S
ince the Sixth Book has described the iron tools, the vessels and the machines used in mines, this Book will describe the methods of assaying[1]ores; because it is desirable to first test them in order that the material mined may be advantageously smelted, or that the dross may be purged away and the metal made pure. Although writers have mentioned such tests, yet none of them have set down the directions for performing them, wherefore it is no wonder that those who come later have written nothing on the subject. By tests of this kind miners can determine with certainty whether ores contain any metal in them or not; or if it has already been indicated that the ore contains one or more metals, the tests show whether it is much or little; the miners also ascertain by such tests the method by which the metal can be separated from that part of the ore devoid of it; and further, by these tests, they determine that part in which there is much metal from that part in which there is little. Unless these tests have been carefully applied before the metals are melted out, the ore cannot be smelted without great loss to the owners, for the parts which do not easily melt in the fire carry the metals off with them or consume them. In the last case, they pass off with the fumes; in the other case they are mixed with the slag and furnace accretions, and in such event the owners lose the labour which they have spent in preparing the furnaces and the crucibles, and further, it is necessary for them to incur fresh expenditure for fluxes and other things. Metals, when they have been melted out, are usually assayed in order that we may ascertain what proportion of silver is in acentumpondiumof copper or lead, or what quantity of gold is in onelibraof silver; and, on the other hand, what proportion of copper or lead is contained in acentumpondiumof silver, or what quantity of silver is contained in onelibraof gold. And from this we can calculate whether it will be worth while to separate the precious metals from the base metals, or not. Further, a test of this kind shows whether coins are good or are debased; and readily detects silver, if the coiners have mixed more than is lawful with the gold; or copper, if the coiners have alloyed with the gold or silver more of it than is allowable. I will explain all these methods with the utmost care that I can.
The method of assaying ore used by mining people, differs from smelting only by the small amount of material used. Inasmuch as, by smelting a small quantity, they learn whether the smelting of a largequantity will compensate them for their expenditure; hence, if they are not particular to employ assays, they may, as I have already said, sometimes smelt the metal from the ore with a loss or sometimes without any profit; for theycan assay the ore at a very small expense, and smelt it only at a great expense. Both processes, however, are carried out in the same way, for just as we assay ore in a little furnace, so do we smelt it in the large furnace. Also in both cases charcoal and not wood is burned. Moreover, in the crucible when metals are tested, be they gold, silver, copper, or lead, they are mixed in precisely the same way as they are mixed in the blast furnace when they are smelted. Further, those who assay ores with fire, either pour out the metal in a liquid state, or, when it has cooled, break the crucible and cleanthe metal from slag; and in the same way the smelter, as soon as the metal flows from the furnace into the forehearth, pours in cold water and takes the slag from the metal with a hooked bar. Finally, in the same way that gold and silver are separated from lead in a cupel, so also are they separated in the cupellation furnace.
It is necessary that the assayer who is testing ore or metals should be prepared and instructed in all things necessary in assaying, and that he should close the doors of the room in which the assay furnace stands, lestanyone coming at an inopportune moment might disturb his thoughts when they are intent on the work. It is also necessary for him to place his balances in a case, so that when he weighs the little buttons of metal the scales may not be agitated by a draught of air, for that is a hindrance to his work.
Muffle FurnaceRound assay furnace.[Pg 223]Muffle FurnaceRectangular assay furnace.[Pg 223]Muffle Assay FurnaceA—Openings in the plate. B—Part of plate which projects beyond the furnace.[Pg 224]Now I will describe the different things which are necessary in assaying, beginning with the assay furnace, of which one differs from another in shape, material, and the place in which it is set. In shape, they may be round or rectangular, the latter shape being more suited to assaying ores. The materials of the assay furnaces differ, in that one is made of bricks, another of iron, and certain ones of clay. The one of bricks is built on a chimney-hearth which is three and a half feet high; the iron one is placed in the same position, and also the one of clay. The brick one is a cubit high, a foot wide on the inside, and one foot two digits long; at a point five digits above the hearth—which is usually the thickness of an unbaked[2]brick—an iron plate is laid, and smeared over with lute on the upper side to prevent it from being injured by the fire; in front of the furnace above the plate is a mouth a palm high, five digits wide, and rounded at the top. The iron plate has three openings which are one digit wide and three digits long, one is at each side and the third at the back; through them sometimes the ash falls from the burning charcoal, and sometimes the draught blows through the chamber which is below the iron plate, and stimulates the fire. For this reason this furnace when used by metallurgists is named from assaying, but when used by the alchemists it is named from the wind[3]. The part of the iron plate which projects from the furnace is generally three-quarters of apalm long and a palm wide; small pieces of charcoal, after being laid thereon, can be placed quickly in the furnace through its mouth with a pair of tongs, or again, if necessary, can be taken out of the furnace and laid there.
