VII

Candle-powerper cubic foot ofgas per hourFish-tail flames, depending upon size0.6 to 2.5Argand, depending upon improvements2.9 to 3.5Regenerative7 to 10

It is seen that the possibilities of gas lighting were recognized in several countries, all of which contributed to its development. Some of the earlier accounts have been drawn chiefly from England, but these are intended merely to serve as examples of the difficulties encountered. Doubtless, similar controversies arose in other countries in which pioneers were also nursing gas-lighting to maturity. However, it is certain that much of the early progress of lighting of this character was fathered in England. Gas-lighting was destined to become a thriving industry, and is of such importance in lighting that another chapter is given its modern developments.

In previous chapters much of the historical development of artificial lighting has been presented and several subjects have been traced to the modern period which marks the beginning of an intensive attack by scientists upon the problems pertaining to the production of efficient and adequate light-sources. Many historical events remain to be touched upon in later chapters, but it is necessary at this point for the reader to become acquainted with certain general physical principles in order that he may read with greater interest some of the chapters which follow. It is seen that from a standpoint of artificial lighting, the "dark age" extended well into the nineteenth century. Oil-lamps and gas-lighting began to be seriously developed at the beginning of the last century, but the pioneers gave attention chiefly to mechanical details and somewhat to the chemistry of the fuels. It was not until the science of physics was applied to light-sources that rapid progress was made.

All the light-sources used throughout the ages, and nearly all modern ones, radiate light by virtue of the incandescence of solids or of solid particles and it is an interesting fact that carbon is generally the solid which emits light. This is due to various physical characteristics of carbon, the chief one being its extremely highmelting-point. However, most practicable light-sources of the past and present may be divided into two general classes: (1) Those in which solids or solid particles are heated by their own combustion, and (2) those in which the solids are heated by some other means. Some light-sources include both principles and some perhaps cannot be included under either principle without qualification. The luminous flames of burning material such as those of wood-splinters, candles, oil-lamps, and gas-jets, and the glowing embers of burning material appear in the first class; and incandescent gas-mantles, electric filaments, and arc-lamps to some extent are representative of the second class. Certain "flaming" arcs involve both principles, but the light of the firefly, phosphorescence, and incandescent gas in "vacuum" tubes cannot be included in this simplified classification. The status of these will become clear later.

It has been seen that flames have been prominent sources of artificial light; and although of low luminous efficiency, they still have much to commend them from the standpoints of portability, convenience, and subdivision. The materials which have been burned for light, whether solid or liquid, are rich in carbon, and the solid particles of carbon by virtue of their incandescence are responsible for the brightness of a flame. A jet of pure hydrogen gas will burn very hot but with so low a brightness as to be barely visible. If solid particles are injected into the flame, much more light usually will be emitted. A gas-burner of the Bunsen type, in which complete combustion is obtained by mixing air in proper proportions with the gas, gives a hotflame which is of a pale blue color. Upon the closing of the orifice through which air is admitted, the flame becomes bright and smoky. The flame is now less hot, as indicated by the presence of smoke or carbon particles, and combustion is not complete. However, it is brighter because the solid particles of carbon in passing upward through the flame become heated to temperatures at which they glow and each becomes a miniature source of light.

A close observer will notice that the flame from a match, a candle, or a gas-jet, is not uniformly bright. The reader may verify this by lighting a match and observing the flame. There is always a bluish or darker portion near the bottom. In this less luminous part the air is combining with the hydrogen of the hydrocarbon which is being vaporized and disintegrated. Even the flame of a candle or of a burning splinter is a miniature gas-plant, for the solid or liquid hydrocarbons are vaporized before being burned. Owing to the incoming colder air at this point, the flame is not hot enough for complete combustion. The unburned carbon particles rise in its draft and become heated to incandescence, thus accounting for the brighter portion. In cases of complete combustion they are eventually oxidized into carbon dioxide before they are able to escape. If a piece of metal be held in the flame, it immediately becomes covered with soot or carbon, because it has reduced the temperature below the point at which the chemical reaction—the uniting of carbon with oxygen—will continue. An ordinary flat gas-flame of the "bats-wing" type may vary in temperature in its central portion from 300°F. at the bottom to about 3000°F. at the top. The central portion lies between two hotter layers in which the vertical variation is not so great. The brightness of the upper portion is due to incandescent carbon formed in the lower part.

When scientists learned by exploring flames that brightness was due to the radiation of light by incandescent solid matter, the way was open for many experiments. In the early days of gas-lighting investigations were made to determine the relation of illuminating value to the chemical constitution of the gas. The results combined with a knowledge of the necessity for solid carbon in the flame led to improvements in the gas for lighting purposes. Gas rich in hydrocarbons which in turn are rich in carbon is high in illuminating value. Heating-effect depends upon heat-units, so the rating of gas in calories or other heat-units per cubic foot is wholly satisfactory only for gas used for heating. The chemical constitution is a better indicator of illuminating value.

As scientific knowledge increased, efforts were made to get solid matter into the flames of light-sources. Instead of confining efforts to the carbon content of the gas, solid materials were actually placed in the flame, and in this manner various incandescent burners were developed. A piece of lime placed in a hydrogen flame or that of a Bunsen burner is seen to become hot and to glow brilliantly. By producing a hotter flame by means of the blowpipe, in which hydrogen and oxygen are consumed, the piece of lime was raised to a higher temperature and a more intense light was obtained. In Paris there was a serious attempt at street-lightingby the use of buttons of zirconia heated in an oxygen-coal-gas flame, but it proved unsuccessful owing to the rapid deterioration of the buttons. This was the line of experimentation which led to the development of the lime-light. The incandescent burner was widely employed, and until the use of electricity became common the lime-light was the mainstay for the stage and for the projection of lantern slides. It is in use even to-day for some purposes. The origin of the phrase "in the lime-light" is obvious. The luminous intensity of the oxyhydrogen lime-light as used in practice was generally from 200 to 400 candle-power. The light decreases rapidly as the burner is used, if a new surface of lime is not presented to the flame from time to time. At the high temperatures the lime is somewhat volatile and the surface seems to change in radiating power. Zirconium oxide has been found to serve better than lime.

Improvements were made in gas-burners in order to obtain hotter flames into which solid matter could be introduced to obtain bright light. Many materials were used, but obviously they were limited to those of a fairly high melting-point. Lime, magnesia, zirconia, and similar oxides were used successfully. If the reader would care to try an experiment in verification of this simple principle, let him take a piece of magnesium ribbon such as is used in lighting for photography and ignite it in a Bunsen flame. If it is held carefully while burning, a ribbon of ash (magnesia) will be obtained intact. Placing this in the faintly luminous flame, he will be surprised at the brilliance of its incandescence when it has become heated. The simpleexperiment indicates the possibilities of light-production in this direction. Naturally, metals of high melting-point such as platinum were tried and a network of platinum wire, in reality a platinum mantle, came into practical use in about 1880. The town of Nantes was lighted by gas-burners using these platinum-gauze mantles, but the mantles were unsuccessful owing to their rapid deterioration. This line of experimentation finally bore fruit of immense value for from it the gas-mantle evolved.

