bars by means of the clampsc c. The discharges being passed through the lamp, the filament is rendered incandescent, though the current through it is very small, and would not be nearly sufficient to produce a visible effect under the conditions of ordinary use of the lamp. Instead of this I now attach to the bars another lamp exactly like the first, but with the seal broken off, the bulb being therefore filled with air at ordinary pressure. When the discharges are directed through the filament, as before, it does not become incandescent. But the result might still be attributed to one of the many possible reactions. I therefore connect both the lamps in multiple arc as illustrated in Fig. 186a. Passing the discharges through both the lamps, again the filament in the exhausted lamplglows very brightly while that in the non-exhausted lampl1remains dark, as previously. But it should not be thought that the latter lamp is taking only a small fraction of the energy supplied to both the lamps; on the contrary, it may consume a considerable portion of the energy and it may become even hotter than the one which burns brightly. In this experiment the potential difference at the terminals of the lamps varies in sign theoretically three to four million times a second. The ends of the filaments are correspondingly electrified, and the gas in the bulbs is violently agitated and a large portion of the supplied energy is thus converted into heat. In the non-exhausted bulb, there being a few million times more gas molecules than in the exhausted one, the bombardment, which is most violent at the ends of the filament, in the neck of the bulb, consumes alarge portion of the energy without producing any visible effect. The reason is that, there being many molecules, the bombardment is quantitatively considerable, but the individual impacts are not very violent, as the speeds of the molecules are comparatively small owing to the small free path. In the exhausted bulb, on the contrary, the speeds are very great, and the individual impacts are violent and therefore better adapted to produce a visible effect. Besides, the convection of heat is greater in the former bulb. In both the bulbs the current traversing the filaments is very small, incomparably smaller than that which they require on an ordinary low-frequency circuit. The potential difference, however, at the ends of the filaments is very great and might be possibly 20,000 volts or more, if the filaments were straight and their ends far apart. In the ordinary lamp a spark generally occurs between the ends of the filament or between the platinum wires outside, before such a difference of potential can be reached.
It might be objected that in the experiment before shown the lamps, being in multiple arc, the exhausted lamp might take a much larger current and that the effect observed might not be exactly attributable to the action of the gas in the bulbs. Such objections will lose much weight if I connect the lamps in series, with the same result. When this is done and the discharges are directed through the filaments, it is again noted that the filament in the non-exhausted bulbl1, remains dark, while that in the exhausted one (l) glows even more intensely than under its normal conditions of working, Fig. 186b. According to general ideas the current through the filaments should now be the same, were it not modified by the presence of the gas around the filaments.
At this juncture I may point out another interesting feature, which illustrates the effect of the rate of change of potential of the currents. I will leave the two lamps connected in series to the barsB B1, as in the previous experiment, Fig. 186b, but will presently reduce considerably the frequency of the currents, which was excessive in the experiment just before shown. This I may do by inserting a self-induction coil in the path of the discharges, or by augmenting the capacity of the condensers. When I now pass these low-frequency discharges through the lamps, the exhausted lamplagain is as bright as before, but it is notedalso that the non-exhausted lampl1glows, though not quite as intensely as the other. Reducing the current through the lamps, I may bring the filament in the latter lamp to redness, and, though the filament in the exhausted lamplis bright, Fig. 186c, the degree of its incandescence is much smaller than in Fig. 186b, when the currents were of a much higher frequency.