The iron assay furnace is made of four iron bars a foot and a half high; which at the bottom are bent outward and broadened a short distance to enable them to stand more firmly; the front part of the furnace is made from two of these bars, and the back part from two of them; to these bars on both sides are joined and welded three iron cross-bars, the first at a height of a palm from the bottom, the second at a height of a foot, and the third at the top. The upright bars are perforated at that point where the side cross-bars are joined to them, in order that three similar iron bars on the remaining sides can be engaged in them; thus there are twelve cross-bars, which make three stages at unequal intervals. At the lower stage, the upright bars are distant from each other one foot and five digits; and at the middle stage the front is distant from the back three palms and one digit, and the sides are distant from each other three palms and as many digits; at the highest stage from the front to the back there is a distance of two palms, and between the sides three palms, so that in this way the furnace becomes narrower at the top. Furthermore, an iron rod, bent to the shape of the mouth, is set into the lowest bar of the front; this mouth, just like that of the brick furnace, is a palm high and five digits wide. Then the front cross-bar of the lower stage is perforated on each side of the mouth, and likewise the back one; through these perforations there pass two iron rods, thus making altogether four bars in the lower stage, and these support an iron plate smeared with lute; part of this plate also projects outside the furnace. The outside of the furnace from the lower stage to the upper, is covered with iron plates, which are bound to the bars by iron wires, and smeared with lute to enable them to bear the heat of the fire as long as possible.
As for the clay furnace, it must be made of fat, thick clay, medium so far as relates to its softness or hardness. This furnace has exactly the same height as the iron one, and its base is made of two earthenware tiles, one foot and three palms long and one foot and one palm wide. Each side of the fore part of both tiles is gradually cut away for the length of a palm, so that they are half a foot and a digit wide, which part projects from the furnace; the tiles are about a digit and a half thick. The walls are similarly of clay, and are set on the lower tiles at a distance of a digit from the edge, and support the upper tiles; the walls are three digits high and have four openings, each of which is about three digits high; those of the back part and of each side are five digits wide, and of the front, a palm and a half wide, to enable the freshly made cupels to be conveniently placed on the hearth, when it has been thoroughly warmed, that they may be dried there. Both tiles are bound on the outer edge with iron wire, pressed into them, so that they will be less easily broken; and the tiles, not unlike the iron bed-plate, have three openings three digits long and a digit wide, in order that when the upper one on account of the heat of the fire or for some other reason has become damaged, the lower one may be exchanged and take its place. Through theseholes, the ashes from the burning charcoal, as I have stated, fall down, and air blows into the furnace after passing through the openings in the walls of the chamber. The furnace is rectangular, and inside at the lower part it is three palms and one digit wide and three palms and as many digits long. At the upper part it is two palms and three digits wide, so that it also grows narrower; it is one foot high; in the middle of the back it is cut out at the bottom in the shape of a semicircle, of half a digit radius. Not unlike the furnace before described, it has in its forepart a mouth which is rounded at the top, one palm high and a palm and a digit wide. Its door is also made of clay, and this has a window and a handle; even the lid of the furnace which is made of clay has its own handle, fastened on with iron wire. The outer parts and sides of this furnace are bound with iron wires, which are usually pressed in, in the shape of triangles. The brick furnaces must remain stationary; the clay and iron ones can be carried from one place to another. Those of brick can be prepared more quickly, while those of iron are more lasting, and those of clay are more suitable. Assayers also make temporary furnaces in another way; they stand three bricks on a hearth, one on each side and a third one at the back, the forepart lies open to the draught, and on these bricks is placed an iron plate, upon which they again stand three bricks, which hold and retain the charcoal.
The setting of one furnace differs from another, in that some are placed higher and others lower; that one is placed higher, in which the man who is assaying the ore or metals introduces the scorifier through the mouth with the tongs; that one is placed lower, into which he introduces the crucible through its open top.