A group of so-called "rare-earths," among which are zirconia, thoria, ceria, erbia, and yttria (these are oxides of zirconium, etc.) possess a number of interesting chemical properties some of which have been utilized to advantage in the development of modern artificial light. They are white or yellowish-white oxides of a highly refractory character found in certain rare minerals. Most of them are very brilliant when heated to a high temperature. This latter feature is easily explained if the nature of light and the radiating properties of substances are considered. Suppose pieces of different substances, for example, glass and lime, are heated in a Bunsen flame to the same temperature which is sufficiently great to cause both of them to glow. Notwithstanding the identical conditions of heating, the glass will be only faintly luminous, while the piece of lime will glow brilliantly. The former is a poor radiator; furthermore, the lime radiates a relatively greater percentage of its total energy in the form of luminous energy.

The latter point will become clearer if the reader will refresh his memory regarding the nature of light.Any luminous source such as the sun, a candle flame, or an incandescent lamp is sending forth electromagnetic waves not unlike those used in wireless telegraphy excepting that they are of much shorter wave-length. The eye is capable of recording some of these waves as light just as a receiving station is tuned to record a range of wave-lengths of electromagnetic energy. The electromagnetic waves sent forth by a light-source like the sun are not all visible, that is, all of them do not arouse a sensation of light. Those that do comprise the visible spectrum and the different wave-lengths of visible radiant energy manifest themselves by arousing the sensations of the various spectral colors. The radiant energy of shortest wave-length perceptible by the visual apparatus excites the sensation of violet and the longest ones the sensation of deep red. Between these two extremes of the visible spectrum, the chief spectral colors are blue, green, yellow, orange, and red in the order of increasing wave-lengths. Electromagnetic energy radiated by a light-source in waves of too great wave-length to be perceived by the eye as light is termed as a class "infra-red radiant energy." Those too short to be perceived as light are termed as a class "ultraviolet radiant energy." A solid body at a high temperature emits electro-magnetic energy of all wave-lengths, from the shortest ultra-violet to the longest infra-red.

Another complication arises in the variation in visibility or luminosity of energy of wave-lengths within the range of the visible spectrum. Obviously, no amount of energy incapable of exciting the sensation of light will be visible. The energy of those wave-lengthsnear the ends of the visible spectrum will be inefficient in producing light. That energy which excites the sensation of yellow-green produces the greatest luminosity per unit of energy and is the most efficient light. The visibility or luminous efficiency of radiant energy may be ranged approximately in this manner according to the colors aroused: yellow-green, yellow, green, orange, blue-green, red, blue, deep red, violet.

Newton, an English scientist, first described the discovery of the visible spectrum and this is of such fundamental importance in the science of light that the first paragraph of his original paper in the "Transactions of the Royal Society of London" is quoted as follows:

In the Year 1666 (at which time I applied my self to the Grinding of Optick Glasses of other Figures than Spherical) I procured me a Triangular Glass-Prism, to try therewith the celebrated Phaenomena of Colours. And in order thereto, having darkened my Chamber, and made a small Hole in my Window-Shuts, to let in a convenient Quantity of the Sun's Light, I placed my Prism at its Entrance, that it might be thereby refracted to the opposite Wall. It was at first a very pleasing Divertisement, to view the vivid and intense Colours produced thereby; but after a while applying my self to consider them more circumspectly, I became surprised to see them in an oblong Form; which, according to the receiv'd Law of Refractions, I expected should have been circular. They were terminated at the Sides with streight Lines, but at the Ends the Decay of Light was so gradual, that it was difficult to determine justly what was the Figure, yet they seemed Semicircular.

In the Year 1666 (at which time I applied my self to the Grinding of Optick Glasses of other Figures than Spherical) I procured me a Triangular Glass-Prism, to try therewith the celebrated Phaenomena of Colours. And in order thereto, having darkened my Chamber, and made a small Hole in my Window-Shuts, to let in a convenient Quantity of the Sun's Light, I placed my Prism at its Entrance, that it might be thereby refracted to the opposite Wall. It was at first a very pleasing Divertisement, to view the vivid and intense Colours produced thereby; but after a while applying my self to consider them more circumspectly, I became surprised to see them in an oblong Form; which, according to the receiv'd Law of Refractions, I expected should have been circular. They were terminated at the Sides with streight Lines, but at the Ends the Decay of Light was so gradual, that it was difficult to determine justly what was the Figure, yet they seemed Semicircular.

Even Newton could not have had the faintest idea ofthe great developments which were to be based upon the spectrum.

Now to return to the peculiar property of rare-earth oxides—namely, their unusual brilliance when heated in a flame—it is easy to understand the reason for this. For example, when a number of substances are heated to the same temperature they may radiate the same amount of energy and still differ considerably in brightness. Many substances are "selective" in their absorbing and radiating properties. One may radiate more luminous energy and less infra-red energy, and for another the reverse may be true. The former would appear brighter than the latter. The scientific worker in light-production has been searching for such "selective" radiators whose other properties are satisfactory. The rare-earths possess the property of selectivity and are fortunately highly refractory. Welsbach used these in his mantle, whose efficiency is due partly to this selective property. Recent work indicates that much higher efficiencies of light-production are still attainable by the principles involved in the gas-mantle.

Turning again to flames, another interesting physical phenomenon is seen on placing solutions of different chemical salts in the flame. For example, if a piece of asbestos is soaked in sodium chloride (common salt) and is placed in a Bunsen flame, the pale-blue flame suddenly becomes luminous and of a yellow color. If this is repeated with other salts, a characteristic color will be noted in each case. The yellow flame is characteristic of sodium and if it is examined by means of a spectroscope, a brilliant yellow line (in fact, a doubleline) will be seen. This forms the basis of spectrum analysis as applied in chemistry.

Every element has its characteristic spectrum consisting usually of lines, but the complexity varies with the elements. The spectra of elements also exhibit lines in the ultra-violet region which may be studied with a photographic plate, with a photo-electric cell, and by other means. Their spectral lines or bands also extend into the infra-red region and here they are studied by means of the bolometer or other apparatus for detecting radiant energy by the heat which it produces upon being absorbed. Spectrum analysis is far more sensitive than the finest weighing balance, for if a grain of salt be dissolved in a barrel of water and an asbestos strip be soaked in the water and held in a Bunsen flame, the yellow color characteristic of sodium will be detectable. A wonderful example of the possibilities of this method is the discovery of helium in the sun before it was found on earth! Its spectral lines were detected in the sun's spectrum and could not be accounted for by any known element. However, it should be stated that the spectrum of an element differs generally with the manner obtained. The electric spark, the arc, the electric discharge in a vacuum tube, and the flame are the means usually employed.