In these experiments the gas acts in two opposite ways in determining the degree of the incandescence of the filaments, that is, by convection and bombardment. The higher the frequency and potential of the currents, the more important becomes the bombardment. The convection on the contrary should be the smaller, the higher the frequency. When the currents are steady there is practically no bombardment, and convection may therefore with such currents also considerably modify the degree of incandescence and produce results similar to those just before shown. Thus, if two lamps exactly alike, one exhausted and one not exhausted, are connected in multiple arc or series to a direct-current machine, the filament in the non-exhausted lamp will require a considerably greater current to be rendered incandescent. This result is entirely due to convection, and the effect is the more prominent the thinner the filament. Professor Ayrton and Mr. Kilgour some time ago published quantitative results concerning the thermal emissivity by radiation and convection in which the effect with thin wires was clearly shown. This effect may be strikingly illustrated by preparing a number of small, short, glass tubes, each containing through its axis the thinnest obtainable platinum wire. If these tubes be highly exhausted, a number of them may be connected in multiple arc to a direct-current machine and all of the wires may be kept at incandescence with a smaller current than that required to render incandescent a single one of the wires if the tube be not exhausted. Could the tubes be so highly exhausted that convection would be nil, then the relative amounts of heat given off by convection and radiation could be determined without the difficulties attending thermal quantitative measurements. If a source of electric impulses of high frequency and very high potential is employed, a still greater number of the tubes may be taken and the wires rendered incandescent by a current not capable of warming perceptibly a wire of the same size immersed in air at ordinary pressure, and conveying the energy to all of them.
I may here describe a result which is still more interesting, and to which I have been led by the observation of these phenomena. I noted that small differences in the density of the air produced a considerable difference in the degree of incandescence of the wires, and I thought that, since in a tube, through which a luminous discharge is passed, the gas is generally not of uniform density, a very thin wire contained in the tube might be rendered incandescent at certain places of smaller density of the gas, while it would remain dark at the places of greater density, where the convection would be greater and the bombardment less intense. Accordingly a tubetwas prepared, as illustrated in Fig. 187, which contained through the middle a very fine platinum wirew. The tube was exhausted to a moderate degree and it was found that when it was attached to the terminal of a high-frequency coil the platinum wirewwould indeed, become incandescent in patches, as illustrated in Fig. 187. Later a number of these tubes with one or more wires were prepared, each showing this result. The effect was best noted when the striated discharge occurred in the tube, but was also produced when the striæ were not visible, showing that, even then, the gas in the tube was not of uniform density. The position of the striæ was generally such, that the rarefactions corresponded to the places of incandescence or greater brightness on the wirew. But in a few instances it was noted, that the bright spots on the wire were covered by the dense parts of the striated discharge as indicated bylin Fig. 187, though the effect was barely perceptible. This was explained in a plausible way by assuming that the convection was not widely different in the dense and rarefied places, and that the bombardment was greater on the dense places of the striated discharge. It is, in fact, often observed in bulbs, that under certain conditions a thin wire is brought to higher incandescence when the air is not too highly rarefied. This is the case when the potential of the coil is not high enough for the vacuum, but the result may be attributed to many different causes. In all cases this curious phenomenon of incandescence disappears when the tube, or rather the wire, acquires throughout a uniform temperature.
Fig. 187, 188.Fig. 187.Fig. 188.
Disregarding now the modifying effect of convection there are then two distinct causes which determine the incandescence of a wire or filament with varying currents, that is, conduction current and bombardment. With steady currents we have to deal only with the former of these two causes, and the heating effect is a minimum, since the resistance is least to steady flow. When the current is a varying one the resistance is greater, and hencethe heating effect is increased. Thus if the rate of change of the current is very great, the resistance may increase to such an extent that the filament is brought to incandescence with inappreciable currents, and we are able to take a short and thick block of carbon or other material and bring it to bright incandescence with a current incomparably smaller than that required to bring to the same degree of incandescence an ordinary thin lamp filament with a steady or low frequency current. This result is important, and illustrates how rapidly our views on these subjects are changing, and how quickly our field of knowledge is extending. In the art of incandescent lighting, to view this result in one aspect only, it has been commonly considered as an essential requirement for practical success, that the lamp filament should be thin and of high resistance. But now we know that the resistance of the filament to the steady flow does not mean anything; the filament might as well be short and thick; for if it be immersed in rarefied gas it will become incandescent by the passage of a small current. It all depends on the frequency and potential of the currents. We may conclude from this, that itwould be of advantage, so far as the lamp is considered, to employ high frequencies for lighting, as they allow the use of short and thick filaments and smaller currents.