Crucible Assay FurnaceA—Iron hoop. B—Double bellows. C—Its nozzle. D—Lever.[Pg 227]In some cases the assayer uses an iron hoop[4]in place of a furnace; this is placed upon the hearth of a chimney, the lower edge being daubed with lute to prevent the blast of the bellows from escaping under it. If the blast is given slowly, the ore will be smelted and the copper will melt in the triangular crucible, which is placed in it and taken away again with the tongs. The hoop is two palms high and half a digit thick; its diameter is generally one foot and one palm, and where the blast from the bellows enters into it, it is notched out. The bellows is a double one, such as goldworkers use, and sometimes smiths. In the middle of the bellows there is a board in which there is an air-hole, five digits wide and seven long, covered by a little flap which is fastened over the air-hole on the lower side of the board; this flap is of equal length and width. The bellows, without its head, is three feet long, and at the back is one foot and one palm wide and somewhat rounded, and it is three palms wide at the head; the head itself is three palms long and two palms and a digit wide at the part where it joins the boards, then it gradually becomes narrower. The nozzle, of which there is only one, is one foot and two digits long; this nozzle, and one-half of the head in which the nozzle is fixed, are placed in an opening of the wall, this being one foot and one palm thick; it reaches only to the iron hoop on thehearth, for it does not project beyond the wall. The hide of the bellows is fixed to the bellows-boards with its own peculiar kind of iron nails. It joins both bellows-boards to the head, and over it there are cross strips of hide fixed to the bellows-boards with broad-headed nails, and similarly fixed to the head. The middle board of the bellows rests on an iron bar, to which it is fastened with iron nails clinched on both ends, so that it cannot move; the iron bar is fixed between two upright posts, through which it penetrates. Higher up on these upright posts there is a wooden axle, with iron journals which revolve in the holes in the posts. In the middle of this axle there is mortised a lever, fixed with iron nails to prevent it from flying out; the lever is five and a half feet long, and its posterior end is engaged in the iron ring of an iron rod which reaches to the "tail" of the lowest bellows-board, and there engages another similar ring. And so when the workman pulls down the lever, the lower part of the bellows is raised and drives the wind into the nozzle; then the wind, penetrating through the hole in the middle bellows-board, which is called the air-hole, lifts up the upper part of the bellows, upon whose upper board is a piece of lead, heavy enough to press down that part of the bellows again, and this being pressed down blows a blast through the nozzle. This is the principle of the double bellows, which is peculiar to the iron hoop where are placed the triangular crucibles in which copper ore is smelted and copper is melted.
MufflesA—Broad little windows of muffle. B—Narrow ones. C—Openings in the back thereof.[Pg 228]I have spoken of the furnaces and the iron hoop; I will now speak of the muffles and the crucibles. The muffle is made of clay, in the shape of an inverted gutter tile; it covers the scorifiers, lest coal dust fall into them and interfere with the assay. It is a palm and a half broad, and the height, which corresponds with the mouth of the furnace, is generally a palm,and it is nearly as long as the furnace; only at the front end does it touch the mouth of the furnace, everywhere else on the sides and at the back there is a space of three digits, to allow the charcoal to lie in the open space between it and the furnace. The muffle is as thick as a fairly thick earthen jar; its upper part is entire; the back has two little windows, and each side has two or three or even four, through which the heat passes into the scorifiers and melts the ore. In place of little windows, some muffles have small holes, ten in the back and more on each side. Moreover, in the back below the little windows, or small holes, there are cut away three semi-circular notches half a digit high, and on each side there are four. The back of the muffle is generally a little lower than the front.
ContainersA—Scorifier. B—Triangular crucible. C—Cupel.[Pg 229]The crucibles differ in the materials from which they are made, because they are made of either clay or ashes; and those of clay, which we also call "earthen," differ in shape and size. Some are made in the shape of a moderately thick salver (scorifiers), three digits wide, and of a capacity of anunciameasure; in these the ore mixed with fluxes is melted, and they are used by those who assay gold or silver ore. Some are triangular and much thicker and more capacious, holding five, or six, or even moreunciae; in these copper is melted, so that it can be poured out, expanded, and tested with fire, and in these copper ore is usually melted.