The spectrum has been dwelt upon at some length because it is of great importance in light-production and probably will figure strongly in future developments. Although in lighting little use has been made of the injection of chemical salts into ordinary flames, it appears certain that such developments would have risen if electric illuminants had not entered the field.However, the principle has been applied with great success in arc-lamps. In the first arc-lamps plain carbon electrodes were used, but in some of the latest carbon-arcs, electrodes of carbon impregnated with various salts are employed. For example, calcium fluoride gives a brilliant yellow light when used in the carbons of the "flame" arc. These are described in detail later.

Following this principle of light-production the vacuum tubes were developed. Crookes studied the light from various gases by enclosing them in a tube which was pumped out until a low vacuum was produced. On connecting a high voltage to electrodes in each end, an electrical discharge passed through the residual gas making it luminous. The different gases show their characteristic spectra and their desirability as light-producers is at once evident.

However, the most general principle of light-production at the present time is the radiation of bodies by virtue of their temperature. If a piece of wire be heated by electricity, it will become very hot before it becomes luminous. At this temperature it is emitting only invisible infra-red energy and has an efficiency of zero as a producer of light. As it becomes hotter it begins to appear red, but as its temperature is raised it appears orange, until if it could be heated to the temperature of the sun, about 10,000°F., it would appear white. All this time its luminous efficiency is increasing, because it is radiating not only an increasing percentage of visible radiant energy but an increasing amount of the most effective luminous energy. But even when it appears white, a large amount of theenergy which it radiates is invisible infra-red and ultra-violet, which are ineffective in producing light, so at best the substance at this high temperature is inefficient as a light-producer.

In this branch of the science of light-production substances are sought not only for their high melting-point, but for their ability to radiate selectively as much visible energy as possible and of the most luminous character. However, at best the present method of utilizing the temperature radiation of hot bodies has limitations.

The luminous efficiencies of light-sources to-day are still very low, but great advances have been made in the past half-century. There must be some radical departures if the efficiency of light-production is to reach a much higher figure. A good deal has been said of the firefly and of phosphorescence. These light-sources appear to emit only visible energy and, therefore, are efficient as radiators of luminous radiant energy. But much remains to be unearthed concerning them before they will be generally applicable to lighting. If ultra-violet radiation is allowed to impinge upon a phosphorescent material, it will glow with a considerable brightness but will be cool to the touch. A substance of the same brightness by virtue of its temperature would be hot; hence phosphorescence is said to be "cold" light.

An acquaintance with certain terms is necessary if the reader is to understand certain parts of the text. The early candle gradually became a standard, and uniform candles are still satisfactory standards where high accuracy is not required. Their luminous intensity and illuminating value became units just as the foot was arbitrarily adopted as a unit of length. The intensity of other light-sources was represented in terms of the number of candles or fraction of a candle which gave the same amount of light. But the luminous intensity of the candle was taken only in the horizontal direction. In the same manner the luminous intensities of light-sources until a short time ago were expressed in candles as measured in a certain direction. Incandescent lamps were rated in terms of mean horizontal candles, which would be satisfactory if the luminous intensity were the same in all directions, but it is not. Therefore, the candle-power in one direction does not give a measure of the total light-output.

If a source of light has a luminous intensity of one candle in all directions, the illumination at a distance of one foot in any direction is said to be a foot-candle. This is the unit of illumination intensity. A lumen is the quantity of light which falls on one square foot if the intensity of illumination is one foot-candle. It is seen that the area of a sphere with a radius of one foot is 4p or 12.57 square feet; therefore, a light-source having a luminous intensity of one candle in all directions emits 12.57 lumens. This is the satisfactory unit, for it measures total quantity of light, and luminous efficiencies may be expressed in terms of lumens per watt, lumens per cubic foot of gas per hour, etc.

Of course, the efficiencies of light-sources are usually of interest to the consumer if they are expressed in terms of cost. But from a practical point of view there are many elements which combine to makeanother important factor, namely, satisfactoriness. Therefore, the efficiency of artificial lighting from the standpoint of the consumer should be the ratio of satisfactoriness to cost. However, the scientist is interested chiefly in the efficiency of the light-source which may be expressed in lumens per watt, or the amount of light obtained from a given rate of consumption or of emission of energy. This method of rating light-sources penalizes those radiating considerable energy which does not produce the sensation of light or which at best is of wave-lengths that are inefficient in this respect. That radiant energy which is wholly of a wave-length of maximum visibility, or, in other words, excites the sensation of yellow-green, is the most efficient in producing luminous sensation. Of course, no illuminants are available which approach this theoretical ideal and it is not likely that this would be a practical ideal. Under monochromatic yellow-green light the magical drapery of color would disappear and the surroundings would be a monochrome of shades of this hue. Having no colors with which to contrast this color, the world would be colorless. This should be obvious when it is considered that an object which is red under an illuminant containing all colors such as sunlight would be black or dark gray under monochromatic yellow-green light. The red under present conditions is kept alive by contrast with other colors, because the latter live by virtue of the fact that most of our present illuminants contain their hues. It is assumed that the reader knows that a red object, for example, appears red because it reflects (or transmits)red rays and absorbs the other rays in the illuminant. In other words, color is due to selective absorption reflection, or transmission.

Perhaps the ideal illuminant, which is most generally satisfactory for general activities, is a white light corresponding to noon sunlight. If this is chosen as the scientific ideal, the illuminants of the present time are much more "efficient" than if the most efficient light is the ideal.

The luminous efficiency of the radiant energy most efficient in producing the sensation of light (yellow-green) is about 625 lumens per watt. That is, if energy of this wave-length alone were radiated by a hypothetical light-source, each watt would produce 625 lumens. The luminous efficiency of the most efficient white light is about 265 lumens per watt; in other words, if a hypothetical light-source radiated energy of only the visible wave-lengths and in proportions to produce the sensation of white, each watt would produce 265 lumens. If such a white light were obtained by pure temperature radiation—that is, by a normal radiator at a temperature of 10,000°F., which is impracticable at present—the luminous efficiency would be about 100 lumens per watt. The normal radiator which emits energy by virtue of its temperature without selectively radiating more or less energy in any part of the spectrum than indicated by the theoretical radiation laws is called a "black-body" or normal radiator. Modern illuminants have luminous efficiencies ranging from 5 to 30 lumens per watt, so it is seen that much is to be done before the limiting efficiencies are reached.

The amount of light obtained from various gas-burners for each cubic foot of gas consumed per hour varies for open gas-flames from 5 to 30 lumens; for Argand burners from 35 to 40 lumens; for regenerative lamps from 50 to 75 lumens; and for gas-mantles from 200 to 250 lumens.