If a wire or filament be immersed in a homogeneous medium, all the heating is due to true conduction current, but if it be enclosed in an exhausted vessel the conditions are entirely different. Here the gas begins to act and the heating effect of the conduction current, as is shown in many experiments, may be very small compared with that of the bombardment. This is especially the case if the circuit is not closed and the potentials are of course very high. Suppose that a fine filament enclosed in an exhausted vessel be connected with one of its ends to the terminal of a high tension coil and with its other end to a large insulated plate. Though the circuit is not closed, the filament, as I have before shown, is brought to incandescence. If the frequency and potential be comparatively low, the filament is heated by the current passingthrough it. If the frequency and potential, and principally the latter, be increased, the insulated plate need be but very small, or may be done away with entirely; still the filament will become incandescent, practically all the heating being then due to the bombardment. A practical way of combining both the effects of conduction currents and bombardment is illustrated in Fig. 188, in which an ordinary lamp is shown provided with a very thin filament which has one of the ends of the latter connected to a shade serving the purpose of the insulated plate, and the other end to the terminal of a high tension source. It should not be thought that only rarefied gas is an important factor in the heating of a conductor by varying currents, but gas at ordinary pressure may become important, if the potential difference and frequency of the currents is excessive. On this subject I have already stated, that when a conductor is fused by a stroke of lightning, the current through it may be exceedingly small, not even sufficient to heat the conductor perceptibly, were the latter immersed in a homogeneous medium.
From the preceding it is clear that when a conductor of high resistance is connected to the terminals of a source of high frequency currents of high potential, there may occur considerable dissipation of energy, principally at the ends of the conductor, in consequence of the action of the gas surrounding the conductor. Owing to this, the current through a section of the conductor at a point midway between its ends may be much smaller thanthrough a section near the ends. Furthermore, the current passes principally through the outer portions of the conductor, but this effect is to be distinguished from the skin effect as ordinarily interpreted, for the latter would, or should, occur also in a continuous incompressible medium. If a great many incandescent lamps are connected in series to a source of such currents, the lamps at the ends may burn brightly, whereas those in the middle may remain entirely dark. This is due principally to bombardment, as before stated. But even if the currents be steady, provided the difference of potential is very great, the lamps at the end will burn more brightly than those in the middle. In such case there is no rhythmical bombardment, and the result is produced entirely by leakage. This leakage or dissipation into space when the tension is high, is considerable when incandescent lamps are used, and still more considerable with arcs, for the latter act like flames. Generally, of course, the dissipation is much smaller with steady, than with varying, currents.
I have contrived an experiment which illustrates in an interesting manner the effect of lateral diffusion. If a very long tube is attached to the terminal of a high frequency coil, the luminosity is greatest near the terminal and falls off gradually towards the remote end. This is more marked if the tube is narrow.
A small tube about one-half inch in diameter and twelve inches long (Fig. 189), has one of its ends drawn out into a fine fibrefnearly three feet long. The tube is placed in a brass socketTwhich can be screwed on the terminalT1of the induction coil. The discharge passing through the tube first illuminates the bottom of the same, which is of comparatively large section; but through the long glass fibre the discharge cannot pass. But gradually the rarefied gas inside becomes warmed and more conducting and the discharge spreads into the glass fibre. This spreading is so slow, that it may take half a minute or more until the discharge has worked through up to the top of the glass fibre, then presenting the appearance of a strongly luminous thin thread. By adjusting the potential at the terminal the light may be made to travel upwards at any speed. Once, however, the glass fibre is heated, the discharge breaks through its entire length instantly. The interesting point to be noted is that, the higher the frequency of the currents, or in other words, the greater relatively the lateral dissipation, at a slower rate may the light be made to propagate through the fibre. This experimentis best performed with a highly exhausted and freshly made tube. When the tube has been used for some time the experiment often fails. It is possible that the gradual and slow impairment of the vacuum is the cause. This slow propagation of the discharge through a very narrow glass tube corresponds exactly to the propagation of heat through a bar warmed at one end. The quicker the heat is carried away laterally the longer time it will take for the heat to warm the remote end. When the current of a low frequency coil is passed through the fibre from end to end, then the lateral dissipation is small and the discharge instantly breaks through almost without exception.