The cupels are made of ashes; like the preceding scorifiers they are tray-shaped, and their lower part is very thick but their capacity is less. In these lead is separated from silver, and by them assays are concluded. Inasmuch as the assayers themselves make the cupels, something must be said about the material from which they are made, and the method of making them. Some make them out of all kinds of ordinary ashes; these are not good, because ashes of this kind contain a certain amount of fat, whereby such cupels are easily broken when they are hot. Others make them likewise out of any kind of ashes which have been previously leached; of this kind are the ashes into which warm water has been infused for the purpose of making lye. These ashes, after being dried in the sun or a furnace, are sifted in a hair sieve; and although warm water washes away thefat from the ashes, still the cupels which are made from such ashes are not very good because they often contain charcoal dust, sand, and pebbles. Some make them in the same way out of any kind of ashes, but first of all pour water into the ashes and remove the scum which floats thereon; then, after it has become clear, they pour away the water, and dry the ashes; they then sift them and make the cupels from them. These, indeed, are good, but not of the best quality, because ashes of this kind are also not devoid of small pebbles and sand. To enable cupels of the best quality to be made, all the impurities must be removed from the ashes. These impurities are of two kinds; the one sort light, to which class belong charcoal dust and fatty material and other things which float in water, the other sort heavy, such as small stones, fine sand, and any other materials which settle in the bottom of a vessel. Therefore, first of all, water should be poured into the ashes and the light impurities removed; then the ashes should be kneaded with the hands, so that they will become properly mixed with the water. When the water has become muddy and turbid, it should be poured into a second vessel. In this way the small stones and fine sand, or any other heavy substance which may be there, remain in the first vessel, and should be thrown away. When all the ashes have settled in this second vessel, which will be shown if the water has become clear and does not taste of the flavour of lye, the water should be thrown away, and the ashes which have settled in the vessel should be dried in the sun or in a furnace. This material is suitable for the cupels, especially if it is the ash of beech wood or other wood which has a small annual growth; those ashes made from twigs and limbs of vines, which have rapid annual growth, are not sogood, for the cupels made from them, since they are not sufficiently dry, frequently crack and break in the fire and absorb the metals. If ashes of beech or similar wood are not to be had, the assayer makes little balls of such ashes as he can get, after they have been cleared of impurities in the manner before described, and puts them in a baker's or potter's oven to burn, and from these the cupels are made, because the fire consumes whatever fat or damp there may be. As to all kinds of ashes, the older they are the better, for it is necessary that they should have the greatest possible dryness. For this reason ashes obtained from burned bones, especially from the bones of the heads of animals, are the most suitable for cupels, as are also those ashes obtained from the horns of deer and the spines of fishes. Lastly, some take the ashes which are obtained from burnt scrapings of leather, when the tanners scrape the hides to clear them from hair. Some prefer to use compounds, that one being recommended which has one and a half parts of ashes from the bones of animals or the spines of fishes, and one part of beech ashes, and half a part of ashes of burnt hide scrapings. From this mixture good cupels are made, though far better ones are obtained from equal portions of ashes of burnt hide scrapings, ashes of the bones of heads of sheep and calves, and ashes of deer horns. But the best of all are produced from deer horns alone, burnt to powder; this kind, by reason of its extreme dryness, absorbs metals least of all. Assayers of our own day, however, generally make the cupels from beech ashes. These ashes, after being prepared in the manner just described, are first of all sprinkled with beer or water, to make them stick together, and are then ground in a small mortar. They are ground again after being mixed with the ashes obtained from the skulls of beasts or from the spines of fishes; the more the ashes are ground the better they are. Some rub bricks and sprinkle the dust so obtained, after sifting it, into the beech ashes, for dust of this kind does not allow the hearth-lead to absorb the gold or silver by eating away the cupels. Others, to guard against the same thing, moisten the cupels with white of egg after they have been made, and when they have been dried in the sun, again crush them; especially if they want to assay in it an ore of copper which contains iron. Some moisten the ashes again and again with cow's milk, and dry them, and grind them in a small mortar, and then mould the cupels. In the works in which silver is separated from copper, they make cupels from two parts of the ashes of the crucible of the cupellation furnace, for these ashes are very dry, and from one part of bone-ash. Cupels which have been made in these ways also need to be placed in the sun or in a furnace; afterward, in whatever way they have been made, they must be kept a long time in dry places, for the older they are, the dryer and better they are.