In the development of light-sources, of course, any harmful effects of gases formed by burning or chemical action must be avoided. Some of the fumes from arcs are harmful, but no commercial arc appears to be dangerous when used as it is intended to be used. Gas-burners rob the atmosphere of oxygen and vitiate it with gases, which, however, are harmless if combustion is complete. That adequate ventilation is necessary where oxygen is being consumed is evident from the data presented by authorities on hygiene. A standard candle when burning vitiates the air in a room almost as much as an adult person. An ordinary kerosene lamp vitiates the atmosphere as much as a half-dozen persons. An ordinary single mantle burner causes as much vitiation as two or three persons.

In order to obtain a bird's-eye view of progress in light-production, the following table of relative luminous efficiencies of several light-sources is given in round numbers. These efficiencies are in terms of the most efficient (yellow-green) light.

Efficiencyin per cent.Sperm-candle0.02Open gas-flame.04Incandescent gas-mantle.19Carbon filament lamp.05Vacuum Mazda lamp1.3Gas-filled Mazda lamp2 to 3Arc-lamps2 to 7White light radiated by "black-body"16Most efficient white light40Firefly95Most efficient light (yellow-green)100

The luminous efficiency of a light-source is distinguished from that of a lamp. The former is the ratio of the light produced to the amount of energy radiated by the light-source. The latter is the ratio of the light produced to the total amount of energy consumed by the device. In other words, the luminous efficiency of a lamp is less than that of the light-source because the consumption of energy in other parts of the lamp besides the light-source are taken into account. These additional losses are appreciable in the mechanisms of arc-lamps but are almost negligible in vacuum incandescent filament lamps. They are unknown for the firefly, so that its luminous efficiency only as a light-source can be determined. Its efficiency as a lighting-plant may be and perhaps is rather low.

As has been seen, the lighting industry, as a public service, was born in London about a century ago and companies to serve the public were organized on the Continent shortly after. From this early beginning gas-light remained for a long time the only illuminant supplied by a public-service company. It has been seen that throughout the ages little advance was made in lighting until oil-lamps were improved by Argand in the eighteenth century. Candles and open-flame oil-lamps were in use when the Pyramids were built and these were common until the approach of the nineteenth century. In fact, several decades passed after the first gas-lighting was installed before this form of lighting began to displace the improved oil-lamps and candles. It was not until about 1850 that it began to invade the homes of the middle and poorer classes. During the first half of the nineteenth century the total light in an average home was less than is now obtained from a single light-source used in residences; still, the total cost of lighting a residence has decreased considerably. If the social and industrial activities of mankind are visualized for these various periods in parallel with the development of artificial lighting, a close relation is evident. Did artificial light advance merely hand in hand with science, invention, commerce, and industry, or did it illuminate the pathway?

Although gas-lighting was born in England it soon began to receive attention elsewhere. In 1815 the first attempt to provide a gas-works in America was made in Philadelphia; but progress was slow, with the result that Baltimore and New York led in the erection of gas-works. There are on record many protests against proposals which meant progress in lighting. These are amusing now, but they indicate the inertia of the people in such matters. When Bollman was projecting a plan for lighting Philadelphia by means of piped gas, a group of prominent citizens submitted a protest in 1833 which aimed to show that the consequences of the use of gas were appalling. But this protest failed and in 1835 a gas-plant was founded in Philadelphia. Thus gas-lighting, which to Sir Walter Scott was a "pestilential innovation" projected by a madman, weathered its early difficulties and grew to be a mighty industry. Continued improvements and increasing output not only altered the course of civilization by increased and adequate lighting but they reduced the cost of lighting over the span of the nineteenth century to a small fraction of its initial cost.

Think of the city of Philadelphia in 1800, with a population of about fifty thousand, dependent for its lighting wholly upon candles and oil-lamps! Washington's birthday anniversary was celebrated in 1817 with a grand ball attended by five hundred of the élite. An old report of the occasion states that the room was lighted by two thousand wax-candles. The cost of this lighting was a hundred times the cost of as much light for a similar occasion at the present time. Can one imagine the present complex activities of a city likePhiladelphia with nearly two million inhabitants to exist under the lighting conditions of a century ago? To-day there are more than fifty thousand street lamps in the city—one for each inhabitant of a century ago. Of these street lamps about twenty-five thousand burn gas. This single instance is representative of gas-lighting which initiated the "light age" and nursed it through the vicissitudes of youth. The consumption of gas has grown in the United States during this time to three billion cubic feet per day. For strictly illuminating purposes in 1910 nearly one hundred billion cubic feet were used. This country has been blessed with large supplies of natural gas; but as this fails new oil-fields are constantly being discovered, so that as far as raw materials are concerned the future of gas-lighting is assured for a long time to come.

The advent of the gas-mantle is responsible for the survival of gas-lighting, because when it appeared electric lamps had already been invented. These were destined to become the formidable light-sources of the approaching century and without the gas-mantle gas-lighting would not have prospered. Auer von Welsbach was conducting a spectroscopic study of the rare-earths when he was confronted with the problem of heating these substances. He immersed cotton in solutions of these salts as a variation of the regular means for studying elements by injecting them into flames. After burning the cotton he found that he had a replica of the original fabric composed of the oxide of the metal, and this glowed brilliantly when left in the flame.

This gave him the idea of producing a mantle forilluminating purposes and in 1885 he placed such a mantle in commercial use. His first mantles were unsatisfactory, but they were improved in 1886 by the use of thoria, an oxide of thorium, in conjunction with other rare-earth oxides. His mantle was now not only stronger but it gave more light. Later he greatly improved the mantles by purifying the oxides and finally achieved his great triumph by adding a slight amount of ceria, an oxide of cerium. Welsbach is deserving of a great deal of credit for his extensive work, which overcame many difficulties and finally gave to the world a durable mantle that greatly increased the amount of light previously obtainable from gas.

The physical characteristics of a mantle depend upon the fabric and upon the rare-earths used. It must not shrink unduly when burned, and the ash should remain porous. It has been found that a mantle in which thoria is used alone is a poor light-source, but that when a small amount of ceria is added the mantle glows brilliantly. By experiment it was determined that the best proportions for the rare-earth content are one part of ceria and ninety-nine parts of thoria. Greater or less proportions of ceria decreased the light-output. The actual percentage of these oxides in the ash of the mantle is about 10 per cent., making the content of ceria about one part in one thousand.

Mantles are made by knitting cylinders of cotton or of other fiber and soaking these in a solution of the nitrates of cerium and thorium. One end of the cylinder is then sewed together with asbestos thread, which also provides the loop for supporting the mantle over the burner. After the mantle has dried inproper form, it is burned; the organic matter disappears and the nitrates are converted into oxides. After this "burning off" has been accomplished and any residual blackening is removed, the mantle is dipped into collodion, which strengthens it for shipping and handling. The collodion is a solution of gun-cotton in alcohol and ether to which an oil such as castor-oil has been added to prevent excessive shrinkage on drying.