Fig. 189, 190.Fig. 189.Fig. 190.
After these experiments and observations which have shown the importance of the discontinuity or atomic structure of the medium and which will serve to explain, in a measure at least, the nature of the four kinds of light effects producible with these currents, I may now give you an illustration of these effects. For the sake of interest I may do this in a manner which to many of you might be novel. You have seen before that we may now convey the electric vibration to a body by means of a single wire or conductor of any kind. Since thehuman frame is conducting I may convey the vibration through my body.
First, as in some previous experiments, I connect my body with one of the terminals of a high-tension transformer and take in my hand an exhausted bulb which contains a small carbon button mounted upon a platinum wire leading to the outside of the bulb, and the button is rendered incandescent as soon as the transformer is set to work (Fig. 190). I may place a conducting shade on the bulb which serves to intensify the action, but is not necessary. Nor is it required that the button should be in conducting connection with the hand through a wire leading through the glass, for sufficient energy may be transmitted through the glass itself by inductive action to render the button incandescent.
Fig. 191, 192.Fig. 191.Fig. 192.
Next I take a highly exhausted bulb containing a strongly phosphorescent body, above which is mounted a small plate of aluminum on a platinum wire leading to the outside, and the currents flowing through my body excite intense phosphorescence in the bulb (Fig. 191). Next again I take in my hand a simple exhausted tube, and in the same manner the gas inside the tube is rendered highly incandescent or phosphorescent (Fig. 192). Finally, I may take in my hand a wire, bare or covered with thick insulation, it is quite immaterial; the electrical vibration is so intense as to cover the wire with a luminous film (Fig. 193).
Fig. 193, 194, 195.Fig. 193.Fig. 194.Fig. 195.
A few words must now be devoted to each of these phenomena. In the first place, I will consider the incandescence of a button or of a solid in general, and dwell upon some facts which apply equally to all these phenomena. It was pointed out before that when a thin conductor, such as a lamp filament, for instance, is connected with one of its ends to the terminal of a transformer of high tension the filament is brought to incandescence partly by a conduction current and partly by bombardment. The shorter and thicker the filament the more important becomes the latter, and finally, reducing the filament to a mere button, all the heating must practically be attributed to the bombardment. So in the experiment before shown, the button is rendered incandescent by the rhythmical impact of freely movable small bodies in the bulb. These bodies may be the molecules of the residual gas, particles of dust or lumps torn from the electrode; whatever they are, it is certain that the heating of the button is essentially connected with the pressure of such freely movable particles, or of atomic matter in general in the bulb. The heating is the more intense the greater the number of impacts per second and the greater the energy of each impact. Yet the button would be heated also if it were connected to a source of a steady potential. In such a case electricity would be carried away from the button by the freely movable carriers or particles flying about, and the quantity of electricity thus carried away might be sufficient to bring the button to incandescence by its passage through the latter. But the bombardment could not be of great importance in such case. For this reason it would require a comparatively very great supply of energy to the button to maintain it at incandescence with a steady potential. The higher the frequency of the electric impulses the more economically can the button be maintained at incandescence. One of the chief reasons why this is so, is, I believe, that with impulses of very high frequency there is less exchange of the freely movable carriers around the electrode and this means, that in the bulb the heated matter is better confined to the neighborhood of the button. If a double bulb, as illustrated in Fig. 194 be made, comprising a large globeBand a small oneb, each containing as usual a filamentfmounted on a platinum wirewandw1, it is found, that if the filamentsf fbe exactly alike, it requires less energy to keep the filament in the globebat a certain degree of incandescence, than that in the globeB. This is due to the confinement of themovable particles around the button. In this case it is also ascertained, that the filament in the small globebis less deteriorated when maintained a certain length of time at incandescence. This is