Cupel Moulds and PestlesA—Little mould. B—Inverted mould. C—Pestle. D—Its knob. E—Second pestle.[Pg 231]Not only potters, but also the assayers themselves, make scorifiers and triangular crucibles. They make them out of fatty clay, which is dry[5], and neither hard nor soft. With this clay they mix the dust of old broken crucibles, or of burnt and worn bricks; then they knead with a pestle the clay thus mixed with dust, and then dry it. As to these crucibles,the older they are, the dryer and better they are. The moulds in which the cupels are moulded are of two kinds, that is, a smaller size and a larger size. In the smaller ones are made the cupels in which silver or gold is purged from the lead which has absorbed it; in the larger ones are made cupels in which silver is separated from copper and lead. Both moulds are made out of brass and have no bottom, in order that the cupels can be taken out of them whole. The pestles also are of two kinds, smaller and larger, each likewise of brass, and from the lower end of them there projects a round knob, and this alone is pressed into the mould and makes the hollow part of the cupel. The part which is next to the knob corresponds to the upper part of the mould.
So much for these matters. I will now speak of the preparation of the ore for assaying. It is prepared by roasting, burning, crushing, and washing. It is necessary to take a fixed weight of ore in order that one may determine how great a portion of it these preparations consume. The hard stone containing the metal is burned in order that, when its hardness has been overcome, it can be crushed and washed; indeed, the very hardest kind, before it is burned, is sprinkled with vinegar, in order that it may more rapidly soften in the fire. The soft stone should be broken with a hammer, crushed in a mortar and reduced to powder; then it should be washed and then dried again. If earth is mixed with the mineral, it is washed in a basin, and that which settles is assayed in the fire after it is dried. All mining products which are washed must again be dried. But ore which is rich in metal is neither burned nor crushed nor washed, but is roasted, lest that method of preparation should lose some of the metal. When the fires havebeen kindled, this kind of ore is roasted in an enclosed pot, which is stopped up with lute. A less valuable ore is even burned on a hearth, being placed upon the charcoal; for we do not make a great expenditure upon metals, if they are not worth it. However, I will go into fuller details as to all these methods of preparing ore, both a little later, and in thefollowing Book.
For the present, I have decided to explain those things which mining people usually call fluxes[6]because they are added to ores, not only for assaying, but also for smelting. Great power is discovered in all these fluxes, but we do not see the same effects produced in every case; and some are of a very complicated nature. For when they have been mixed with the ore and are melted in either the assay or the smelting furnace, some of them, because they melt easily, to some extent melt the ore; others, because they either make the ore very hot or penetrate into it, greatly assist the fire in separating the impurities from the metals, and they also mix the fused part with the lead, or they partly protect from the fire the ore whose metal contents would be either consumed in the fire, or carried up with the fumes and fly out of the furnace; some fluxes absorb the metals. To the first order belongs lead, whether it be reduced to little granules or resolved into ash by fire, or red-lead[7], or ochre made from lead[8], or litharge, or hearth-lead, orgalena; also copper, the same either roasted or in leaves or filings[9]; also the slags of gold, silver, copper, and lead; also soda[10], its slags, saltpetre, burned alum, vitriol,sal tostus, and melted salt[11]; stones which easily melt in hot furnaces, the sand which is made from them[12]; softtophus[13],and a certain white schist[14]. But lead, its ashes, red-lead, ochre, and litharge, are more efficacious for ores which melt easily; hearth-lead for those which melt with difficulty; and galena for those which melt with greater difficulty. To the second order belong iron filings, their slag,sal artificiosus, argol, dried lees of vinegar[15], and the lees of theaquawhich separates gold from silver[16]; these lees andsal artificiosushave the power of penetrating into ore, the argol to a considerable degree, the lees of vinegar to a greater degree, but most of all those of theaquawhich separates gold from silver; filings and slags of iron, since they melt more slowly, have the power of heating the ore. To the third order belong pyrites, the cakes which are melted from them, soda, its slags, salt, iron, iron scales, iron filings, iron slags, vitriol, the sand which is resolved from stones which easily melt in the fire, andtophus; but first of all are pyrites and the cakes which are melted from it, for they absorb the metals of the ore and guard them from the fire which consumes them. To the fourth order belong lead and copper, and their relations. And so with regard to fluxes, it is manifest that some are natural, others fall in the category of slags, and the rest are purged from slag. When weassay ores, we can without great expense add to them a small portion of any sort of flux, but when we smelt them we cannot add a large portion without great expense. We must, therefore, consider how great the cost is, to avoid incurring a greater expense on smelting an ore than the profit we make out of the metals which it yields.