The materials and structure of the fabric of mantles have been subjected to much study. Cotton was first used; then ramie fibers were introduced. The ramie mantle was found to possess a greater life than the cotton mantle. Later the mantles were mercerized by immersion in ammonia-water and this process yielded a stronger material. The latest development is the use of an artificial silk as the base fabric, which results in a mantle superior to previous mantles in strength, flexibility, permanence of form, and permanence of luminous property. This artificial silk mantle will permit of handling even after it has been in use for several hundred hours. This great advance appears to be due to the fact that after the artificial-silk fibers have been burned off, the fibers are solid and continuous instead of porous as in previous mantles.

The color-value of the light from mantles may be varied considerably by altering the proportions of the rare-earths. The yellowness of the light has been traced to ceria, so by varying the proportions of ceria, the color of the light may be influenced.

The inverted mantle introduced greater possibilitiesinto gas-lighting. The light could be directed downward with ease and many units such as inverted bowls were developed. In fact, the lighting-fixtures and the lighting-effects obtainable kept pace with those of electric lighting, notwithstanding the greater difficulties encountered by the designer of gas-lighting fixtures. Many problems were encountered in designing an inverted burner operating on the Bunsen principle, but they were finally satisfactorily solved. In recent years a great deal of study has been given to the efficiency of gas-burners, with the result that a high level of development has been reached.

Several methods of electrical ignition have been evolved which in general employ the electric spark. Electrical ignition and developments of remote control have added great improvements especially to street-lighting by means of gas. Gas-valves for remote control are actuated by gas pressure and by electromagnets. In general, the gas-lighting engineers have kept pace marvelously with electric lighting, when their handicaps are considered.

Various types of burners have appeared which aimed to burn more gas in a given time under a mantle and thereby to increase the output of light. These led to the development of the pressure system in which the pressure of gas was at first several times greater than usual. The gas is fed into the mixing tube under this higher pressure in a manner which also draws in an adequate amount of air. In this way the combustion at the burner is forced beyond the point reached with the usual pressure. Ordinary gas pressure is equal to that of a few inches of water, but high-pressure systems employ pressures as great as sixty inches of water. Under this high-pressure system, mantle-burners yield as high as 500 lumens per cubic foot of gas per hour.

The fuels for gas-lighting are natural gas, carbureted water-gas, and coal-gas obtained by distilling coal, but there are different methods of producing the artificial gases. Coal-gas is produced analytically by distilling certain kinds of coal, but water-gas and producer-gas are made synthetically by the action of several constituents upon one another. Carbureted water-gas is made from fixed carbon, steam, and oil and also from steam and oil. Producer-gas is made by the action of steam or air or both upon fixed carbon. Water-gas made from steam and oil is usually limited to those places where the raw materials are readily available. The composition of a gas determines its heating and illuminating values, and constituents favorable to one are not necessarily favorable to the other. Coal-gas usually is of lower illuminating value than carbureted water-gas. It contains more hydrogen, for example, than water-gas and it is well known that hydrogen gives little light on burning.

It has been seen in a previous chapter that the distillation of gas from coal for illuminating purposes began in the latter part of the eighteenth century. From this beginning the manufacture of coal-gas has been developed to a great and complex industry. The method is essentially destructive distillation. The coal is placed in a retort and when it reaches a temperature of about 700°F. through heating by an outside fire, the coal begins to fuse and hydrocarbon vapors begin toemanate. These are generally paraffins and olefins. As the temperature increases, these hydrocarbons begin to be affected. The chemical combinations which have long existed are broken up and there are rearrangements of the atoms of carbon and hydrogen. The actual chemical reactions become very complex and are somewhat shrouded in uncertainty. In this last stage the illuminating and heating values of the gas are determined. Usually about four hours are allowed for the complete distillation of the gaseous and liquid products from a charge of coal. Many interesting chemical problems arise in this process and the influences of temperature and time cannot be discussed within the scope of this book. Besides the coal-gas, various by-products are obtained depending upon the raw materials, upon the procedure, and upon the market.

After the coal-gas is produced it must be purified and the sulphureted hydrogen at least must be removed. One method of accomplishing this is by washing the gas with water and ammonia, which also removes some of the carbon dioxide and hydrocyanic acid. Various other undesirable constituents are removed by chemical means, depending upon the conditions. The purified gas is now delivered to the gas-holder; but, of course, all this time the pressure is governed, in order that the pressure in the mains will be maintained constant.

Much attention has been given to the enrichment of gas for illuminating purposes; that is, to produce a gas of high illuminating value from cheap fuel or by inexpensive processes. This has been done by decomposing the tar obtained during the distillation of coaland adding these gases to the coal-gas; by mixing carbureted water-gas with coal-gas; by carbureting inferior coal-gases; and by mixing oil-gas with inferior coal-gas.

Water-gas is of low illuminating value, but after it is carbureted it burns with a brilliant flame. The water-gas is made by raising the temperature of the fuel bed of hard coal or coke by forced air, which is then cut off, while steam is passed through the incandescent fuel. This yields hydrogen and carbon monoxide. To make carbureted water-gas, oil-gas is mixed with it, the latter being made by heating oil in retorts.

A great many kinds of gas are made which are determined by the requirements and the raw materials available. The amount of illuminating gas yielded by a ton of fuel, of course, varies with the method of manufacture, with the raw material, and with the use to which the fuel is to be put. The production of coal-gas per ton of coal is of the order of magnitude of 10,000 cubic feet. A typical yield by weight of a coal-gas retort is,

10,000 cubic feet of gas17percent.coke70""tar5""ammoniacal liquid8""

The coke is not pure carbon but contains the non-volatile minerals which will remain as ash when the coke is burned, just as if the original coal had been burned. On the crown of the retort used in coal-gas production, pure carbon is deposited. This is used for electric-arc carbons and for other purposes. Fromthe tar many products are derived such as aniline dyes, benzene, carbolic acid, picric acid, napthalene, pitch, anthracene, and saccharin.

A typical analysis of the gas distilled from coal is very approximately as follows,

Hydrocarbons40percent.Hydrogen50""Carbon monoxide4""Nitrogen4""Carbon dioxide1""Various other gases1""

It is seen that illuminating gas is not a definite compound but a mixture of a number of gases. The proportion of these is controlled in so far as possible in order to obtain illuminating value and some of them are reduced to very small percentages because they are valueless as illuminants or even harmful. The constituents are seen to consist of light-giving hydrocarbons, of gases which yield chiefly heat, and of impurities. The chief hydrocarbons found in illuminating gas are,

ethyleneC2H4crotonyleneC4H6propyleneC3H6benzeneC6H6butyleneC4H8tolueneC7H8amyleneC5H10xyleneC8H10acetyleneC2H2methaneC H4allyleneC3H4ethaneC2H6

A gas which has played a prominent part in lighting is acetylene, produced by the interaction of water and calcium carbide. No other gas easily produced upon a commercial scale yields as much light, volume for volume, as acetylene. It has the great advantage of being easily prepared from raw material whose yield of gas is considerably greater for a given amount than the raw materials which are used in making other illuminating gases. The simplicity of the manufacture of acetylene from calcium carbide and water gives to this gas a great advantage in some cases. It has served for individual lighting in houses and in other places where gas or electric service was unavailable. Where space is limited it also had an advantage and was adopted to some extent on automobiles, motor-boats, ships, lighthouses, and railway cars before electric lighting was developed for these purposes.