a necessary consequence of the fact that the gas in the small bulb becomes strongly heated and therefore a very good conductor, and less work is then performed on the button, since the bombardment becomes less intense as the conductivity of the gas increases. In this construction, of course, the small bulb becomes very hot and when it reaches an elevated temperature the convection and radiation on the outside increase. On another occasion I have shown bulbs in which this drawback was largely avoided. In these instances a very small bulb, containing a refractory button, was mounted in a large globe and the space between the walls of both was highly exhausted. The outer large globe remained comparatively cool in such constructions. When the large globe was on the pump and the vacuum between the walls maintained permanent by the continuous action of the pump, the outer globe would remain quite cold, while the button in the small bulb was kept at incandescence. But when the seal was made, and the button in the small bulb maintained incandescent some length of time, the large globe too would become warmed. From this I conjecture that if vacuous space (as Prof. Dewar finds) cannot convey heat, it is so merely in virtue of our rapid motion through space or, generally speaking, by the motion of the medium relatively to us, for a permanent condition couldnot be maintained without the medium being constantly renewed. A vacuum cannot, according to all evidence, be permanently maintained around a hot body.
In these constructions, before mentioned, the small bulb inside would, at least in the first stages, prevent all bombardment against the outer large globe. It occurred to me then to ascertain how a metal sieve would behave in this respect, and several bulbs, as illustrated in Fig. 195, were prepared for this purpose. In a globeb, was mounted a thin filamentf(or button) upon a platinum wirewpassing through a glass stem and leading to the outside of the globe. The filamentfwas surrounded by a metal sieves. It was found in experiments with such bulbs that a sieve with wide meshes apparently did not in the slightest affect the bombardment against the globeb. When the vacuum was high, the shadow of the sieve was clearly projected against the globe and the latter would get hot in a short while. In some bulbs the sieveswas connected to a platinum wire sealed in the glass. When this wire was connected to the other terminal of the induction coil (thee. m. f.being kept low in this case), or to an insulated plate, the bombardment against the outer globebwas diminished. By taking a sieve with fine meshes the bombardment against the globebwas always diminished, but even then if the exhaustion was carried very far, and when the potential of the transformer was very high, the globebwould be bombarded and heated quickly, though no shadow of the sieve was visible, owing to the smallness of the meshes. But a glass tube or other continuous body mounted so as to surround the filament, did entirely cut off the bombardment and for a while the outer globebwould remain perfectly cold. Of course when the glass tube was sufficiently heated the bombardment against the outer globe could be noted at once. The experiments with these bulbs seemed to show that the speeds of the projected molecules or particles must be considerable (though quite insignificant when compared with that of light), otherwise it would be difficult to understand how they could traverse a fine metal sieve without being affected, unless it were found that such small particles or atoms cannot be acted upon directly at measurable distances. In regard to the speed of the projected atoms, Lord Kelvin has recently estimated it at about one kilometre a second or thereabouts in an ordinary Crookes bulb. As the potentials obtainable with a disruptive discharge coil are much higher than with ordinary coils, the speeds must, of course, be much greater when the bulbs are lighted from such a coil. Assuming the speed to be as high as five kilometres and uniform through the whole trajectory, as it should be in a very highly exhausted vessel, then if the alternate electrifications of the electrode would be of a frequency of five million, the greatest distance a particle could get away from the electrode would be one millimetre, and if it could be acted upon directly at that distance, the exchange of electrode matter or of the atoms would be very slow and there would be practically no bombardment against the bulb. This at least should be so, if the action of an electrode upon the atoms of the residual gas would be such as upon electrified bodies which we can perceive. A hot body enclosed in an exhausted bulb produces always atomic bombardment, but a hot body has no definite rhythm, for its molecules perform vibrations of all kinds.