The colour of the fumes which the ore emits after being placed on a hot shovel or an iron plate, indicates what flux is needed in addition to the lead, for the purpose of either assaying or smelting. If the fumes have a purple tint, it is best of all, and the ore does not generally require any flux whatever. If the fumes are blue, there should be added cakes melted out of pyrites or other cupriferous rock; if yellow, litharge and sulphur should be added; if red, glass-galls[17]and salt; if green, then cakes melted from cupriferous stones, litharge, and glass-galls; if the fumes are black, melted salt or iron slag, litharge and white lime rock. If they are white, sulphur and iron which is eaten with rust; if they are white with green patches, iron slag and sand obtained from stones which easily melt; if the middle part of the fumes are yellow and thick, but the outer parts green, the same sand and iron slag. The colour of the fumes not only gives us information as to the proper remedies which should be applied to each ore, but also more or less indication as to the solidified juices which are mixed with it, and which give forth such fumes. Generally, blue fumes signify that the ore contains azure yellow, orpiment; red, realgar; green, chrysocolla; black, black bitumen; white, tin[18]; white with green patches, the same mixed with chrysocolla; the middle part yellow and other parts green show that it contains sulphur. Earth, however, and other things dug up which contain metals, sometimes emit similarly coloured fumes.
If the ore contains anystibium, then iron slag is added to it; if pyrites, then are added cakes melted from a cupriferous stone and sand made from stones which easily melt. If the ore contains iron, then pyrites and sulphur are added; for just as iron slag is the flux for an ore mixed with sulphur, so on the contrary, to a gold or silver ore containing iron, from which they arenot easily separated, is added sulphur and sand made from stones which easily melt.
Sal artificiosus[19]suitable for use in assaying ore is made in many ways. By the first method, equal portions of argol, lees of vinegar, and urine, are all boiled down together till turned into salt. The second method is from equal portions of the ashes which wool-dyers use, of lime, of argol purified, and of melted salt; onelibraof each of these ingredients is thrown into twentylibraeof urine; then all are boiled down to one-third and strained, and afterward there is added to what remains onelibraand fourunciaeof unmelted salt, eight pounds of lye being at the same time poured into the pots, with litharge smeared around on the inside, and the whole is boiled till the salt becomes thoroughly dry. The third method follows. Unmelted salt, and iron which is eaten with rust, are put into a vessel, and after urine has been poured in, it is covered with a lid and put in a warm place for thirty days; then the iron is washed in the urine and taken out, and the residue is boiled until it is turned into salt. In the fourth method by whichsal artificiosusis prepared, the lye made from equal portions of lime and the ashes which wool-dyers use, together with equal portions of salt, soap, white argol, and saltpetre, are boiled until in the end the mixture evaporates and becomes salt. This salt is mixed with the concentrates from washing, to melt them.
Saltpetre is prepared in the following manner, in order that it may be suitable for use in assaying ore. It is placed in a pot which is smeared on the inside with litharge, and lye made of quicklime is repeatedly poured over it, and it is heated until the fire consumes it. Wherefore the saltpetre does not kindle with the fire, since it has absorbed the lime which preserves it, and thus it is prepared[20].
The following compositions[21]are recommended to smelt all ores which the heat of fire breaks up or melts only with difficulty. Of these, one is made from stones of the third order, which easily melt when thrown into hot furnaces. They are crushed into pure white powder, and with half anunciaof this powder there are mixed twounciaeof yellow litharge, likewise crushed. This mixture is put into a scorifier large enough to hold it, and placed under the muffle of a hot furnace; when the charge flows like water, which occurs after half an hour, it is taken out of the furnace and poured on to a stone, and when it has hardened it has the appearance of glass, and this is likewise crushed. This powder is sprinkled over any metalliferous ore which does not easily melt when we are assaying it, and it causes the slag to exude.