The color of the acetylene flame is satisfactory and it is extremely brilliant compared with most flames. An interesting experiment is found in placing a spark-gap in the flame and sending a series of sparks across it. If the conditions are proper the flame will became very much brighter. When the gas issues from a proper jet under sufficient pressure, the flame is quite steady. Its luminous efficiency gives it an advantage over other open gas-flames in lighting rooms, because for the same amount of light it vitiates the air and exhausts the oxygen to a less degree than the others. Of course, in these respects the gas-mantle is superior.

The reaction which takes place when water and calcium carbide are brought together is a double decomposition and is represented by,

CaC2+ H2O = C2H2+ CaO

CaC2+ H2O = C2H2+ CaO

It will be seen that the products are acetylene gas and calcium oxide or lime. The lime, being hydroscopicand being in the presence of water or water-vapor in the acetylene generator, really becomes calcium hydroxide Ca(OH)2, commonly called slaked lime. If there are impurities in the calcium carbide, it is sometimes necessary to purify the gas before it may be safely used for interior lighting.

The burners and mantles used in acetylene lighting are essentially the same as those for other gas-lighting, excepting, of course, that they are especially adapted for it in minor details.

The chief source of calcium carbide in this country is the electric furnace. Cheap electrical energy from hydro-electric developments, such as the Niagara plants, have done much to make the earth yield its elements. Aluminum is very prevalent in the soil of the earth's surface, because its oxide, alumina, is a chief constituent of ordinary clay. But the elements, aluminum and oxygen, cling tenaciously to each other and only the electric furnace with its excessively high temperatures has been able to separate them on a large commercial scale. Similarly, calcium is found in various compounds over the earth's surface. Limestone abounds widely, hence the oxide and carbonate of lime are wide-spread. But calcium clings tightly to the other elements of its compounds and it has taken the electric furnace to bring it to submission. The cheapness of calcium carbide is due to the development of cheap electric power. It is said that calcium carbide was discovered as a by-product of the electric furnace by accidentally throwing water upon the waste materials of a furnace process. The discovery of a commercial scale of manufacture of calcium carbide hasbeen a boon to isolated lighting. Electric lighting has usurped its place on the automobile and is making inroads in country-home lighting. Doubtless, acetylene will continue to serve for many years, but its future does not appear as bright as it did many years ago.

The Pintsch gas, used to some extent in railroad passenger-cars in this country, is an oil-gas produced by the destructive distillation of petroleum or other mineral oil in retorts heated externally. The product consists chiefly of methane and heavy hydrocarbons with a small amount of hydrogen. In the early days of railways, some trains were not run after dark and those which were operated were not always lighted. At first attempts were made at lighting railway cars with compressed coal-gas, but the disadvantage of this was the large tank required. Obviously, a gas of higher illuminating-value per volume was desired where limited storage space was available, and Pintsch turned his attention to oil-gas. Gas suffers in illuminating-value upon being compressed, but oil-gas suffers only about half the loss that coal-gas does. In about 1880 Pintsch developed a method of welding cylinders and buoys which satisfied lighthouse authorities and he was enabled to furnish these filled with compressed gas. Thus the buoy was its own gas-tank. He devised lanterns which would remain lighted regardless of wind and waves and thus gained a start with his compressed-gas systems. He compressed the gas to a pressure of about one hundred and fifty pounds per square inch and was obliged to devise a reducer which would deliver the gas to the burner at about one pound per square inch. This regulatorserved well throughout many years of exacting service. The system began to be adopted on ships and railroads in 1880 and for many years it has served well.

Although gas-lighting has affected the activities of mankind considerably by intensifying commerce and industry and by advancing social progress, the illuminants which eventually took the lead have extended the possibilities and influences of artificial light. In the brief span of a century civilized man is almost totally independent of natural light in those fields over which he has control. What another century will bring can be predicted only from the accomplishments of the past. These indicate possibilities beyond the powers of imagination.

Early in 1800 Volta wrote a letter to the President of the Royal Society of London announcing the epochal discovery of a device now known as the voltaic pile. This letter was published in the Transactions and it created great excitement among scientific men, who immediately began active investigations of certain electrical phenomena. Volta showed that all metals could be arranged in a series so that each one would indicate a positive electric potential when in contact with any metal following it in the series. He constructed a pile of metal disks consisting of zinc and copper alternated and separated by wet cloths. At first he believed that mere contact was sufficient, but when, later, it was shown that chemical action took place, rapid progress was made in the construction of voltaic cells. The next step after his pile was constructed was to place pairs of strips of copper and zinc in cups containing water or dilute acid. Volta received many honors for his discovery, which contributed so much to the development of electrical science and art—among them a call to Paris by Bonaparte to exhibit his electrical experiments, and to receive a medal struck in his honor.

While Volta was being showered with honors, various scientific men with great enthusiasm were entering newfields of research, among which was the heating value of electric current and particularly of electric sparks made by breaking a circuit. Late in 1800 Sir Humphrey Davy was the first to use charcoal for the sparking points. In a lecture before the Royal Society in the following year he described and demonstrated that the "spark" passing between two pieces of charcoal was larger and more brilliant than between brass spheres. Apparently, he was producing a feeble arc, rather than a pure spark. In the years which immediately followed many scientific men in England, France, and Germany were publishing the results of their studies of electrical phenomena bordering upon the arc.

By subscription among the members of the Royal Society, a voltaic battery of two thousand cells was obtained and in 1808 Davy exhibited the electric arc on a large scale. It is difficult to judge from the reports of these early investigations who was the first to recognize the difference between the spark and the arc. Certainly the descriptions indicate that the simple spark was not being experimented with, but the source of electric current available at that time was of such high resistance that only feeble arcs could have been produced. In 1809 Davy demonstrated publicly an arc obtained by a current from a Volta pile of one thousand plates. This he described as "a most brilliant flame, of from half an inch to one and a quarter inches in length."

In the library of the Royal Society, Davy's notes made during the years of 1805 and 1812 are available in two large volumes. These were arranged and pagedby Faraday, who was destined to contribute greatly to the future development of the science and art of electricity. In one of these volumes is found an account of a lecture-experiment by Davy which certainly is a description of the electric arc. An extract of this account is as follows:

The spark [presumably the arc], the light of which was so intense as to resemble that of the sun, ... produced a discharge through heated air nearly three inches in length, and of a dazzling splendor. Several bodies which had not been fused before were fused by this flame.... Charcoal was made to evaporate, and plumbago appeared to fuse in vacuo. Charcoal was ignited to intense whiteness by it in oxymuriatic acid, and volatilized by it, but without being decomposed.