If a bulb containing a button or filament be exhausted as high as is possible with the greatest care and by the use of the best artifices, it is often observed that the discharge cannot, at first, break through, but after some time, probably in consequence of some changes within the bulb, the discharge finally passes through and the button is rendered incandescent. In fact, it appears that the higher the degree of exhaustion the easier is the incandescence produced. There seem to be no other causes to which the incandescence might be attributed in such case except to the bombardment or similar action of the residual gas, or of particles of matter in general. But if the bulb be exhausted with the greatest care can these play an important part? Assume the vacuum in the bulb to be tolerably perfect, the great interest then centres in the question: Is the medium which pervades all space continuous or atomic? If atomic, then the heating of a conducting button or filament in an exhausted vessel might be due largely to ether bombardment, and then the heating of a conductor in general through which currents of high frequency or high potential are passed must be modified by the behavior of such medium; then also the skin effect, the apparent increase of the ohmic resistance, etc., admit, partially at least, of a different explanation.
It is certainly more in accordance with many phenomena observed with high-frequency currents to hold that all space is pervaded with free atoms, rather than to assume that it is devoid of these, and dark and cold, for so it must be, if filled with a continuous medium, since in such there can be neither heat nor light.Is then energy transmitted by independent carriers or by the vibration of a continuous medium? This important question is by no means as yet positively answered. But most of the effects which are here considered, especially the light effects, incandescence, or phosphorescence, involve the presence of free atoms and would be impossible without these.
In regard to the incandescence of a refractory button (or filament) in an exhausted receiver, which has been one of the subjects of this investigation, the chief experiences, which may serve as a guide in constructing such bulbs, may be summed up as follows: 1. The button should be as small as possible, spherical, of a smooth or polished surface, and of refractory material which withstands evaporation best. 2. The support of the button should be very thin and screened by an aluminum and mica sheet, as I have described on another occasion. 3. The exhaustion of the bulb should be as high as possible. 4. The frequency of the currents should be as high as practicable. 5. The currents should be of a harmonic rise and fall, without sudden interruptions. 6. The heat should be confined to the button by inclosing the same in a small bulb or otherwise. 7. The space between the walls of the small bulb and the outer globe should be highly exhausted.
Most of the considerations which apply to the incandescence of a solid just considered may likewise be applied to phosphorescence. Indeed, in an exhausted vessel the phosphorescence is, as a rule, primarily excited by the powerful beating of the electrode stream of atoms against the phosphorescent body. Even in many cases, where there is no evidence of such a bombardment, I think that phosphorescence is excited by violent impacts of atoms, which are not necessarily thrown off from the electrode but are acted upon from the same inductively through the medium or through chains of other atoms. That mechanical shocks play an important part in exciting phosphorescence in a bulb may be seen from the following experiment. If a bulb, constructed as that illustrated in Fig. 174, be taken and exhausted with the greatest care so that the discharge cannot pass, the filamentfacts by electrostatic induction upon the tubetand the latter is set in vibration. If the tubeobe rather wide, about an inch or so, the filament may be so powerfully vibrated that whenever it hits the glass tube it excites phosphorescence. But the phosphorescence ceases when the filament comes to rest. The vibration can be arrested and again started by varying thefrequency of the currents. Now the filament has its own period of vibration, and if the frequency of the currents is such that there is resonance, it is easily set vibrating, though the potential of the currents be small. I have often observed that the filament in the bulb is destroyed by such mechanical resonance. The filament vibrates as a rule so rapidly that it cannot be seen and the experimenter may at first be mystified. When such an experiment as the one described is carefully performed, the potential of the currents need be extremely small, and for this reason I infer that the phosphorescence is then due to the mechanical shock of the filament against the glass, just as it is produced by striking a loaf of sugar with a knife. The mechanical shock produced by the projected atoms is easily noted when a bulb containing a button is grasped in the hand and the current turned on suddenly. I believe that a bulb could be shattered by observing the conditions of resonance.