Others, in place of litharge, substitute lead ash,[22]which is made in the following way: sulphur is thrown into lead which has been melted in a crucible, and it soon becomes covered with a sort of scum; when this is removed, sulphur is again thrown in, and the skin which forms is again taken off; this is frequently repeated, in fact until all the lead is turned into powder. There is a powerful flux compound which is made from oneunciaeach of prepared saltpetre, melted salt, glass-gall, and argol, and one-third of anunciaof litharge and abesof glass ground to powder; this flux, being added to an equal weight of ore, liquefies it. A more powerful flux is made by placing together in a pot, smeared on the inside with litharge, equal portions of white argol, common salt, and prepared saltpetre, and these are heated until a white powder is obtained from them, and this is mixed with as much litharge; one part of this compound is mixed with two parts of the ore which is to be assayed. A still more powerful flux than this is made out of ashes of black lead, saltpetre, orpiment,stibium, and dried lees of theaquawith which gold workers separate gold from silver. The ashes of lead[23]are made from one pound of lead and one pound of sulphur; the lead is flattened out into sheets by pounding with a hammer, and placed alternately with sulphur in a crucible or pot, and they are heated together until the fire consumes the sulphur and the lead turns to ashes. Onelibraof crushed saltpetre is mixed with onelibraof orpiment similarly ground to powder, and the two are cooked in an iron pan until they liquefy; they are then poured out, and after cooling are again ground to powder. Alibraofstibiumand abesof the dried lees (of what?) are placed alternately in a crucible and heated to the point at which they form a button, which is similarly reduced to powder. Abesof this powder and onelibraof the ashes of lead, as well as alibraof powder made out of the saltpetre and orpiment, are mixed together and apowder is made from them, one part of which added to two parts of ore liquefies it and cleanses it of dross. But the most powerful flux is one which has twodrachmaeof sulphur and as much glass-galls, and half anunciaof each of the following,—stibium, salt obtained from boiled urine, melted common salt, prepared saltpetre, litharge, vitriol, argol, salt obtained from ashes of musk ivy, dried lees of theaquaby which gold-workers separate gold from silver, alum reduced by fire to powder, and oneunciaof camphor[24]combined with sulphur and ground into powder. A half or whole portion of this mixture, as the necessity of the case requires, is mixed with one portion of the ore and two portions of lead, and put in a scorifier; it is sprinkled with powder of crushed Venetian glass, and when the mixture has been heated for an hour and a half or two hours, a button will settle in the bottom of the scorifier, and from it the lead is soon separated.
There is also a flux which separates sulphur, orpiment and realgar from metalliferous ore. This flux is composed of equal portions of iron slag, whitetophus, and salt. After these juices have been secreted, the ores themselves are melted, with argol added to them. There is one flux which preservesstibiumfrom the fire, that the fire may not consume it, and which preserves the metals from thestibium; and this is composed of equal portions of sulphur, prepared saltpetre, melted salt, and vitriol, heated together in lye until no odour emanates from the sulphur, which occurs after a space of three or four hours.[25]
It is also worth while to substitute certain other mixtures. Take two portions of ore properly prepared, one portion of iron filings, and likewise one portion of salt, and mix; then put them into a scorifier and place them in a muffle furnace; when they are reduced by the fire and run together, a button will settle in the bottom of the scorifier. Or else take equal portions of ore and of lead ochre, and mix with them a small quantity of iron filings, and put them into a scorifier, then scatter iron filings over the mixture. Or else take ore which has been ground to powder and sprinkle it in a crucible, and then sprinkle over it an equal quantity of salt that has been three or four times moistened with urine and dried; then, again and again alternately, powdered ore and salt; next, after the crucible has been covered with a lid and sealed, it is placed upon burning charcoal. Or else take one portion of ore, one portion of minute lead granules, half a portion of Venetian glass, and the same quantity of glass-galls. Or else take one portion of ore, one portion of lead granules, half a portion of salt, one-fourth of a portion of argol, and the same quantity of lees of theaquawhich separates gold from silver. Or else take equal portions of prepared ore and a powder in which thereare equal portions of very minute lead granules, melted salt,stibiumand iron slag. Or else take equal portions of gold ore, vitriol, argol, and of salt. So much for the fluxes.