The spark [presumably the arc], the light of which was so intense as to resemble that of the sun, ... produced a discharge through heated air nearly three inches in length, and of a dazzling splendor. Several bodies which had not been fused before were fused by this flame.... Charcoal was made to evaporate, and plumbago appeared to fuse in vacuo. Charcoal was ignited to intense whiteness by it in oxymuriatic acid, and volatilized by it, but without being decomposed.

From a consideration of his source of electricity, a voltaic pile of two thousand plates, it is certain that this could not have been an electric spark. Later in his notes Davy continued:

...the charcoal became ignited to whitness, and by withdrawing the points from each other, a constant discharge took place through the heated air, in a space at least equal to four inches, producing a most brilliant ascending arch of light, broad and conical in form in the middle.

...the charcoal became ignited to whitness, and by withdrawing the points from each other, a constant discharge took place through the heated air, in a space at least equal to four inches, producing a most brilliant ascending arch of light, broad and conical in form in the middle.

This is surely a description of the electric arc. Apparently the electrodes were in a horizontal position and the arc therefore was horizontal. Owing to the rise of the heated air, the arc tended to rise in the form of an arch. From this appearance the term "arc" evolved and Davy himself in 1820 definitely named theelectric flame, the "arc." This name was continued in use even after the two carbons were arranged in a vertical co-axial position and the arc no more "arched." An interesting scientific event of 1820 was the discovery by Arago and by Davy independently that the arc could be deflected by a magnet and that it was similar to a wire carrying current in that there was a magnetic field around it. This has been taken advantage of in certain modern arc-lamps in which inclined carbons are used. In these arcs a magnet keeps the arc in place, for without the magnet the arc would tend to climb up the carbons and go out.

In 1838 Gassiot made the discovery that the temperature of the positive electrode of an electric arc is much greater than that of the negative electrode. This is explained in electronic theory by the bombardment of the positive electrode by negative electrons or corpuscles of electricity. This temperature-difference was later taken into account in designing direct-current arc-lamps, for inasmuch as most of the light from an ordinary arc is emitted by the end of the positive electrode, this was placed above the negative electrode. In this manner most of the light from the arc is directed downward where desired. In the few instances in modern times where the ordinary direct-current arc has been used for indirect lighting, in which case the arc is above an inverted shade, the positive carbon is placed below the negative one. Gassiot first proved that the positive electrode is hotter than the negative one by striking an arc between the ends of two horizontal wires of the same substance and diameter. After the arc operated for some time, the positive wirewas melted for such a distance that it bent downward, but the negative remained quite straight.

Charcoal was used for the electrodes in all the early experiments, but owing to the intense heat of the arc, it burned away rapidly. A progressive step was made in 1843 when electrodes were first made by Foucault from the carbon deposited in retorts in which coal was distilled in the production of coal-gas. However, charcoal, owing to its soft porous character, gives a longer arc and a larger flame. In 1877 the "cored" carbons were introduced. These consist of hard molded carbon rods in which there is a core of soft carbon. In these are combined the advantages of charcoal and hard carbon and the core in burning away more rapidly has a tendency to hold the arc in the center. Modern carbons for ordinary arc-lamps are generally made of a mixture of retort-carbon, soot, and coal-tar. This paste is forced through dies and the carbons are baked at a fairly high temperature. A variation in the hardness of the carbons may be obtained as the requirements demand by varying the proportions of soot and retort-carbon. Cored carbons are made by inserting a small rod in the center of the die and the carbons are formed with a hollow core. This may be filled with a softer carbon.

If two carbons connected to a source of electric current are brought together, the circuit is completed and a current flows. If the two carbons are now slightly separated, an arc will be formed. As the arc burns the carbons waste away and in the case of direct current, the positive decreases in length more rapidly than the negative one. This is due largely to the extremelyhigh temperature of the positive tip, where the carbon fairly boils. A crater is formed at the positive tip and this is always characteristic of the positive carbon of the ordinary arc, although it becomes more shallow as the arc-length is increased. The negative tip has a bright spot to which one end of the arc is attached. By wasting away, the length of the arc increases and likewise its resistance, until finally insufficient current will pass to maintain the arc. It then goes out and to start it the carbons must be brought together and separated. The mechanisms of modern arc-lamps perform these functions automatically by the ingenious use of electromagnets.

The interior of the arc is of a violet color and the exterior is a greenish yellow. The white-hot spot on the negative tip is generally surrounded by a fringe of agitated globules which consist of tar and other ingredients of carbons. Often material is deposited from the positive crater upon the negative tip and these accretions may build up a rounded tip. This deposit sometimes interferes with the proper formation of the arc and also with the light from the arc. It is often responsible for the hissing noise, although this hissing occurs with any length of arc when the current is sufficiently increased. The hissing seems to be due to the crater enlarging under excessive current until it passes the confines of the cross-section of the carbon. It thus tends to run up the side, where it comes in contact with oxygen of the air. In this manner the carbon is directly burned instead of being vaporized, as it is when the hot crater is small and is protected from the air by the arc itself. The temperature of the positive crateris in the neighborhood of 6000° to 7000°F. The brightness of the arc under pressure is the greatest produced by artificial means and is very intense. By putting the arc under high pressure, the brightness of the sun may be attained. The temperature of the hottest spot on the negative tip is about a thousand degrees below that of the positive.

No great demand arose for arc-lamps until the development of the Gramme dynamo in 1870, which provided a practicable source of electric current. In 1876 Jablochkov invented his famous "electric candle" consisting of two rods of carbon placed side by side but separated by insulating material. In this country Brush was the pioneer in the development of open arc-lamps. In 1877 he invented an arc-lamp and an efficient form of dynamo to supply the electrical energy. The first arc-lamps were ordinary direct-current open arcs and the carbons were made from high-grade coke, lampblack, and syrup. The upper positive carbon in these lamps is consumed at a rate of one to two inches per hour. Inasmuch as about 85 per cent. of the total light is emitted by the upper (positive) carbon and most of this from the crater, the lower carbon is made as small as possible in order not to obstruct any more light than necessary. The positive carbon of the open arc is often cored and the negative is a smaller one of solid carbon. This combination operates quite satisfactorily, but sometimes solid carbons are used outdoors. The voltage across the arc is about 50 volts.

In 1846 Staite discovered that the carbons of an arc enclosed in a glass vessel into which the air was not freely admitted were consumed less rapidly than whenthe arc operated in the open air. After the appearance of the dynamo, when increased attention was given to the development of arc-lamps, this principle of enclosing the arcs was again considered. The early attempts in about 1880 were unsuccessful because low voltages were used and it was not until the discovery was made that the negative tip builds up considerably for voltages under 65 volts, that higher voltages were employed. In 1893 marked improvements were consummated and Jandus brought out a successful enclosed arc operating at 80 volts. Marks contributed largely to the success of the enclosed arc by showing that a small current and a high voltage of 80 to 85 volts were the requisites for a satisfactory enclosed arc.