In the experiment before cited it is, of course, open to say, that the glass tube, upon coming in contact with the filament, retains a charge of a certain sign upon the point of contact. If now the filament again touches the glass at the same point while it is oppositely charged, the charges equalize under evolution of light. But nothing of importance would be gained by such an explanation. It is unquestionable that the initial charges given to the atoms or to the glass play some part in exciting phosphorescence. So, for instance, if a phosphorescent bulb be first excited by a high frequency coil by connecting it to one of the terminals of the latter and the degree of luminosity be noted, and then the bulb be highly charged from a Holtz machine by attaching it preferably to the positive terminal of the machine, it is found that when the bulb is again connected to the terminal of the high frequency coil, the phosphorescence is far more intense. On another occasion I have considered the possibility of some phosphorescent phenomena in bulbs being produced by the incandescence of an infinitesimal layer on the surface of the phosphorescent body. Certainly the impact of the atoms is powerful enough to produce intense incandescence by the collisions, since they bring quickly to a high temperature a body of considerable bulk. If any such effect exists, then the best appliance for producing phosphorescence in a bulb, which we know so far, is a disruptive discharge coil giving an enormous potential with but few fundamental discharges, say 25-30 per second, just enough to produce a continuous impression upon the eye. It is a fact that such a coil excites phosphorescence under almost any condition and at all degrees of exhaustion, and I have observed effects which appear to be due to phosphorescence even at ordinary pressures of the atmosphere, when the potentials are extremely high. But if phosphorescent light is produced by the equalization of charges of electrified atoms (whatever this may mean ultimately), then the higher the frequency of the impulses or alternate electrifications, the more economical will be the light production. It is a long known and noteworthy fact that all the phosphorescent bodies are poor conductors of electricity and heat, and that all bodies cease to emit phosphorescent light when they are brought to a certain temperature. Conductors on the contrary do not possess this quality. There are but few exceptions to the rule. Carbon is one of them. Becquerel noted that carbon phosphoresces at a certain elevated temperature preceding the dark red. This phenomenon may be easily observed in bulbs provided with a rather large carbon electrode (say, a sphere of six millimetres diameter). If the current is turned on after a few seconds, a snow white film covers the electrode, just before it gets dark red. Similar effects are noted with other conducting bodies, but many scientific men will probably not attribute them to true phosphorescence. Whether true incandescence has anything to do with phosphorescence excited by atomic impact or mechanical shocks still remains to be decided, but it is a fact that all conditions, which tend to localize and increase the heating effect at the point of impact, are almost invariably the most favorable for the production of phosphorescence. So, if the electrode be very small, which is equivalent to saying in general, that the electric density is great; if the potential be high, and if the gas be highly rarefied, all of which things imply high speed of the projected atoms, or matter, and consequently violent impacts—the phosphorescence is very intense. If a bulb provided with a large and small electrode be attached to the terminal of an induction coil, the small electrode excites phosphorescence while the large one may not do so, because of the smaller electric density and hence smaller speed of the atoms. A bulb provided with a large electrode may be grasped with the hand while the electrode is connected to the terminal of the coil and it may not phosphoresce; but if instead of grasping the bulb with the hand, the same be touched with a pointed wire, the phosphorescence at once spreadsthrough the bulb, because of the great density at the point of contact. With low frequencies it seems that gases of great atomic weight excite more intense phosphorescence than those of smaller weight, as for instance, hydrogen. With high frequencies the observations are not sufficiently reliable to draw a conclusion. Oxygen, as is well-known, produces exceptionally strong effects, which may be in part due to chemical action. A bulb with hydrogen residue seems to be most easily excited. Electrodes which are most easily deteriorated produce more intense phosphorescence in bulbs, but the condition is not permanent because of the impairment of the vacuum and the deposition of the electrode matter upon the phosphorescent surfaces. Some liquids, as oils, for instance, produce magnificent effects of phosphorescence (or fluorescence?), but they last only a few seconds. So if a bulb has a trace of oil on the walls and the current is turned on, the phosphorescence only persists for a few moments until the oil is carried away. Of all bodies so far tried, sulphide of zinc seems to be the most susceptible to phosphorescence. Some samples, obtained through the kindness of Prof. Henry in Paris, were employed in many of these bulbs. One of the defects of this sulphide is, that it loses its quality of emitting light when brought to a temperature which is by no means high. It can therefore, be used only for feeble intensities. An observation which might deserve notice is, that when violently bombarded from an aluminum electrode it assumes a black color, but singularly enough, it returns to the original condition when it cools down.