In the assay furnace, when it has been prepared in the way in which I have described, is first placed a muffle. Then selected pieces of live charcoals are laid on it, for, from pieces of inferior quality, a great quantity of ash collects around the muffle and hinders the action of the fire. Then the scorifiers are placed under the muffle with tongs, and glowing coals are placed under the fore part of the muffle to warm the scorifiers more quickly; and when the lead or ore is to be placed in the scorifiers, they are taken out again with the tongs. When the scorifiers glow in the heat, first of all the ash or small charcoals, if any have fallen into them, should be blown away with an iron pipe two feet long and a digit in diameter; this same thing must be done if ash or small coal has fallen into the cupels. Next, put in a small ball of lead with the tongs, and when this lead has begun to be turned into fumes and consumed, add to it the prepared ore wrapped in paper. It is preferable that the assayer should wrap it in paper, and in this way put it in the scorifier, than that he should drop it in with a copper ladle; for when the scorifiers are small, if he uses a ladle he frequently spills some part of the ore. When the paper is burnt, he stirs the ore with a small charcoal held in the tongs, so that the lead may absorb the metal which is mixed in the ore; when this mixture has taken place, the slag partly adheres by its circumference to the scorifier and makes a kind of black ring, and partly floats on the lead in which is mixed the gold or silver; then the slag must be removed from it.
The lead used must be entirely free from every trace of silver, as is that which is known asVillacense.[26]But if this kind is not obtainable, the lead must be assayed separately, to determine with certainty that proportion of silver it contains, so that it may be deducted from the calculation of the ore, and the result be exact; for unless such lead be used, the assay will be false and misleading.TongsA—Claws of the tongs. B—Iron, giving form of an egg. C—Opening.[Pg 240]The lead balls are made with a pair of iron tongs, about one foot long; its iron claws are so formed that when pressed together they are egg-shaped; each claw contains a hollow cup, and when the claws are closed there extends upward from the cup a passage, so there are two openings, one of which leads to each hollow cup. And so when the molten lead is poured in through the openings, it flows down into the hollow cup, and two balls are formed by one pouring.
In this place I ought not to omit mention of another method of assaying employed by some assayers. They first of all place prepared ore in the scorifiers and heat it, and afterward they add the lead. Of this method I cannot approve, for in this way the ore frequently becomes cemented, and for this reason it does not stir easily afterward, and is very slow in mixing with the lead.
If the whole space of the furnace covered by the muffle is not filled with scorifiers, cupels are put in the empty space, in order that they may become warmed in the meantime. Sometimes, however, it is filled with scorifiers, when we are assaying many different ores, or many portions of one ore at the same time. Although the cupels are usually dried in one hour, yet smaller ones are done more quickly, and the larger ones more slowly. Unless the cupels are heated before the metal mixed with lead is placed in them, they frequently break, and the lead always sputters and sometimes leaps out of them; if the cupel is broken or the lead leaps out of it, it is necessary to assay another portion of ore; but if the lead only sputters, then the cupels should be covered with broad thin pieces of glowing charcoal, and when the lead strikes these, it falls back again, and thus the mixture is slowly exhaled. Further, if in the cupellation the lead which is in the mixture is not consumed, but remains fixed and set, and is covered by a kind of skin, this is a sign that it has not been heated by a sufficiently hot fire; put into the mixture, therefore, a dry pine stick, or a twig of a similar tree, and hold it in the hand in order that it can be drawn away when it has been heated. Then take care that the heat is sufficient and equal; if the heat has not passed all round the charge, as it should when everything is done rightly, but causes it to have a lengthened shape, so that it appears to have a tail, this is a sign that the heat is deficient where the tail lies.HookSmall iron hook.[Pg 240]Then in order that the cupel may be equally heated by the fire, turn it around with a small iron hook, whose handle is likewise made of iron and is a foot and a half long.
Next, if the mixture has not enough lead, add as much of it as is required with the iron tongs, or with the brass ladle to which is fastened a very long handle. In order that the charge may not be cooled, warm the lead beforehand.But it is better at first to add as much lead as is required to the ore which needs melting, rather than afterward when the melting has been half finished, that the whole quantity may not vanish in fumes, but part of it remain fast. When the heat of the fire has nearly consumed the lead, then is the time when the gold and silver gleam in their varied colours, and when all the lead has been consumed the gold or silver settles in the cupel. Then as soon as possible remove the cupel out of the furnace, and take the button out of it while it is still warm, in order that it does not adhere to the ashes. This generally happens if the button is already cold when it is taken out. If the ashes do adhere to it, do not scrape it with a knife, lest some of it be lost and the assay be erroneous, but squeeze it with the iron tongs, so that the ashes drop off through the pressure. Finally, it is of advantage to make two or three assays of the same ore at the same time, in order that if by chance one is not successful, the second, or in any event the third, may be certain.