The principle of the enclosed arc is simple. A closely fitting glass globe surrounds the arc, the fit being as close as the feeding of the carbons will permit. When the arc is struck the oxygen is rapidly consumed and the heated gases and the enclosure check the supply of fresh air. The result is that the carbons are consumed about one tenth as rapidly as in the open arc. There is no crater formed on the positive tip and the arc wanders considerably. The efficiency of the enclosed arc as a light-producer is lower than that of the open arc, but it found favor because of its slow rate of consumption of the carbons and consequent decreased attention necessary. This arc operates a hundred hours or more without trimming, and will therefore operate a week or more in street-lighting without attention. When it is considered that open arcs for all-night burning were supplied with two pairs of carbons, the second set going into use automatically when the first were consumed, the value of the enclosed arc is apparent. However, the open arc has served well and has given way to greater improvements. It is rapidly disappearing from use.

The alternating-current arc-lamp was developed after the appearance of the direct-current open-arc and has been widely used. It has no positive or negative carbons, for the alternating current is reversing in direction usually at the rate of 120 times per second; that is, it passes through 60 complete cycles during each second. No marked craters form on the tips and the two carbons are consumed at about the same rate. The average temperature of the carbon tips is lower than that of the positive tip of a direct-current arc, with the result that the luminous efficiency is lower. These arcs have been made of both the open and enclosed type. They are characterized by a humming noise due to the effect of alternating current upon the mechanism and also upon the air near the arc. This humming sound is quite different from the occasional hissing of a direct-current arc. When soft carbons are used, the arc is larger and apparently this mass of vapor reduces the humming considerably. The humming is not very apparent for the enclosed alternating-current arc. The alternating arc can easily be detected by closely observing moving objects. If a pencil or coin be moved rapidly, a number of images appear which are due to the pulsating character of the light. At each reversal of the current, the currentreaches zero value and the arc is virtually extinguished. Therefore, there is a maximum brightness midway between the reversals.

Various types of all these arcs have been developed to meet the different requirements of ordinary lighting and to adapt this method of light-production to the needs of projection, stage-equipment, lighthouses, search-lights, and other applications.

Up to this point the ordinary carbon arc has been considered and it has been seen that most of the light is emitted by the glowing end of the positive carbon. In fact, the light from the arc itself is negligible. A logical step in the development of the arc-lamp was to introduce salts in order to obtain a luminous flame. This possibility as applied to ordinary gas-flames had been known for years and it is surprising that it had not been early applied to carbons. Apparently Bremer in 1898 was the first to introduce fluorides of calcium, barium, and strontium. The salts deflagrate and a luminous flame envelops the ordinary feeble arc-flame. From these arcs most of the light is emitted by the arc itself, hence the name "flame-arcs."

By the introduction of metallic salts into the carbons the possibilities of the arc-lamp were greatly extended. The luminous output of such lamps is much greater than that of an ordinary carbon arc using the same amount of electrical energy. Furthermore, the color or spectral character of the light may be varied through a wide range by the use of various salts. For example, if carbons are impregnated with calcium fluoride, the arc-flame when examined by means of a spectroscope will be seen to contain the characteristicspectrum of calcium, namely, some green, orange, and red rays. These combine to give to this arc a very yellow color. As explained in a previous chapter, the salts for this purpose may be wisely chosen from a knowledge of their fundamental or characteristic flame-spectra.

These lamps have been developed to meet a variety of needs and their luminous efficiencies range from 20 to 40 lumens per watt, being several times that of the ordinary carbon open-arc. The red flame-arc owes its color chiefly to strontium, whose characteristic visible spectrum consists chiefly of red and yellow rays. Barium gives to the arc a fairly white color. The yellow and so-called white flame-arcs have been most commonly used. Flame-arcs have been produced which are close to daylight in color, and powerful blue-white flame-arcs have satisfied the needs of various chemical industries and photographic processes. These arcs are generally operated in a space where the air-supply is restricted similar to the enclosed-arc principle. Inasmuch as poisonous fumes are emitted in large quantities from some flame-arcs, they are not used indoors without rather generous ventilation. In fact, the flame-arcs are such powerful light-sources that they are almost entirely used outdoors or in very large interiors especially of the type of open factory buildings. They are made for both direct and alternating current and the mechanisms have been of several types. The electrodes are consumed rather rapidly so they are made as long as possible. In one type of arc, the carbons are both fed downward, their lower ends forming a narrow V with the arc-flame between their tips.Under these conditions the arc tends to travel vertically and finally to "stretch" itself to extinction. However, the arc is kept in place by means of a magnet above it which repels the arc and holds it at the ends of the carbons.

The chief objection to the early flame-arcs was the necessity for frequent renewal of the carbons. This was overcome to a large extent in the Jandus regenerative lamp in which the arc operates in a glass enclosure surrounded by an opal globe. However, in addition to the inner glass enclosure, two cooling chambers of metal are attached to it. Air enters at the bottom and the fumes from the arc pass upward and into the cooling chambers, where the solid products are deposited. The air on returning to the bottom is thus relieved of these solids and the inner glass enclosure remains fairly clean. The lower carbon is impregnated with salts for producing the luminous flame and the upper carbon is cored. The life of the electrodes is about seventy-five hours.

The next step was the introduction of the so-called "luminous-arc" which is a "flame-arc" with entirely different electrodes. The lower (negative) electrode consists of an iron tube packed chiefly with magnetite (an iron oxide) and titanium oxide in the approximate proportions of three to one respectively. The magnetite is a conductor of electricity which is easily vaporized. The arc-flame is large and the titanium gives it a high brilliancy. The positive electrode, usually the upper one, is a short, thick, solid cylinder of copper, which is consumed very slowly. This lamp, knownas the magnetite-arc, has a luminous efficiency of about 20 lumens per watt with a clear glass globe.

The mechanisms which strike the arc and feed the carbons are ingenious devices of many designs depending upon the kind of arc and upon the character of the electric circuit to which it is connected. Late developments in electric incandescent filament lamps have usurped some of the fields in which the arc-lamp reigned supreme for years and its future does not appear as bright now as it did ten years ago. High-intensity arcs have been devised with small carbons for special purposes and considered as a whole a great amount of ingenuity has been expended in the development of arc-lamps. There will be a continued demand for arc-lamps, for scientific developments are opening new fields for them. Their value in photo-engraving, in the moving-picture production studios, in moving-picture projection, and in certain aspects of stage-lighting is firmly established, and it appears that they will find application in certain chemical industries because the arc is a powerful source of radiant energy which is very active in its effects upon chemical reactions.

The luminous efficiencies of arc-lamps depend upon so many conditions that it is difficult to present a concise comparison; however, the following may suffice to show the ranges of luminous output per watt under actual conditions of usage. These efficiencies, of course, are less than the efficiencies of the arc alone, because the losses in the mechanism, globes, etc., are included.


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