The most important fact arrived at in pursuing investigations in this direction is, that in all cases it is necessary, in order to excite phosphorescence with a minimum amount of energy, to observe certain conditions. Namely, there is always, no matter what the frequency of the currents, degree of exhaustion and character of the bodies in the bulb, a certain potential (assuming the bulb excited from one terminal) or potential difference (assuming the bulb to be excited with both terminals) which produces the most economical result. If the potential be increased, considerable energy may be wasted without producing any more light, and if it be diminished, then again the light production is not as economical. The exact condition under which the best result is obtained seems to depend on many things of a different nature, and it is to be yet investigated by other experimenters, but it will certainlyhave to be observed when such phosphorescent bulbs are operated, if the best results are to be obtained.
Coming now to the most interesting of these phenomena, the incandescence or phosphorescence of gases, at low pressures or at the ordinary pressure of the atmosphere, we must seek the explanation of these phenomena in the same primary causes, that is, in shocks or impacts of the atoms. Just as molecules or atoms beating upon a solid body excite phosphorescence in the same or render it incandescent, so when colliding among themselves they produce similar phenomena. But this is a very insufficient explanation and concerns only the crude mechanism. Light is produced by vibrations which go on at a rate almost inconceivable. If we compute, from the energy contained in the form of known radiations in a definite space the force which is necessary to set up such rapid vibrations, we find, that though the density of the ether be incomparably smaller than that of any body we know, even hydrogen, the force is something surpassing comprehension. What is this force, which in mechanical measure may amount to thousands of tons per square inch? It is electrostatic force in the light of modern views. It is impossible to conceive how a body of measurable dimensions could be charged to so high a potential that the force would be sufficient to produce these vibrations. Long before any such charge could be imparted to the body it would be shattered into atoms. The sun emits light and heat, and so does an ordinary flame or incandescent filament, but in neither of these can the force be accounted for if it be assumed that it is associated with the body as a whole. Only in one way may we account for it, namely, by identifying it with the atom. An atom is so small, that if it be charged by coming in contact with an electrified body and the charge be assumed to follow the same law as in the case of bodies of measurable dimensions, it must retain a quantity of electricity which is fully capable of accounting for these forces and tremendous rates of vibration. But the atom behaves singularly in this respect—it always takes the same "charge."
It is very likely that resonant vibration plays a most important part in all manifestations of energy in nature. Throughout space all matter is vibrating, and all rates of vibration are represented, from the lowest musical note to the highest pitch of the chemical rays, hence an atom, or complex of atoms, no matter what its period, must find a vibration with which it is in resonance.When we consider the enormous rapidity of the light vibrations, we realize the impossibility of producing such vibrations directly with any apparatus of measurable dimensions, and we are driven to the only possible means of attaining the object of setting up waves of light by electrical means and economically, that is, to affect the molecules or atoms of a gas, to cause them to collide and vibrate. We then must ask ourselves—How can free molecules or atoms be affected?